Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 3 de 3
Filtrar
Mais filtros

Base de dados
Ano de publicação
Tipo de documento
Intervalo de ano de publicação
1.
Chem Commun (Camb) ; 60(74): 10172-10175, 2024 Sep 12.
Artigo em Inglês | MEDLINE | ID: mdl-39190499

RESUMO

Here, we successfully synthesized a pair of enantiomeric molecular piezoelectric materials by H/F substitution strategy. These compounds show a large piezoelectric coefficient d33 value of 25 pC N-1 measured by the quasi-static method. A simple energy harvesting device was fabricated based on this crystal, showing great potential in piezoelectric mechanical energy harvesters.

2.
Chempluschem ; 89(10): e202400386, 2024 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-39031624

RESUMO

Ferroelastic materials with high phase transition temperature have broad application prospects in information conversion and storage, shape memory, energy conversion, hyperelasticity, etc. However, most of the current reports focus on inorganic ferroelastic materials. Inorganic ferroelastic materials have the disadvantages of high energy consumption and harmful metals, which limit their application in practical work. In contrast, organic ferroelastic materials have the advantages of structural adjustability, environmental protection, easy processing, low cost, mechanical flexibility, and so on, which have great development potential in new ferroelastic materials. Here, we have successfully designed and synthesized a pair of homochiral enantiomers [(R/S)-4-fluorobenzoic acid-2-amino-2-phenylethanol] (R- and S-F) using the chemical design strategy of H/F substitution. Compared with the non-F substitution [(R/S)-benzoic acid-2-amino-2-phenylethanol] (R- and S-H), they undergo 2F1-type ferroelastic phase transitions at 370 K. Notably, the ferroelastic domains of R/S-F can be controlled through two physical channels that are temperature and stress, showing great potential in dual-channel switches.

3.
Chem Commun (Camb) ; 60(32): 4322-4325, 2024 Apr 16.
Artigo em Inglês | MEDLINE | ID: mdl-38535993

RESUMO

Here, we synthesized a series of cholesteryl-based compounds, whose phases and their transformation can be modulated by temperature and the chain length of the fluoroalkyl moieties. To our knowledge, this is the first time that the phase transition could be modulated with perfluoroalkyl tail engineering in organic single-component ferroelectric crystals.

SELEÇÃO DE REFERÊNCIAS
DETALHE DA PESQUISA