1.
Chem Commun (Camb)
; 59(28): 4193-4196, 2023 Apr 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36942515
RESUMEN
A series of (NHC)(cod)Ir(I) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(I) complexes demonstrated efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, and allowed for excellent ortho-selectivity control with aromatic silylating agents.