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Chiral benzazaboroles as catalysts for enantioselective sulfonylation of cis-1,2-diols.
Kuwano, Satoru; Hosaka, Yusei; Arai, Takayoshi.
Afiliação
  • Kuwano S; Soft Molecular Activation Research Center (SMARC), Chiba Iodine Resource Innovation Center (CIRIC), Molecular Chirality Research Center (MCRC), Synthetic Organic Chemistry, Department of Chemistry, Graduate School of Science, Chiba University, 1-33 Yayoi, Inage, Chiba, Japan. skuwano@chiba-u.jp tarai@faculty.chiba-u.jp.
Org Biomol Chem ; 17(18): 4475-4482, 2019 05 08.
Article em En | MEDLINE | ID: mdl-30900704
ABSTRACT
A newly developed benzazaborole smoothly catalyzed the enantioselective sulfonylation of cis-1,2-diols. Using a chiral benzazaborole/NMI co-catalyst system, various sulfonate esters were prepared in high yields with good enantioselectivities.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article