(Acetyl-acetonato-κ(2)O,O')[(2-bromo-phen-yl)diphenyl-phosphane-κP]carbonyl-rhodium(I).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 4): m482, 2012 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-22589842
ABSTRACT
In the title compound, [Rh(C(5)H(7)O(2))(C(18)H(14)BrP)(CO)], the Rh(I) atom adopts a slightly distorted square-planar geometry involving two O atoms [Rh-O = 2.077â
(2) and 2.033â
(2)â
Å] of the acetyl-acetonate ligand, one carbonyl C atom [Rh-C = 1.813â
(2)â
Å] and one P atom [Rh-P = 2.242â
(5)â
Å] of the PPh(2)(2-BrC(6)H(4)) phosphane ligand. Difference electron density maps indicate a disorder of the Br atom over two positions in an approximate 0.950.05 ratio. However, this disorder could not be resolved satisfactorily with the present data.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2012
Tipo de documento:
Article