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We have developed a mid-infrared Doppler-free saturation absorption spectroscopy apparatus that employs a commercial continuous-wave optical parametric oscillator (CW OPO), complemented by a home-built automation and wavelength scanning system. Here, we report a comprehensive spectral scan of the Q branch transitions of the ν3 = 1 band of methane (CH4) with an average linewidth (FWHM) of 4.5â MHz. The absolute frequency calibration was achieved using previously reported transition frequencies determined using optical frequency combs, while a Fabry-Perot etalon was used for the relative frequency calibration. We report 15 transitions with improved accuracies of 1.13â MHz (3.76 × 10-5â cm-1).
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Vibronically resolved laser-induced fluorescence/dispersed fluorescence (LIF/DF) and cavity ring-down (CRD) spectra of the electronic transition of the calcium isopropoxide [CaOCH(CH3)2] radical have been obtained under jet-cooled conditions. An essentially constant energy separation of 68 cm-1 has been observed for the vibrational ground levels and all fundamental vibrational levels accessed in the LIF measurement. To simulate the experimental spectra and assign the recorded vibronic bands, Franck-Condon (FC) factors and vibrational branching ratios (VBRs) are predicted from vibrational modes and their frequencies calculated using the complete-active-space self-consistent field (CASSCF) and equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) methods. Combined with the calculated electronic transition energy, the computational results, especially those from the EOM-CCSD calculations, reproduced the experimental spectra with considerable accuracy. The experimental and computational results suggest that the FC matrix for the studied electronic transition is largely diagonal, but transitions from the vibrationless levels of the à state to the XÌ-state levels of the CCC bending (ν14 and ν15), CaO stretch (ν13), and CaOC asymmetric stretch (ν9 and ν11) modes also have considerable intensities. Transitions to low-frequency in-plane [ν17(a')] and out-of-plane [ν30(a'')] CaOC bending modes were observed in the experimental LIF/DF spectra, the latter being FC-forbidden but induced by the pseudo-Jahn-Teller (pJT) effect. Both bending modes are coupled to the CaOC asymmetric stretch mode via the Duschinsky rotation, as demonstrated in the DF spectra obtained by pumping non-origin vibronic transitions. The pJT interaction also induces transitions to the ground-state vibrational level of the ν10(a') mode, which has the CaOC bending character. Our combined experimental and computational results provide critical information for future direct laser cooling of the target molecule and other alkaline earth monoalkoxide radicals.
RESUMO
Laser-induced fluorescence/dispersed fluorescence (LIF/DF) and cavity ring-down spectra of the A1Ì2A''/A2Ì2A'-XÌ2A' electronic transition of the calcium ethoxide (CaOC2H5) radical have been obtained under jet-cooled conditions. An essentially constant Ã2-Ã1 energy separation for different vibronic levels is observed in the LIF spectrum, which is attributed to both the spin-orbit (SO) interaction and non-relativistic effects. Electronic transition energies, vibrational frequencies, and spin-vibrational eigenfunctions calculated using the coupled-cluster method, along with results from previous complete active space self-consistent field calculations, have been used to predict the vibronic energy level structure and simulate the recorded LIF/DF spectra. Although the vibrational frequencies and Franck-Condon (FC) factors calculated under the Born-Oppenheimer approximation and the harmonic oscillator approximation reproduce the dominant spectral features well, the inclusion of the pseudo-Jahn-Teller (pJT) and SO interactions, especially those between the A1Ì2Aâ³/A2Ì2A' and the BÌ2A' states, induces additional vibronic transitions and significantly improves the accuracy of the spectral simulations. Notably, the spin-vibronic interactions couple vibronic levels and alter transition intensities. The calculated FC matrix for the A1Ì2A''/A2Ì2A'-XÌ2A' transition contains a number of off-diagonal matrix elements that connect the vibrational ground levels to the levels of the ν8 (CO stretch), ν11 (OCC bending), ν12 (CaO stretch), ν13 (in-plane CaOC bending), and ν21 (out-of-plane CaOC bending) modes, which are used for vibrational assignments. Transitions to the ν21(aâ³) levels are allowed due to the pJT effect. Furthermore, when LIF transitions to the Ã-state levels of the CaOC-bending modes, ν13 and ν21, are pumped, A1Ì2A''/A2Ì2A'âXÌ2A' transitions to the combination levels of these two modes with the ν8, ν11, and ν12 modes are also observed in the DF spectra due to the Duschinsky mixing. Implications of the present spectroscopic investigation to laser cooling of asymmetric-top molecules are discussed.
RESUMO
In this study, we report the development of an electrically active solid-liquid interface for the evanescent-wave cavity-ring-down spectroscopic (EW-CRDS) technique to enable spectroelectrochemical investigations of redox events. Because of a high-quality transparent conductive electrode film of indium tin oxide (ITO) coated on the interface of total internal reflection of the EW-CRDS platform, a cavity ring-down time of about 900 ns was obtained allowing spectroelectrochemical studies at solid-liquid interfaces. As a proof-of-concept on the capabilities of the developed platform, measurements were performed to address the effects of an applied electric potential to the adsorption behavior of the redox protein cytochrome c (Cyt-C) onto different interfaces, namely, bare-ITO, 3-aminopropyl triethoxysilane (APTES), and Cyt-C antibody. For each interface, the adsorption and desorption constants, the surface equilibrium constant, the Gibbs free energy of adsorption, and the surface coverage were optically measured by our electrically active EW-CRDS tool. Optical measurements at a set of constant discrete values of the applied electric potential were acquired for kinetic adsorption analysis. Cyclic voltammetry (CV) scans under synchronous optical readout were performed to study the effects of each molecular interface on the redox process of surface-adsorbed protein species. Overall, the experimental results demonstrate the ability of the electro-active EW-CRDS platform to unambiguously measure electrode-driven redox events of surface-confined molecular species at low submonolayer coverages and at a single diffraction-limited spot. Such capability is expected to open several opportunities for the EW-CRDS technique to investigate a variety of electrochemical phenomena at solid-liquid interfaces.
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A procedure for timely, accurate, and reproducible alignment of an optical cavity is described.
RESUMO
We report room-temperature cavity ring-down (CRD) spectra of the à â XÌ electronic transition of 1-, 2-, and 3-methylallyl peroxy (MAOOâ¢) radicals produced by 193 nm photolysis of methyl-substituted allyl chlorides in the presence of O2. Vibronic structure of experimentally observed spectra was simulated using calculated relative populations of MAOO⢠conformers, their electronic transition frequencies and oscillator strengths, as well as their vibrational frequencies and Franck-Condon factors of the à â XÌ electronic transition. The reaction intermediate for the production of 1- and 3-MAOO⢠radicals, CH3CHCHCH2, is a resonance-stabilized free radical. CRD spectra of 1- and 3-MAOO⢠radicals obtained using different precursors suggest that allylic rearrangement between the two resonance structures (CH3CH=CHCH2⢠and CH3CHâ¢CH=CH2) is significantly faster than oxygen addition. Branching ratio between terminal and nonterminal oxygen addition was predicted to be 52:48 on the basis of calculated spin densities, which agrees qualitatively with the experimental CRD spectra of 1- and 3-MAOO⢠radicals.
RESUMO
The BÌ-XÌ laser-induced fluorescence (LIF) and dispersed fluorescence (DF) spectra of the atmospherically important ß-monofluoro ethoxy (MFEO), ß,ß-difluoro ethoxy (DFEO), and ß,ß,ß-trifluoro ethoxy (TFEO) radicals were recorded with vibronic resolution under jet-cooled conditions. To simulate the spectra, Franck-Condon factors were obtained from quantum chemical computations carried out at the CAM-B3LYP/6-311++G(d,p) level of theory. The simulations reproduce well both the LIF and DF spectra. Both conformers (G and T) of MFEO and one (G) of the two conformers of DFEO contribute to the LIF spectrum. A comparison between the experimental and calculated spectra confirms the expected long-range field effects of the CHxF3-x group on electronic transition energies and bond strengths, especially in the excited electronic (BÌ) state. Although TFEO has only one conformer, its LIF spectrum is highly congested, which is attributed to the interaction between CO stretch and the -CF3 internal rotation.
RESUMO
Laser-induced fluorescence (LIF) and dispersed fluorescence (DF) spectra of the Ã2E-XÌ2A1 electronic transition of the calcium methoxide (CaOCH3) radical have been obtained under jet-cooled conditions. Complete active space self-consistent field and coupled-cluster calculations on the free radical were performed to aid the assignment of vibronic transitions observed in the LIF/DF spectra. In addition to dominant spectral features that are well reproduced by vibrational frequencies and Franck-Condon (FC) factors calculated ab initio, the FC matrix for the Ã2E-XÌ2A1 electronic transition contains considerable off-diagonal elements that connect (i) the CaO-stretch (ν4) mode and non-CaO stretch modes and (ii) the asymmetric CaOC stretch (ν3) and the CaOC bending (ν8) modes. The Jahn-Teller and pseudo-Jahn-Teller interactions involving the Ã2E state as well as the spin-orbit interaction induce additional vibronic transitions that are not allowed under the Born-Oppenheimer approximation. Additionally, anharmonic vibrational terms in the ground state induce transitions that are forbidden in the harmonic-oscillator approximation. Spin-orbit splitting has been observed for several vibrational levels of the Ã2E state, and an essentially constant value was measured at all levels accessed in the LIF experiment. Implications of the present spectroscopic investigation to the proposed schemes of laser-cooling MOCH3 (M = alkaline earth metals) molecules and detection of time-reversal-symmetry-violating interactions are discussed.
RESUMO
Room-temperature cavity ring-down (CRD) spectra of the à â XÌ electronic transition of tetrahydrofuranyl peroxy (THFOOâ¢) and tetrahydropyranyl peroxy (THPOOâ¢) radicals were recorded. The peroxy radicals were produced by Cl-initiated oxidation of tetrahydrofuran and tetrahydropyran. Quantum chemical calculations of the lowest-energy conformers of all regioisomers of these two peroxy radicals have been carried out to aid the spectral simulation. Conformational identification and vibrational assignment were achieved by comparing the experimentally obtained spectra to the simulated ones. The absence of α-THPOO⢠absorption peaks in the CRD spectrum is attributed to ring opening due to its weak Cα'O bond.