IrIII -based Octahedral Metalloligands Derived Primitive Cubic Frameworks for Enhanced CO2 /N2 Separation.

Huang, Sheng-Li; Liu, Naifang; Ling, Yun; Luo, He-Kuan

Ir^III -based Octahedral Metalloligands Derived Primitive Cubic Frameworks for Enhanced CO₂ /N₂ Separation.

Huang, Sheng-Li; Liu, Naifang; Ling, Yun; Luo, He-Kuan.

Afiliação

Huang SL; Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 2 Fusionopolis Way. Innovis, #08-03, Singapore, 138634, Singapore.
Liu N; Institute of Materials Research and Engineering, Agency for Science, Technology and Research, 2 Fusionopolis Way. Innovis, #08-03, Singapore, 138634, Singapore.
Ling Y; Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore.
Luo HK; Department of Chemistry, Fudan University, Shanghai, China.

Chem Asian J ; 12(24): 3110-3113, 2017 Dec 14.

Article em En | MEDLINE | ID: mdl-29057626

RESUMO

We developed a metalloligand strategy to construct porous frameworks, viz. the combined use of IrIII -based octahedral metalloligands and the linear unit [Ni(cyclam)] easily afforded two isostructural complexes 1 and 2 with primitive cubic frameworks. Both complexes show good CO2 /N2 separation property.

Palavras-chave

carbon dioxide adsorption; gas separation; iridium; metal-organic frameworks; metalloligand; primitive cubic frameworks

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article