Oxocarbon Anions Templated in Silver Clusters.

Three types of oxocarbon anions as templates were used to synthesize high-nuclear silver clusters, [Ag16(C2O4){S2P(OEt)2}12]2(PF6)4 (1), [Ag16(C4O4){S2P(OEt)2}12]2(PF6)4 (2), and [Ag32(S)2(C5O5)2{S2P(OEt)2}22](PF6)2 (3), and characterized by multi-NMR spectroscopy and X-ray crystallography. As the template size increases, the shape and size of the clusters change accordingly. The template effect in high-nuclear silver clusters has been investigated in this work.