(Acetyl-acetonato-κ(2)O,O')carbon-yl[tris-(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate.

ABSTRACT

The title compound, [Rh(C(5)H(7)O(2))(C(30)H(21)P)(CO)]·0.5C(3)H(6)O, has two different complex molecules in the asymmetric unit, with the Rh(I) atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.