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(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol.
Ballistreri, Francesco Paolo; Gangemi, Chiara M A; Pappalardo, Andrea; Tomaselli, Gaetano A; Toscano, Rosa Maria; Trusso Sfrazzetto, Giuseppe.
Afiliação
  • Ballistreri FP; Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, Italy. fballistreri@unict.it.
  • Gangemi CM; Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, Italy. gangemichiara@unict.it.
  • Pappalardo A; Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, Italy. andrea.pappalardo@unict.it.
  • Tomaselli GA; I.N.S.T.M. UdR of Catania, Viale A. Doria 6, 95125 Catania, Italy. andrea.pappalardo@unict.it.
  • Toscano RM; Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, Italy. gtomaselli@unict.it.
  • Trusso Sfrazzetto G; Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, Italy. rmtoscano@unict.it.
Int J Mol Sci ; 17(7)2016 Jul 12.
Article em En | MEDLINE | ID: mdl-27420047
ABSTRACT
Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article