Poly[dichloridobis(µ(2)-di-4-pyridyl sulfide-κN,N')cobalt(II)].
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 3): m247, 2009 Feb 04.
Article
em En
| MEDLINE
| ID: mdl-21582041
In the title compound, [CoCl(2)(C(10)H(8)N(2)S)(2)](n), the Co(II) atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octa-hedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the Co(II) centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intra-molecular C-Hâ¯N and C-Hâ¯Cl hydrogen bonds.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2009
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Article