Diode effect in Josephson junctions with a single magnetic atom.

Current flow in electronic devices can be asymmetric with bias direction, a phenomenon underlying the utility of diodes1 and known as non-reciprocal charge transport2. The promise of dissipationless electronics has recently stimulated the quest for superconducting diodes, and non-reciprocal superconducting devices have been realized in various non-centrosymmetric systems3-10. Here we investigate the ultimate limits of miniaturization by creating atomic-scale Pb-Pb Josephson junctions in a scanning tunnelling microscope. Pristine junctions stabilized by a single Pb atom exhibit hysteretic behaviour, confirming the high quality of the junctions, but no asymmetry between the bias directions. Non-reciprocal supercurrents emerge when inserting a single magnetic atom into the junction, with the preferred direction depending on the atomic species. Aided by theoretical modelling, we trace the non-reciprocity to quasiparticle currents flowing by means of electron-hole asymmetric Yu-Shiba-Rusinov states inside the superconducting energy gap and identify a new mechanism for diode behaviour in Josephson junctions. Our results open new avenues for creating atomic-scale Josephson diodes and tuning their properties through single-atom manipulation.

High-temperature Josephson diode.

Many superconducting systems with broken time-reversal and inversion symmetry show a superconducting diode effect, a non-reciprocal phenomenon analogous to semiconducting p-n-junction diodes. While the superconducting diode effect lays the foundation for realizing ultralow dissipative circuits, Josephson-phenomena-based diode effect (JDE) can enable the realization of protected qubits. The superconducting diode effect and JDE reported thus far are at low temperatures (~4 K), limiting their applications. Here we demonstrate JDE persisting up to 77 K using an artificial Josephson junction of twisted layers of Bi2Sr2CaCu2O8+δ. JDE manifests as an asymmetry in the magnitude and distributions of switching currents, attaining the maximum at 45° twist. The asymmetry is induced by and tunable with a very small magnetic field applied perpendicular to the junction and arises due to interaction between Josephson and Abrikosov vortices. We report a large asymmetry of 60% at 20 K. Our results provide a path towards realizing superconducting Josephson circuits at liquid-nitrogen temperature.

Robust Spectral π Pairing in the Random-Field Floquet Quantum Ising Model.

Motivated by an experiment on a superconducting quantum processor [X. Mi et al., Science 378, 785 (2022).SCIEAS0036-807510.1126/science.abq5769], we study level pairings in the many-body spectrum of the random-field Floquet quantum Ising model. The pairings derive from Majorana zero and π modes when writing the spin model in Jordan-Wigner fermions. Both splittings have log-normal distributions with random transverse fields. In contrast, random longitudinal fields affect the zero and π splittings in drastically different ways. While zero pairings are rapidly lifted, the π pairings are remarkably robust, or even strengthened, up to vastly larger disorder strengths. We explain our results within a self-consistent Floquet perturbation theory and study implications for boundary spin correlations. The robustness of π pairings against longitudinal disorder may be useful for quantum information processing.

Non-Abelian Holonomy of Majorana Zero Modes Coupled to a Chaotic Quantum Dot.

If a quantum dot is coupled to a topological superconductor via tunneling contacts, each contact hosts a Majorana zero mode in the limit of zero transmission. Close to a resonance and at a finite contact transparency, the resonant level in the quantum dot couples the Majorana modes, but a ground-state degeneracy per fermion parity subspace remains if the number of Majorana modes coupled to the dot is five or larger. Upon varying shape-defining gate voltages while remaining close to resonance, a nontrivial evolution within the degenerate ground-state manifold is achieved. We characterize the corresponding non-Abelian holonomy for a quantum dot with chaotic classical dynamics using random matrix theory and discuss measurable signatures of the non-Abelian time evolution.

Resistivity Tensor of Vortex-Lattice States in Josephson Junction Arrays.

Two-dimensional Josephson junction arrays frustrated by a perpendicular magnetic field are predicted to form a cascade of distinct vortex lattice states. Here, we show that the resistivity tensor provides both structural and dynamical information on the vortex-lattice states and intervening phase transitions, which allows for experimental identification of these symmetry-breaking ground states. We illustrate our general approach by a microscopic theory of the resistivity tensor for a range of magnetic fields exhibiting a rich set of vortex lattices as well as transitions to liquid-crystalline vortex states.

Diode Effects in Current-Biased Josephson Junctions.

Current-biased Josephson junctions exhibit hysteretic transitions between dissipative and superconducting states as characterized by switching and retrapping currents. Here, we develop a theory for diodelike effects in the switching and retrapping currents of weakly damped Josephson junctions. We find that while the diodelike behavior of switching currents is rooted in asymmetric current-phase relations, nonreciprocal retrapping currents originate in asymmetric quasiparticle currents. These different origins also imply distinctly different symmetry requirements. We illustrate our results by a microscopic model for junctions involving a single magnetic atom. Our theory provides significant guidance in identifying the microscopic origin of nonreciprocities in Josephson junctions.

Andreev Reflection in Scanning Tunneling Spectroscopy of Unconventional Superconductors.

We evaluate the differential conductance measured in an STM setting at arbitrary electron transmission between STM tip and a 2D superconductor with arbitrary gap structure. Our analytical scattering theory accounts for Andreev reflections, which become prominent at larger transmissions. We show that this provides complementary information about the superconducting gap structure beyond the tunneling density of states, strongly facilitating the ability to extract the gap symmetry and its relation to the underlying crystalline lattice. We use the developed theory to discuss recent experimental results on superconductivity in twisted bilayer graphene.

Anderson's Theorem for Correlated Insulating States in Twisted Bilayer Graphene.

The emergence of correlated insulating phases in magic-angle twisted bilayer graphene exhibits strong sample dependence. Here, we derive an Anderson theorem governing the robustness against disorder of the Kramers intervalley coherent (K-IVC) state, a prime candidate for describing the correlated insulators at even fillings of the moiré flat bands. We find that the K-IVC gap is robust against local perturbations, which are odd under PT, where P and T denote particle-hole conjugation and time reversal, respectively. In contrast, PT-even perturbations will in general induce subgap states and reduce or even eliminate the gap. We use this result to classify the stability of the K-IVC state against various experimentally relevant perturbations. The existence of an Anderson theorem singles out the K-IVC state from other possible insulating ground states.

Tuning a Two-Impurity Kondo System by a Moiré Superstructure.

Two-impurity Kondo models are paradigmatic for correlated spin-fermion systems. Working with Mn atoms on Au(111) covered by a monolayer of MoS_{2}, we tune the interadatom exchange via the adatom distance and the adatom-substrate exchange via the location relative to a moiré structure of the substrate. Differential-conductance measurements on isolated adatoms exhibit Kondo peaks with heights depending on the adatom location relative to the moiré structure. Mn dimers spaced by a few atomic lattice sites exhibit split Kondo resonances. In contrast, adatoms in closely spaced dimers couple antiferromagnetically, resulting in a molecular-singlet ground state. Exciting the singlet-triplet transition by tunneling electrons, we find that the singlet-triplet splitting is surprisingly sensitive to the moiré structure. We interpret our results theoretically by relating the variations in the singlet-triplet splitting to the heights of the Kondo peaks of single adatoms, finding evidence for coupling of the adatom spin to multiple conduction electron channels.

Quantum Magnetism and Topological Superconductivity in Yu-Shiba-Rusinov Chains.

Chains of magnetic adatoms on superconductors have been discussed as promising systems for realizing Majorana end states. Here, we show that dilute Yu-Shiba-Rusinov (YSR) chains are also a versatile platform for quantum magnetism and correlated electron dynamics, with widely adjustable spin values and couplings. Focusing on subgap excitations, we derive an extended t-J model for dilute quantum YSR chains and use it to study the phase diagram as well as tunneling spectra. We explore the implications of quantum magnetism for the formation of a topological superconducting phase, contrasting it to existing models assuming classical spin textures.

Moiré Tuning of Spin Excitations: Individual Fe Atoms on MoS_{2}/Au(111).

Magnetic adatoms on properly designed surfaces constitute exquisite systems for addressing, controlling, and manipulating single quantum spins. Here, we show that monolayers of MoS_{2} on a Au(111) surface provide a versatile platform for controllably tuning the coupling between adatom spins and substrate electrons. Even for equivalent adsorption sites with respect to the atomic MoS_{2} lattice, we observe that Fe adatoms exhibit behaviors ranging from pure spin excitations, characteristic of negligible exchange and dominant single-ion anisotropy, to a fully developed Kondo resonance, indicating strong exchange and negligible single-ion anisotropy. This tunability emerges from a moiré structure of MoS_{2} on Au(111) in conjunction with pronounced many-body renormalizations. We also find striking spectral variations in the immediate vicinity of the Fe atoms, which we explain by quantum interference reflecting the formation of Fe-S hybrid states despite the nominally inert nature of the substrate. Our work establishes monolayer MoS_{2} as a tuning layer for adjusting the quantum spin properties over an extraordinarily broad parameter range. The considerable variability can be exploited for quantum spin manipulations.

Hilbert Space Geometry of Random Matrix Eigenstates.

The geometry of multiparameter families of quantum states is important in numerous contexts, including adiabatic or nonadiabatic quantum dynamics, quantum quenches, and the characterization of quantum critical points. Here, we discuss the Hilbert space geometry of eigenstates of parameter-dependent random matrix ensembles, deriving the full probability distribution of the quantum geometric tensor for the Gaussian unitary ensemble. Our analytical results give the exact joint distribution function of the Fubini-Study metric and the Berry curvature. We discuss relations to Levy stable distributions and compare our results to numerical simulations of random matrix ensembles as well as electrons in a random magnetic field.

Yu-Shiba-Rusinov States in the Charge-Density Modulated Superconductor NbSe2.

NbSe2 is a remarkable superconductor in which charge-density order coexists with pairing correlations at low temperatures. Here, we study the interplay of magnetic adatoms and their Yu-Shiba-Rusinov (YSR) bound states with the charge density order. Exploiting the incommensurate nature of the charge-density wave (CDW), our measurements provide a thorough picture of how the CDW affects both the energies and the wave functions of the YSR states. Key features of the dependence of the YSR states on adsorption site relative to the CDW are explained by model calculations. Several properties make NbSe2 a promising substrate for realizing topological nanostructures. Our results will be important in designing such systems.

Quantum Hall Response to Time-Dependent Strain Gradients in Graphene.

Mechanical deformations of graphene induce a term in the Dirac Hamiltonian that is reminiscent of an electromagnetic vector potential. Strain gradients along particular lattice directions induce local pseudomagnetic fields and substantial energy gaps as indeed observed experimentally. Expanding this analogy, we propose to complement the pseudomagnetic field by a pseudoelectric field, generated by a time-dependent oscillating stress applied to a graphene ribbon. The joint Hall-like response to these crossed fields results in a strain-induced charge current along the ribbon. We analyze in detail a particular experimental implementation in the (pseudo)quantum Hall regime with weak intervalley scattering. This allows us to predict an (approximately) quantized Hall current that is unaffected by screening due to diffusion currents.

Interfering Tunneling Paths through Magnetic Molecules on Superconductors: Asymmetries of Kondo and Yu-Shiba-Rusinov Resonances.

Magnetic adsorbates on superconductors induce a Kondo resonance outside and Yu-Shiba-Rusinov (YSR) bound states inside the superconducting energy gap. When probed by scanning tunneling spectroscopy, the associated differential-conductance spectra frequently exhibit characteristic bias-voltage asymmetries. Here, we observe correlated variations of Kondo and YSR asymmetries across an Fe-porphyrin molecule adsorbed on Pb(111). We show that both asymmetries originate in interfering tunneling paths via a spin-carrying orbital and the highest occupied molecular orbital (HOMO). Strong evidence for this model comes from nodal planes of the HOMO, where tunneling reveals symmetric Kondo and YSR resonances. Our results establish an important mechanism for the asymmetries of Kondo and YSR line shapes.

Universal Scaling Theory of the Boundary Geometric Tensor in Disordered Metals.

We investigate the finite-size scaling of the boundary quantum geometric tensor (QGT) numerically close to the Anderson localization transition in the presence of small external magnetic fields. The QGT exhibits universal scaling and reveals the crossover between the orthogonal and unitary critical states in weak random magnetic fields. The flow of the QGT near the critical points determines the critical exponents. Critical distributions of the QGT are universal and exhibit a remarkable isotropy even in a homogeneous magnetic field. We predict universal and isotropic Hall conductance fluctuations at the metal-insulator transition in an external magnetic field.

Landauer-Büttiker Approach to Strongly Coupled Quantum Thermodynamics: Inside-Outside Duality of Entropy Evolution.

We develop a Landauer-Büttiker theory of entropy evolution in time-dependent, strongly coupled electron systems. The formalism naturally avoids the problem of the system-bath distinction by defining the entropy current in the attached leads. This current can then be used to infer changes of the entropy of the system which we refer to as the inside-outside duality. We carry out this program in an adiabatic expansion up to first order beyond the quasistatic limit. When combined with particle and energy currents, as well as the work required to change an external potential, our formalism provides a full thermodynamic description, applicable to arbitrary noninteracting electron systems in contact with reservoirs. This provides a clear understanding of the relation between heat and entropy currents generated by time-dependent potentials and their connection to the occurring dissipation.

Wave-Function Hybridization in Yu-Shiba-Rusinov Dimers.

Magnetic adsorbates on superconductors induce local bound states within the superconducting gap. These Yu-Shiba-Rusinov (YSR) states decay slowly away from the impurity compared to atomic orbitals, even in 3D bulk crystals. Here, we use scanning tunneling spectroscopy to investigate their hybridization between two nearby magnetic Mn adatoms on a superconducting Pb(001) surface. We observe that the hybridization leads to the formation of symmetric and antisymmetric combinations of YSR states. We investigate how the structure of the dimer wave functions and the energy splitting depend on the shape of the underlying monomer orbitals and the orientation of the dimer with respect to the Pb lattice.

Tuning the Coupling of an Individual Magnetic Impurity to a Superconductor: Quantum Phase Transition and Transport.

The exchange scattering at magnetic adsorbates on superconductors gives rise to Yu-Shiba-Rusinov (YSR) bound states. Depending on the strength of the exchange coupling, the magnetic moment perturbs the Cooper pair condensate only weakly, resulting in a free-spin ground state, or binds a quasiparticle in its vicinity, leading to a (partially) screened spin state. Here, we use the flexibility of Fe-porphin (FeP) molecules adsorbed on a Pb(111) surface to reversibly and continuously tune between these distinct ground states. We find that the FeP moment is screened in the pristine adsorption state. Approaching the tip of a scanning tunneling microscope, we exert a sufficiently strong attractive force to tune the molecule through the quantum phase transition into the free-spin state. We ascertain and characterize the transition by investigating the transport processes as function of tip-molecule distance, exciting the YSR states by single-electron tunneling as well as (multiple) Andreev reflections.