Stabilization/solidification of heavy metal-contaminated marl soil using a binary system of cement and fuel fly ash.

The stabilization/solidification (S/S) method is one of the most effective remediation techniques for treating contaminated soils. Several stabilizers, mostly the cementitious materials, have been used for the S/S treatment. In this paper, the feasibility of utilizing fuel fly ash (FFA) as a partial replacement of ordinary Portland cement (OPC) for the S/S treatment of marl soil contaminated with heavy metals was investigated. Two industrial waste materials, namely steel and electroplating wastes, were used to synthetically contaminate the marl soil. The stabilizers comprising of OPC and FFA were mixed with the contaminated soil at different dosages ranging from 10 to 40%, by mass, and a total of 48 S/S-treated soil mixtures were prepared. A series of experiments, including density, porosity, permeability, unconfined compressive strength (UCS), and toxicity characteristics leaching procedure (TCLP), were carried out on the soil mixtures to evaluate the efficiency of the proposed S/S treatment. Test results showed that the incorporation of FFA at higher volumes reduced the density and increased the porosity and permeability of the treated mixtures. Although FFA addition resulted in reducing the UCS values by an average of 46%, and this reduction was more significant at higher FFA percentages, the UCS values of all mixtures were more than 0.35 MPa (350 kPa), which passed the minimum requirements set by USEPA. In addition, the metal immobilization ability of the proposed treatment was confirmed by the TCLP analysis. As compared to the negative effect of the contamination of the soil by the electroplating waste, the contamination of the soil by steel waste had a higher negative effect. The results of this study would contribute in selecting an environment-friendly treatment of the contaminated soils using industrial waste materials, such as FFA, as a partial replacement of OPC. Nevertheless, the present study is an initial attempt to explore the possibility of utilizing FFA as a partial replacement of OPC in S/S treatment of marl soil contaminated with heavy metals. It is recommended to conduct another study in future including analysis of the treated soil mixtures using XRD, SEM, and FTIR techniques to better understand the stabilization/solidification mechanism and its implications on the test results.

Effect of silica fume substitution by limestone powder and cement kiln dust on the shrinkage, durability, and sustainability of UHPC.

Silica fume is usually used in UHPC, three times more than that for normal concrete, to enhance mechanical properties and durability. However, silica fume (SF) is an expensive material and has high production costs. This work is aimed at investigating the shrinkage and durability performance of previously developed UHPC mixtures utilizing the two calcareous waste materials, namely limestone powder (LSP) and cement kiln dust (CKD), by partially replacing the silica fume. The optimally selected mixtures of UHPC, having flow and strength above the minimum required, were used for detailed investigation in terms of shrinkage and durability characteristics. The results showed that by replacing SF with up to 20% of LSP and up to 20% of CKD, the mechanical properties of UHPC remained satisfactory compared to the control mixture with 100% SF. However, the ultimate shrinkage was higher for mixtures incorporating LSP or CKD, indicating the need for more volume of steel fibers to compensate for the shrinkage strains. The developed UHPCs also exhibited high resistance against reinforcement corrosion and sulfate attack, making them suitable for use in aggressive exposure conditions. However, special attention needs to be paid to the CKD content, where it is recommended to limit the content of CKD to about 15% or less to control the durability performance of the UHPCs. In addition, the sustainability analysis of developed UHPC mixtures was carried out using the life-cycle assessment and eco-strength intensity index. The results indicated that the UHPC mixtures possess a higher life-cycle and are therefore more sustainable.

Engineered and green natural pozzolan-nano silica-based alkali-activated concrete: shrinkage characteristics and life cycle assessment.

Alkali-activated concrete (AAC) or binders (AABs) have emerged as a substitute to conventional ordinary Portland cement (OPC)-based concrete owing to their techno-ecological merits. Saudi Arabia has vast resources of natural pozzolan whose impact on some fresh and hardened properties was encouraging; however, the long-term shrinkage behavior of AABs and life cycle assessment (LCA) of the developed product is yet to be explored. Therefore, this study evaluates shrinkage characteristics and LCA of Saudi natural pozzolan (NP)-based AAC. The synergistic impact of admixing nano-silica (NS) up to 7.5% dosage was also observed on the properties of engineered AABs in comparison with OPC-based concrete. The shrinkage properties were correlated with the microstructure and pore structure. The study revealed that the shrinkage properties of both NP-based AABs and OPC-based concrete are comparable. However, adding NS increased the drying shrinkage strain because of the finer pore structure than AABs without NS, which was confirmed through nuclear magnetic resonance (NMR). The maximum average drying shrinkage strain of 510 µÎµ was recorded in the OPC concrete, whereas in the engineered AAC with 0, 1, 2.5, 5, and 7.5% NS, it was 486, 537, 568, 601, and 651 µÎµ, respectively. It is postulated that the NP can be beneficially valorized in the production of green AABs without compromising the shrinkage characteristics, while the NS is favorable for enhancing the strength and refinement of the pore matrix. Besides, the LCA indicated the feasibility of recycling the high volume of natural waste by AAB technology, which significantly lowers the carbon footprints and minimizes the environmental implications in infrastructural applications.

Synthesis of waste limestone powder-based alkali-activated binder: experimental, optimization modeling, and eco-efficiency assessment.

More than half of the CO2 emissions during the manufacturing of ordinary Portland cement (OPC) occur due to the calcination of calcium carbonate in addition to burning of fossil fuel to power the process. Consequently, there is a concerted effort to decrease the carbon footprint associated with this process, by minimizing the use of OPC. In line with this trend, an attempt was made in the reported study to synthesize a novel alkali-activated binder using CaCO3-rich waste limestone powder (WLSP) as a precursor. Utilizing the Taguchi method, four important parameters were varied at three levels to optimize the alkali-activated mixture. Analysis of variance (ANOVA) of the obtained results was performed to assess the impact of each of the factors on the properties of the developed binder. To enhance the strength further, OPC was added as a partial replacement of WLSP. The binder was characterized using scanning electron microscopy. The results have indicated that alkaline activator to binder ratio, Na2SiO3 to NaOH ratio, and sand to binder ratio of 0.575, 1.57, and 2.5, respectively, were the optimum to obtain satisfactory strength and workability with a 13.7-M NaOH activator solution. The incorporation of a small quantity of OPC in the mixture remarkably improved the density and strength of the alkali-activated-WLSP binder. Pirssonite (CaCO3.Na2CO3.2H2O) and C/N-A-S-H were the dominant mineral phases formed in the developed binder, particularly in the ones alkali-activated WLSP/OPC. In addition, the eco-efficiency assessment revealed that the WLSP is a promising low-carbon binder that can be used in developing more sustainable alkali-activated binder. The results have shown that the WLSP can be potentially utilized in developing binder that can be potentially used in the structural applications.