Lead isotope exchange between dissolved and fluvial particulate matter: a laboratory study from the Johor River estuary.

Atmospheric aerosols are the dominant source of Pb to the modern marine environment, and as a result, in most regions of the ocean the Pb isotopic composition of dissolved Pb in the surface ocean (and in corals) matches that of the regional aerosols. In the Singapore Strait, however, there is a large offset between seawater dissolved and coral Pb isotopes and that of the regional aerosols. We propose that this difference results from isotope exchange between dissolved Pb supplied by anthropogenic aerosol deposition and adsorbed natural crustal Pb on weathered particles delivered to the ocean by coastal rivers. To investigate this issue, Pb isotope exchange was assessed through a closed-system exchange experiment using estuarine waters collected at the Johor River mouth (which discharges to the Singapore Strait). During the experiment, a known amount of dissolved Pb with the isotopic composition of NBS-981 (206Pb/207Pb = 1.093) was spiked into the unfiltered Johor water (dissolved and particulate 206Pb/207Pb = 1.199) and the changing isotopic composition of the dissolved Pb was monitored. The mixing ratio of the estuarine and spike Pb should have produced a dissolved 206Pb/207Pb isotopic composition of 1.161, but within a week, the 206Pb/207Pb in the water increased to 1.190 and continued to increase to 1.197 during the next two months without significant changes of the dissolved Pb concentration. The kinetics of isotope exchange was assessed using a simple Kd model, which assumes multiple sub-reservoirs within the particulate matter with different exchange rate constants. The Kd model reproduced 56% of the observed Pb isotope variance. Both the closed-system experiment and field measurements imply that isotope exchange can be an important mechanism for controlling Pb and Pb isotopes in coastal waters. A similar process may occur for other trace elements.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

Meta-analysis indicates better climate adaptation and mitigation performance of hybrid engineering-natural coastal defence measures.

Traditional approaches to coastal defence often struggle to reduce the risks of accelerated climate change. Incorporating nature-based components into coastal defences may enhance adaptation to climate change with added benefits, but we need to compare their performance against conventional hard measures. We conduct a meta-analysis that compares the performances of hard, hybrid, soft and natural measures for coastal defence across different functions of risk reduction, climate change mitigation, and cost-effectiveness. Hybrid and soft measures offer higher risk reduction and climate change mitigation benefits than unvegetated natural systems, while performing on par with natural measures. Soft and hybrid measures are more cost-effective than hard measures, while hybrid measures provide the highest hazard reduction among all measures. All coastal defence measures have a positive economic return over a 20-year period. Mindful of risk context, our results provide strong an evidence-base for integrating and upscaling nature-based components into coastal defences in lower risk areas.

A modest 0.5-m rise in sea level will double the tsunami hazard in Macau.

Rising sea levels will have overwhelmingly negative impacts on coastal communities globally. With previous research focused on how sea-level rise (SLR) affects storm-induced flooding, we show that SLR will also increase both the frequency and the intensity of tsunami-induced flooding, another significant coastal hazard associated with sea-level extremes. We developed probabilistic tsunami inundation maps for Macau, a densely populated coastal city located in the South China Sea, under current sea-level, 0.5-m SLR, and 1-m SLR conditions, using an extensive Monte Carlo tsunami inundation simulation. Our results indicate that conservative amounts of SLR of 0.5 m (by 2060) and 1 m (by 2100) would dramatically increase the frequency of tsunami-induced flooding incidences by a factor of 1.2 to 2.4 and 1.5 to 4.7, respectively.

High-frequency Coastal Overwash Deposits from Phra Thong Island, Thailand.

The 26th December 2004 Indian Ocean Tsunami (IOT) emanated from an Mw 9.2 earthquake that generated a 1600 km-long rupture along the Sumatran Megathrust and generated tsunami waves up to 30 m high. The IOT directly impacted the Bay of Bengal and east Africa, with over 283,000 people perishing. At the time, this catastrophic event was considered unprecedented and sparked intense investigations to test this claim. It is now believed that four pre-2004 IOT events have occurred in the last 2500 years, recurring every 550 to 700 years. Much of this information comes from Phra Thong Island, Thailand, where a sequence of four stacked sandsheets separated by organic units has been recognised and compared to the 2004 IOT event. Recently, ground-penetrating radar on Phra Thong Island identified a region that could not be explained by the known stratigraphy. The stratigraphy of the area was investigated from auger cores and pits, and several previously-unrecognised sandsheets were identified and compared to the known tsunami sandsheets. The proximity of the newly-recognised sandsheets to the palaeo-coastline of Phra Thong Island does not preclude the impacts of localised storms in sandsheet emplacement or that tsunamigenic earthquake recurrence may have been more frequent in the past.

Half-metre sea-level fluctuations on centennial timescales from mid-Holocene corals of Southeast Asia.

Sea-level rise is a global problem, yet to forecast future changes, we must understand how and why relative sea level (RSL) varied in the past, on local to global scales. In East and Southeast Asia, details of Holocene RSL are poorly understood. Here we present two independent high-resolution RSL proxy records from Belitung Island on the Sunda Shelf. These records capture spatial variations in glacial isostatic adjustment and paleotidal range, yet both reveal a RSL history between 6850 and 6500 cal years BP that includes two 0.6 m fluctuations, with rates of RSL change reaching 13±4 mm per year (2σ). Observations along the south coast of China, although of a lower resolution, reveal fluctuations similar in amplitude and timing to those on the Sunda Shelf. The consistency of the Southeast Asian records, from sites 2,600 km apart, suggests that the records reflect regional changes in RSL that are unprecedented in modern times.

A century long sedimentary record of anthropogenic lead (Pb), Pb isotopes and other trace metals in Singapore.

Reconstructing the history of metal deposition in Singapore lake sediments contributes to understanding the anthropogenic and natural metal deposition in the data-sparse Southeast Asia. To this end, we present a sedimentary record of Pb, Pb isotopes and eleven other metals (Ag, As, Ba, Cd, Co, Cr, Cu, Ni, Tl, U and Zn) from a well-dated sediment core collected near the depocenter of MacRitchie Reservoir in central Singapore. Before the 1900s, the sedimentary Pb concentration was less than 2 mg/kg for both soil and sediment, with a corresponding (206)Pb/(207)Pb of ∼1.20. The Pb concentration increased to 55 mg/kg in the 1990s, and correspondingly the (206)Pb/(207)Pb decreased to less than 1.14. The (206)Pb/(207)Pb in the core top sediment is concordant with the (206)Pb/(207)Pb signal of aerosols in Singapore and other Southeast Asian cities, suggesting that Pb in the reservoir sediment was mainly from atmospheric deposition. Using the Pb concentration in the topmost layer of sediment, the estimated atmospheric Pb flux in Singapore today is ∼1.6 × 10(-2) g/m(2) yr. The concentrations of eleven other metals preserved in the sediment were also determined. A principal component analysis showed that most of the metals exhibit an increasing trend towards 1990s with a local concentration peak in the mid-20(th) century.

Temporal distributions of anthropogenic Al, Zn and Pb in Hong Kong Porites coral during the last two centuries.

A 182-year long record of trace metal concentrations of aluminum, zinc and lead was reconstructed from a massive Porites coral skeleton from southeastern Hong Kong to evaluate the impacts of anthropogenic activity on the marine environment. Zn/Ca and Pb/Ca ratios fluctuate synchronously from the early 19th century to the present, indicating that the marine environment has been anthropogenically influenced since industrialization. Additionally, land reclamation, mining, and ship building activities are recorded by elevated Al/Ca ratios from 1900 to 1950. The coral record indicates that high levels of Zn, Pb and Al occur coincidentally with local wars, and may have contributed to partial colony mortality. Pb/Ca does not correlate well with hemispheric proxy records after 1950, indicating that coastal corals may be recording local rather than hemispheric contamination. Pb/Ca levels in Hong Kong, Guangdong and Hainan corals imply a continuous supply of Pb-based contamination to southern China not reflected in hemispheric signals.