Chiral Open-[60]Fullerene Ligands with Giant Dissymmetry Factors.

ABSTRACT

The optical resolution of open-[60]fullerenes has been limited to only one example since 1998, while the recent advances revealed the excellence of fullerenes as revisited chiral functional materials. Different from conventional chiral induction on [60]fullerene by a multiple-functionalization, a random disruption of the spherical π-conjugation is avoidable for open-[60]fullerenes. Moreover, the macrocyclic orifices enable a metal coordination which endows modulated electronic structures on chiral chromophores. Herein, we showcase Li+-coordination behavior and optical resolution of three chiral open-[60]fullerene ligands, showing a giant dissymmetry factor up to 0.20 owing to a congenital topology of the spherical π-conjugation.