Electrochemical intramolecular C-H amination: synthesis of benzoxazoles and benzothiazoles.
Chemistry
; 21(8): 3211-4, 2015 Feb 16.
Article
em En
| MEDLINE
| ID: mdl-25641711
ABSTRACT
A new method for metal-free intramolecular C-H amination has been developed. Electrochemical oxidation of 2-pyrimidyloxybenzenes and 2-pyrimidylthiobenzenes, which can be easily prepared from phenols and thiophenols, respectively, followed by the treatment of the resulting pyrimidinium ions with piperidine gives 2-aminobenzoxazoles and 2-aminobenzothiazoles, respectively.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article