A strained intramolecular P/Al-FLP and its reactivity toward allene.
Chem Commun (Camb)
; 58(97): 13451-13454, 2022 Dec 06.
Article
em En
| MEDLINE
| ID: mdl-36342335
ABSTRACT
FLPs featuring aluminum-phosphane interactions, spring-loaded by a rigid biphenylene linker, have been accessed through a route where trimethyltin units at phosphane-functionalized organic backbones are exchanged by an AlCl2 moiety. Upon contact with substrates like CO2 these are readily bound by the Al/P site with release of strain. The system could also be utilized for a unique reactivity, namely the activation of allene.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article