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Poly[dichloridobis(µ(2)-di-4-pyridyl sulfide-κN,N')cobalt(II)].
Wang, Jian-Ge; Qin, Jian-Hua; Zhang, Gui-Ying.
Afiliação
  • Wang JG; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online ; 65(Pt 3): m247, 2009 Feb 04.
Article em En | MEDLINE | ID: mdl-21582041
In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa-hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra-molecular C-H⋯N and C-H⋯Cl hydrogen bonds.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2009 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2009 Tipo de documento: Article