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Na11B21O36X2 (X = Cl, Br): halogen sodium borates with a new graphene-like borate double layer.
Dong, Xiaoyu; Wu, Hongping; Shi, Yunjing; Yu, Hongwei; Yang, Zhihua; Zhang, Bingbing; Chen, Zhaohui; Yang, Yun; Huang, Zhenjun; Pan, Shilie; Zhou, Zhongxiang.
Afiliação
  • Dong X; Xinjiang Technical Institute of Physics & Chemistry, Key Laboratory of Functional Materials and Devices under Special Environments, CAS, 40-1 South Beijing Road, Urumqi 830011, PR China.
Chemistry ; 19(23): 7338-41, 2013 Jun 03.
Article em En | MEDLINE | ID: mdl-23630069
Borate not graphene: The [B6O12]∞(6-) single borate layer is a graphene-like layer (see figure). The weak Na(+)-Br(Cl)(-) ionic connection between the layers leads to the layer cleavage, and difficulty of the block crystal growth.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article