Theoretical and experimental investigations of speckle features based on free-space surface scattering.

Speckle is a significant challenge for laser imaging systems, as it degrades the image quality. In this study, an improved theoretical model is established to describe the speckle features in free-space optical path. The model quantitatively defines the relationship between speckle contrast and five parameters: wavelength, screen surface roughness, light-spot diameter, incidence angle, and observation angle. Subsequently, the theoretical results are experimentally verified. This study enhances the theory of speckle suppression in free-space optical path, and thus enriches the existing speckle suppression theory. The speckle features based on free-space surface-scattered fields have the potential for applications related to non-imaging optics.

Prompt Hole Extraction Suppresses V5+ Dissolution and Sustains Large-Area BiVO4 Photoanodes for Over 2100 h Water Oxidation.

Nanostructured bismuth vanadate (BiVO4) is at the forefront of emerging photoanodes in photoelectrochemical tandem devices for solar water splitting owing to the suitable band edge position and efficient charge separation capability. However, the (photo)chemical corrosion involving V5+ dissolution limits the long-term stability of BiVO4. Herein, guided by DFT calculations, we introduce an ALD-derived NiOx catalyst layer on BiVO4 to stabilize the surface Bi-O bonds, facilitate hole extraction, and thus suppress the V5+ dissolution. At the same time, the ALD NiOx catalyst layer could efficiently suppress the surface recombination and accelerate the surface OER kinetics, boosting the half-cell applied bias photon-to-current efficiency of BiVO4 to 2.05%, as well as a fill factor of 47.1%. By adding trace NaVO3 to the electrolyte, the NiOx/BiVO4 photoanode with an illumination area of 10.5 cm2 shows a record operational stability of more than 2100 h.

Methane removal efficiencies of biochar-mediated landfill soil cover with reduced depth.

Biochar amendment for landfill soil cover has the potential to enhance methane removal efficiency while minimizing the soil depth. However, there is a lack of information on the response of biochar-mediated soil cover to the changes in configuration and operational parameters during the methane transport and transformation processes. This study constructed three biochar-amended landfill soil covers, with reduced soil depths from 75 cm (C2) to 55 cm (C3) and 45 cm (C4), and the control group (C1) with 75 cm and no biochar. Two operation phases were conducted under two soil moisture contents and three inlet methane fluxes in each phase. The methane removal efficiency increased for all columns along with the increase in methane flux. However, increasing moisture content from 10% to 20% negatively influenced the methane removal efficiency due to mass transfer limitation when at a low inlet methane flux, especially for C1; while this adverse effect could be alleviated by a high flux. Except for the condition with low moisture content and flux combination, C3 showed comparable methane removal efficiency to C2, both dominating over C1. As for C4 with only 45 cm, a high moisture content combined with a high methane flux enabled its methane removal efficiency to be competitive with other soil depths. In addition to the geotechnical reasons for gas transport processes, the evolution in methanotroph community structure (mainly type I methanotrophs) induced by biochar amendment and variations in soil properties supplemented the biological reasons for the varying methane removal efficiencies.

Nontarget Insights into the Fate of Cl-/Br-Containing DOM in Leachate during Membrane Treatment.

Halogenated organic compounds in wastewater are persistent and bioaccumulative contaminants of great concern, but few are known at the molecular level. Herein, we focus on nontarget screening of halogenated dissolved organic matter (DOM) in highly concentrated organic matrices of waste leachates and their concentrates. Solid-phase extraction (SPE) was optimized before capturing halogenated signatures via HaloSeeker 2.0 software on mining full-scan high-resolution mass spectrometry (HRMS) fingerprints. This study identified 438 Cl-/Br-containing DOM formulas in 21 leachates and membrane concentrates. Among them, 334 formulas were achieved via SPE with mixed-sorbent cartridges (mixed-SPE), surpassing the 164 formulas achieved through Bond Elut PPL cartridges (PPL-SPE). Herein, only four samples identified via PPL-SPE exhibited a resolution of >50% for extracted Cl-/Br-containing DOM by either SPE. The halogenated DOM constituted 6.87% of the total DOM mass features. Nevertheless, more abundant adsorbable organic halogens deciphered waste leachates and highly concentrated waste streams as reservoirs for halogenated contaminants. Remarkably, 75.7-98.1% of Cl-/Br-containing DOM in primary membrane concentrates remained stable through the secondary membrane treatment, indicating the persistence of these unknown contaminants even post-treatment.

Impacts of digestate-based compost on soil property and nutrient availability.

The treatment of digestate from food waste (DFW) has emerged as the bottleneck for food waste anaerobic digestion. DFW generally contains abundant nutrients that can be recycled by composting. However, the effect of DFW-based compost on soil improvement has not been extensively explored. In this study, soil properties were improved by adding various amounts of DFW-based compost, and the growth conditions of Pak choi were monitored. The results indicated that the DFW-based compost could provide nitrogen, calcium, magnesium, and organic matter, thereby enhancing the growth of Pak choi, accumulating chlorophyll, and improving photosynthesis efficiency. As the amount of added DFW-based compost increased from 0% to 20%, the fresh biomass, leaf weight, and root weight of Pak choi increased by 242%, 262%, and 99%, respectively. The total chlorophyll content was 2.62 mg g-1 in control and increased to 12.45 mg g-1 in the group with 20% DFW-based compost, benefiting the photochemical efficiency of Pak choi. However, the growth was inhibited when the addition amount exceeded 20%, potentially due to excessive nutrient supplementation. Overall, the addition of 20% of DFW-based compost was suggested to promote the growth of Pak choi by providing proper nutrients.

Recent advances in structural engineering of photocatalysts for environmental remediation.

Photocatalysis appears to be an appealing approach for environmental remediation including pollutants degradation in water, air, and/or soil, due to the utilization of renewable and sustainable source of energy, i.e., solar energy. However, their broad applications remain lagging due to the challenges in pollutant degradation efficiency, large-scale catalyst production, and stability. In recent decades, massive efforts have been devoted to advance the photocatalysis technology for improved environmental remediation. In this review, the latest progress in this aspect is overviewed, particularly, the strategies for improved light sensitivity, charge separation, and hybrid approaches. We also emphasize the low efficiency and poor stability issues with the current photocatalytic systems. Finally, we provide future suggestions to further enhance the photocatalyst performance and lower its large-scale production cost. This review aims to provide valuable insights into the fundamental science and technical engineering of photocatalysis in environmental remediation.

Dissecting contributions of representative heavy metal components in PM2.5 to its cytotoxicity.

PM2.5 is a complex pollutant that is a pervasive threat to human health. The health risks and toxicity mechanisms of PM2.5 components must be identified to alleviate the corresponding risks. In this study, a reductionism approach based on model PM2.5 particles was used to investigate the contributions of the most harmful components in PM2.5 to its toxicity. Human liver and kidney cells were used as models. The results showed that Cr(VI) was the most critical toxic component among other components (Pb, As, and benzo[a]pyrene) in human liver and kidney cells. PM2.5-Cr(VI) induced oxidative stress, which led to cytotoxicity by inducing cell cycle arrest in the S-phase in HepG2 and HEK293 cells. The presented findings can provide valuable insights into the toxicity levels of PM2.5 components, which can help clarify the potential health risks from PM2.5 exposure.

Isolation and characterization of quorum quenching bacteria from municipal solid waste and bottom ash co-disposal landfills.

Co-landfilling of bottom ash (BA) accelerates the clogging of leachate collection systems (LCSs) and increases the risk of landfill failure. The clogging was mainly associated with bio-clogging, which may be reduced by quorum quenching (QQ) strategies. This communication reports on a study of how isolated facultative QQ bacterial strains from municipal solid waste (MSW) landfills and BA co-disposal landfills. In MSW landfills, two novel QQ strains (Brevibacillus agri and Lysinibacillus sp. YS11) can degrade the signal molecule hexanoyl-l-homoserine lactone (C6-HSL) and octanoyl-l-homoserine lactone (C8-HSL), respectively. Pseudomonas aeruginosa could degrade C6-HSL and C8-HSL in BA co-disposal landfills. Moreover, P. aeruginosa (0.98) was observed with a higher growth rate (OD600) compared to that of B. agri (0.27) and Lysinibacillus sp. YS11 (0.53). These results indicated that the QQ bacterial strains were associated with leachate characteristics and signal molecules and could be used for controlling bio-clogging in landfills.

The efficiency and mechanism of humidity in alleviating CO2 inhibition on H2S adsorption to straw biochars.

Adsorption tests were conducted to clarify the impact of carbon dioxide (CO2) on hydrogen sulfide (H2S) removal to straw biochars and the role of humidity in affecting the CO2 impact. When straw biochars were dry, CO2 proved significantly detrimental to their H2S adsorption, regardless of the CO2 contents. In contrast, when adjusting the humidity of the biochars to 20%, the presence of CO2 promoted the conversion of H2S into sulfites, though still inhibited the generation of elemental sulfur, through which the original negative CO2 impact was nearly compensated. The presence of low to medium contents of CO2 even slightly improved the adsorption capacity and extended the breakthrough time. This phenomenon was ascribed to a favorable carbon surface environment for H2S dissociation and oxidation, created from the reactions of the major minerals (Ca and Mg) with CO2 and water. To sum up, the CO2 inhibition on the H2S adsorption to biochars was ascribed to the competition of CO2 for the active sites; however, humidity induced a series of CO2-participated chemical reactions between H2S and the minerals, sufficiently alleviating the CO2 inhibition. The results also highlight the necessity to recognize the most critical biochar properties or an efficient balance of crucial biochar properties in achieving an optimal H2S removal when CO2 is present in the syngas.

Quantification and control of gaseous emissions from solid waste landfill surfaces.

Landfilling is the most common option for solid waste disposal worldwide. Landfill sites can emit significant quantities of greenhouse gases (GHGs; e.g., methane, carbon dioxide, and nitrous oxide) and release toxic and odorous compounds (e.g., sulfides). Due to the complex composition and characteristics of landfill surface gas emissions, the quantification and control of landfill emissions are challenging. This review attempts to comprehensively understand landfill emission quantification and control options by primarily focusing on GHGs and odor compounds. Landfill emission quantification was highlighted by combining different emissions monitoring approaches to improve the quality of landfill emission data. Also, landfill emission control requires a specific approach that targets emission compounds or a systematic approach that reduces overall emissions by combining different control methods since the diverse factors dominate the emissions of various compounds and their transformation. This integrated knowledge of emission quantification and control options for GHGs and odor compounds is beneficial for establishing field monitoring campaigns and incorporating mitigation strategies to quantify and control multiple landfill emissions.

Coupled effect of microbiologically induced calcium carbonate and biofilms in leachate.

Fouling and clogging are persistent challenges to the collection and treatment of leachate. The main components of fouling and clogging are calcium carbonate (CaCO3) and biofilms. However, the relationships between CaCO3 and biofilms remain to be clarified. In this study, the interaction between microbially induced CaCO3 precipitation (MICP) and biofilms was investigated using Luria-Bertani (LB) or urea media. Results showed that the bacteria promoted the precipitation of CaCO3 and the formation of a complex mixture of biofilms. The amount of formed CaCO3 in the urea medium was 12.9 times of that in the LB medium. The high MICP potential in the urea medium was associated with increased pH and alkalinity. In addition, the clogging materials exhibited a layered structure and uneven distribution over the clogging width and depth profile. These results indicated the presence of nucleation sites of CaCO3 on the surface of and inside the bacteria. This research provides insights into the regulation of MICP and biofilms through dynamic control of clogging and fouling.

Investigation of speckle suppression beyond human eye sensitivity by using a passive multimode fiber and a multimode fiber bundle.

A method of speckle suppression without any active device is expected for pico-projectors. The effectiveness of the passive method of speckle reduction using a single multimode fiber and a multimode fiber bundle was actually measured and theoretically analyzed. The dependences of the speckle contrast and speckle suppression coefficient on the parameters of multimode fiber and projection systems were investigated. Our results shown that the efficiency of speckle suppression was limited because only the radial direction of the objective lens aperture was used. An improvement using both of the radial and azimuthal directions of the objective lens aperture is required.

A label-free lead(II) ion sensor based on surface plasmon resonance and DNAzyme-gold nanoparticle conjugates.

Detection of lead(II) (Pb2+) ions in water is important for the protection of human health and environment. The growing demand for onsite detection still faces challenges for sensitive and easy-to-use methods. In this work, a novel surface plasmon resonance (SPR) biosensor based on GR-5 DNAzyme and gold nanoparticles (AuNPs) was developed. Thiolated DNAzyme was immobilized on the gold surface of the sensor chip followed by anchoring the substrate-functionalized AuNPs through the DNAzyme-substrate hybridization. The coupling between the localized surface plasmon (LSP) of AuNPs and the surface plasmon polaritons (SPP) on the gold sensor surface was used to improve the sensitivity. The substrate cleavage in the presence of Pb2+ ions was catalyzed by DNAzyme, leading to the removal of AuNPs and the diminished LSP-SPP coupling. The optimal detection limit was 80 pM for the sensor fabricated with 1 µM DNAzyme, corresponding to two or three orders of magnitude lower than the toxicity levels of Pb2+ in drinking water defined by WHO and USEPA. By tuning the surface coverage of DNAzyme, the sensitivity and dynamic range could be controlled. This sensor also featured high selectivity to Pb2+ ions and simple detection procedure. Successful detection of Pb2+ ions in groundwater indicates that this method has the prospect in the onsite detection of Pb2+ ions in water. Given the variety of AuNPs and metal-specific DNAzymes, this detection strategy would lead to the development of more sensitive and versatile heavy metal sensors. Graphical abstract.

Anisotropy estimation of compacted municipal solid waste using pressurized vertical well liquids injection.

Waste hydraulic conductivity and anisotropy represent two important parameters controlling fluid movement in landfills, and thus are the key inputs in design methods where predictions of moisture movement are necessary. Although municipal waste hydraulic conductivity has been estimated in multiple laboratory and field studies, measurements of anisotropy, particularly at full scale, are rare, even though landfilled municipal waste is generally understood to be anisotropic. Measurements from a buried liquids injection well surrounded by pressure transducers at a full-scale landfill in Florida were collected and examined to provide an estimate of in-situ waste anisotropy. Liquids injection was performed at a constant pressure and the resulting pore pressures in the surrounding waste were monitored. Numerical fluid flow modeling was employed to simulate the pore pressures expected to occur under the conditions operated. Nine different simulations were performed at three different lateral hydraulic conductivity values and three different anisotropy values. Measured flowrate and pore pressures collected from conditions of approximate steady state were compared with the simulation results to assess the range of anisotropies. The results support that compacted municipal waste in landfills is anisotropic, provide anisotropy estimates greater than previous measurements, and suggest that anisotropy decreases with landfill depth.

Predicting maturity and identifying key factors in organic waste composting using machine learning models.

The measurement of germination index (GI) in composting is a time-consuming and laborious process. This study employed four machine learning (ML) models, namely Random Forest (RF), Artificial Neural Network (ANN), Support Vector Regression (SVR), and Decision Tree (DT), to predict GI based on key composting parameters. The prediction results showed that the coefficient of determination (R2) for RF (>0.9) and ANN (>0.9) was higher than SVR (<0.6) and DT (<0.8), suggesting that RF and ANN displayed superior predictive performance for GI. The SHapley additive exPlanations value result indicated that composting time, temperature, and pH were the important features contributing to GI. Composting time was found to have the most significant impact on GI. Overall, RF and ANN were suggested as effective tools for predicting GI in composting. This study offers the reliable approach of accurately predicting GI in composting processes, thereby enabling intelligent composting practices.

Assessing the aging and environmental implications of polyethylene mulch films in agricultural land.

Polyethylene mulch films (MFs) are widely employed in agricultural land to enhance crop yield and quality, but the MF residue causes significant environmental concerns. To promote the sustainable application of MFs, it is essential to assess their fate throughout their service life and understand the underlying degradation mechanisms. In this study, surface-exposed and soil-buried MFs were separately collected from agricultural land in Inner Mongolia, China. The variations in aging performance and corresponding property alterations of MF were thoroughly examined. The results indicated that sunlight exposure considerably hastens MF degradation, whereas buried MFs experience a more moderate aging process due to the inhibitory effects of the dark and anaerobic environment on oxidation. Surface cracking was observed in MF-Light samples as a result of photodegradation, while chemical and moisture interactions with soil caused partial perforation in MF-Soil samples. Relative to the pristine MF, the oxidation, unsaturation, and hydroxylation levels of MF-Light increased to 0.88, 0.35, and 0.73, respectively, with corresponding values for MF-Soil at 0.44, 0.13, and 0.24. The generated oxygen-containing functional groups lead to a decrease in contact angles of MF-Light and MF-Soil, enhancing their hydrophilicity. The aging process of MFs led to a decline in mechanical properties, posing challenges for recycling. Moreover, nearly all phthalate esters (PAEs) were released from MFs, regardless of sunlight exposure or soil burial. The use of MFs also impacted the abundance of soil microbial communities. Specifically, the selected polyethylene MF enriched Actinobacteriota by 75%, while reducing Chloroflexi and Firmicutes by 27% and 45%, respectively.

Hydrothermal-enhanced pyrolysis for efficient NOX reduction and biochar valorization from food waste digestate.

Pyrolysis has emerged as a promising technology for valorizing digestate resulting from the anaerobic digestion of food waste. However, the high NOX emissions during pyrolysis limit its application. This study proposed a hydrothermal coupled pyrolysis process to control the element transfer in digestate during biochar production. The efficient reduction of NOX emissions and the improvement of biochar adsorbability were realized. The hydrothermal process reduced the nitrogen content in solid digestate by 49.10 %-81.79 %, thus reducing the NOX precursors in syngas and the N-containing substances in bio-oil. Additionally, the specific surface area and the total pore volume of biochar were enhanced from 25 m2/g to 60-73 m2/g and 0.06 cm3/g to 0.12-0.14 cm3/g, respectively. More defects, oxygen-containing functional groups, and doped Ca on the biochar resulted in a high phosphate removal efficiency of 94 %. The proposed technology provides an efficient and environmentally friendly way to utilize the digestate.

Manipulating soil microbial community assembly by the cooperation of exogenous bacteria and biochar for establishing an efficient and healthy CH4 biofiltration system.

Manipulating the methanotroph (MOB) composition and microbial diversity is a promising strategy to optimize the methane (CH4) biofiltration efficiency of an engineered landfill cover soil (LCS) system. Inoculating soil with exogenous MOB-rich bacteria and amending soil with biochar show strong manipulating potential, but how the two stimuli interactively shape the microbial community structure and diversity has not been clarified. Therefore, three types of soils with active CH4 activities, including paddy soil, river wetland soil, and LCS were selected for enriching MOB-dominated communities (abbreviated as B_PS, B_RWS, and B_LCS, respectively). They were then inoculated to LCS which was amended with two distinct biochar. Besides the aerobic CH4 oxidation efficiencies, the evolution of the three microbial communities during the MOB enrichment processes and their colonization in two-biochar amended LCS were obtained. During the MOB enriching, a lag phase in CH4 consumption was observed merely for B_LCS. Type II MOB Methylocystis was the primary MOB for both B_PS and B_LCS; while type I MOB dominated for B_RWS and the major species were altered by gas concentrations. Compared to biochar, a more critical role was demonstrated for the bacteria inoculation in determining the community diversity and function of LCS. Instead, biochar modified the community structures by mainly stimulating the dominant MOB but could induce stochastic processes in community assembly, possibly related to its inorganic nutrients. Particularly, combined with biochar advantages, the paddy soil-derived bacteria consortiums with diverse MOB species demonstrated the potent adaption to LCS niches, not only retaining the high CH4-oxidizing capacities but also shaping a community structure with more diverse soil function. The results provided new insights into the optimization of an engineered CH4-mitigation soil system by manipulating the soil microbiomes with the cooperation of exogenous bacteria and biochar.

Enhancing methane production from food waste with iron-carbon micro-electrolysis in a two-stage process.

A two-stage process, consisting of a leach-bed reactor (LBR) and an up-flow anaerobic sludge blanket reactor (UASB), has been commonly adopted to improve food waste anaerobic digestion. However, its application is limited due to low hydrolysis and methanogenesis efficiencies. This study proposed a strategy of incorporating iron-carbon micro-electrolysis (ICME) into the UASB and recirculating its effluent to the LBR to improve the two-stage process efficiency. Results showed that the integration of the ICME with the UASB significantly increased the CH4 yield by 168.29%. The improvement of the food waste hydrolysis in the LBR mainly contributed to the enhanced CH4 yield (approximately 94.5%). The enrichment of hydrolytic-acidogenic bacterial activity, facilitated by the Fe2+ generated through ICME, might be the primary cause of the improved food waste hydrolysis. Moreover, ICME enriched the growth of hydrogenotrophic methanogens and stimulated the hydrogenotrophic methanogenesis pathway in the UASB, contributing partially to the enhanced CH4 yield.

Different Fenton treatments on diverse landfill organics: Discover the underestimated effect of derived-DOM.

Fenton is one of the most promising processes for the removal of dissolved organic matter (DOM). It has always been highly suspected that derived-DOM would be generated during Fenton reaction, but there is lack of direct evidence at the molecular level. The present study explored the molecular properties of the derived-DOM of five common Fenton technologies for degradation of nine landfill organics including leachates and concentrates based on UPLC Orbitrap MS/MS analysis. The comparative results confirmed that DOM derivation was essential for Fenton technologies, with the DOM derivation rate as high as 17.3%-70.3%. The derived-DOM are dominated by trace organic contaminants (CHON-DOM), and typical new contaminants (PPCPs, flavors, etc.). Heterogeneous Fenton had significantly lesser derived-DOM (35.1% ± 16.9%) than other Fenton technologies. Among all landfill organics, medium leachate was most likely to derive DOM (51.4% ± 13.9%), while unexpectedly old leachate had the lowest derivation rate (32.0% ± 5.3%). In the overall membrane treatment process, the secondary membrane concentrate is more susceptible to DOM derivation (43.4% ± 5.5%-49.6% ± 3.8%) than the primary membrane concentrate (40.7% ± 14.1%), and the elements and subcategories composition and molecular property indexes of the derived-DOM become more complex. On the contrary, the DOM derivatization rate of the biological treatment effluent after Fenton treatment was much lower than that of the various concentrates after Fenton treatment and the molecular property are simpler. Therefore, Fenton may replace the membrane process directly as a deep treatment process after biological treatment of landfill leachate. These information would help the selection and application of Fenton technologies.