Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids.
Dalton Trans
; 45(12): 4989-92, 2016 Mar 28.
Article
em En
| MEDLINE
| ID: mdl-26934989
ABSTRACT
Assembly of cucurbit[6] and a {Cd2Ge8V12O48} cluster produced two rotaxane-shaped and polyrotaxane-shaped solids by changing the ratio of starting precursors in the system. The high oxygen density of the polyoxoanion surface provides active sites to extend a single rotaxane-shaped hybrid 1 to a 1D polyrotaxane-shaped hybrid 2. This construction strategy may afford an entirely new methodology for polyoxometalate-based hybrid chemistry.
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01-internacional
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MEDLINE
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En
Ano de publicação:
2016
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Article