trans-Dichloridobis[dicyclo-hex-yl(phen-yl)phosphane-κP]palladium(II).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 4): m404, 2012 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-22589787
ABSTRACT
The title compound, [PdCl(2){P(C(6)H(11))(2)(C(6)H(5))}(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3343â
(5)â
Å, as the Pd atom lies on an inversion centre, while the Pd-Cl bond lengths are 2.3017â
(4)â
Å. The observed structure was found to be closely related to [PdCl(2){P(C(6)H(11))(3)}(2)] [Grushin et al. (1994 â¶). Inorg. Chem.33, 4804-4806], [PdBr(2){P(C(6)H(11))(3)}(2)] [Clarke et al. (2003 â¶). Dalton Trans. pp. 4393-4394] and [PdCl(2)P(C(6)H(11))(2)(C(7)H(7))}(2)] [Vuoti et al. (2008 â¶). Eur. J. Inorg. Chem. pp. 397-407] (C(6)H(11) is cyclo-hexyl and C(7)H(7) is o-tol-yl). One of the cyclo-hexyl rings is disordered with the phenyl ring in a 0.587â
(9)413â
(9) ratio. Five long-range C-Hâ¯Cl inter-actions were observed within the structure.
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Ano de publicação:
2012
Tipo de documento:
Article