Ultrasonic Transducer From Piezoelectric Polymer Multilayer Through Electrophoretic Deposition for Photoacoustic Imaging.

Emerging ultrasound imaging modality based on optical-generated acoustic waves, such as photoacoustic (PA) imaging, has enabled novel functional imaging on biological samples. The performance of the ultrasonic transducer plays a critical role in producing higher quality PA images. However, the high electrical impedance of the small piezoelectric elements in the transducer array causes an electrical mismatch with external circuitry and results in degraded sensitivity. One effective method for reducing the electrical impedance is to implement a piezoelectric multilayer configuration instead of the conventional single layer for the transducer. In this work, we introduced an ultrasonic transducer comprising a piezoelectric polymer multilayer structure produced by an innovative multicycle powder-based electrophoretic deposition, using a suspension of polymer nanoparticles. The multicycle electrophoretic deposition overcomes the redissolution issue in solution-based methods. The ultrasonic transducer comprising the piezoelectric polymer multilayer exhibits significantly enhanced receiving sensitivity as compared to the ultrasonic transducer using a single layer. Ultrasonic transducer with multielement array configuration is obtained using the piezoelectric polymer multilayer, and PA imaging with improved resolution is demonstrated. Theoretical analysis shows that the enhanced transducer performance is mainly attributed to the improved electrical impedance match between the piezoelectric polymer element in the transducer and external receiving circuit.

Concave Array Ultrasonic Transducer From Multilayer Piezoelectric Ceramic for Photoacoustic Imaging.

Implementation of piezoelectric multilayer ceramic (MLC) is an effective way to reduce impedance and improve the performance of linear-array transducer for ultrasonic system applications. However, the ultrasonic image derived from a planar linear-array transducer generally suffers from degradation of lateral resolution and contrast. In this article, we designed and fabricated a focused 5-MHz 128-element linear-array ultrasonic transducer with concave structure using five-layered 0.1Pb (Ni1/3Nb2/3)O3 -0.35Pb(Zn1/3Nb2/3)O3 -0.15Pb(Mg1/3Nb2/3)O3-0.1PbZrO3-0.3PbTiO3 (PNN-PZN-PMN-PZ-PT) piezo- electric ceramic. The transducer showed a bandwidth of 63% at -6 dB and the lateral resolution up to 0.33 mm. An improved transmission signal of 90% higher than a commercial single-layer ceramic transducer was also achieved. We further demonstrated high-resolution photoacoustic imaging with the obtained concave linear-array transducer.

Graphene field-effect transistors with ferroelectric gating.

Recent experiments on ferroelectric gating have introduced a novel functionality, i.e., nonvolatility, in graphene field-effect transistors. A comprehensive understanding in the nonlinear, hysteretic ferroelectric gating and an effective way to control it are still absent. In this Letter, we quantitatively characterize the hysteretic ferroelectric gating using the reference of an independent background doping (n(BG)) provided by normal dielectric gating. More importantly, we prove that n(BG) can be used to control the ferroelectric gating by unidirectionally shifting the hysteretic ferroelectric doping in graphene. Utilizing this electrostatic effect, we demonstrate symmetrical bit writing in graphene-ferroelectric field-effect transistors with resistance change over 500% and reproducible no-volatile switching over 105 cycles.

Piezoelectric polymer multilayer on flexible substrate for energy harvesting.

A piezoelectric polymer multilayer structure formed on a flexible substrate is investigated for mechanical energy harvesting under bending mode. Analytical and numerical models are developed to clarify the effect of material parameters critical to the energy harvesting performance of the bending multilayer structure. It is shown that the maximum power is proportional to the square of the piezoelectric stress coefficient and the inverse of dielectric permittivity of the piezoelectric polymer. It is further found that a piezoelectric multilayer with thinner electrodes can generate more electric energy in bending mode. The effect of improved impedance matching in the multilayer polymer on energy output is remarkable. Comparisons between piezoelectric ceramic multilayers and polymer multilayers on flexible substrate are discussed. The fabrication of a P(VDF-TrFE) multilayer structure with a thin Al electrode layer is experimentally demonstrated by a scalable dip-coating process on a flexible aluminum substrate. The results indicate that it is feasible to produce a piezoelectric polymer multilayer structure on flexible substrate for harvesting mechanical energy applicable for many low-power electronics.

Graphene-ferroelectric hybrid structure for flexible transparent electrodes.

Graphene has exceptional optical, mechanical, and electrical properties, making it an emerging material for novel optoelectronics, photonics, and flexible transparent electrode applications. However, the relatively high sheet resistance of graphene is a major constraint for many of these applications. Here we propose a new approach to achieve low sheet resistance in large-scale CVD monolayer graphene using nonvolatile ferroelectric polymer gating. In this hybrid structure, large-scale graphene is heavily doped up to 3 × 10(13) cm(-2) by nonvolatile ferroelectric dipoles, yielding a low sheet resistance of 120 Ω/□ at ambient conditions. The graphene-ferroelectric transparent conductors (GFeTCs) exhibit more than 95% transmittance from the visible to the near-infrared range owing to the highly transparent nature of the ferroelectric polymer. Together with its excellent mechanical flexibility, chemical inertness, and the simple fabrication process of ferroelectric polymers, the proposed GFeTCs represent a new route toward large-scale graphene-based transparent electrodes and optoelectronics.

Miniaturized acceleration sensors with in-plane polarized piezoelectric thin films produced by micromachining.

Miniaturized acceleration sensors employing piezoelectric thin films were fabricated through batch micromachining with silicon and silicon-on-insulator (SOI) wafers. The acceleration sensors comprised multiple suspension beams supporting a central seismic mass. Ferroelectric (Pb,La)(Zr,Ti) O(3) (PLZT) thin films were coated and in-plane polarized on the surfaces of the suspension beams for realizing electromechanical conversion through the piezoelectric effect. Interdigital electrodes were formed on the PLZT films and connected in parallel. Finite element analyses were conducted for the stress and strain distributions, providing guidance to the structural design, including optimizing electrode positioning for collecting the electrical output constructively. Uniformity of the beam thickness and sample consistency were significantly improved by using SOI wafers instead of silicon wafers. The measurement results showed that all the sensor samples had fundamental resonances of symmetric out-of-plane vibration mode at frequencies in the range of 8 to 35 kHz, depending on the sample dimensions. These sensors exhibited stable electrical outputs in response to acceleration input, achieving a high signal-to-noise ratio without any external amplifier or signal conditioning.