Harmonic generation from silicon membranes at visible and ultraviolet wavelengths.

Nonlinear silicon photonics offers unique abilities to generate, manipulate and detect optical signals in nano-devices, with applications based on field localization and large third order nonlinearity. However, at the nanoscale, inefficient nonlinear processes, absorption, and the lack of realistic models limit the nano-engineering of silicon. Here we report measurements of second and third harmonic generation from undoped silicon membranes. Using experimental results and simulations we identify the effective mass of valence electrons, which determines second harmonic generation efficiency, and oscillator parameters that control third order processes. We can then accurately predict the nonlinear optical properties of complex structures, without introducing and artificially separating the effective χ(2) into surface and volume contributions, and by simultaneously including effects of linear and nonlinear dispersions. Our results suggest that judicious exploitation of the nonlinear dispersion of ordinary semiconductors can provide reasonable nonlinear efficiencies and transformational device physics well into the UV range.

Ensemble Methods for APS In-Flight Particle Temperature and Velocity Prediction Considering Torch Electrodes Ageing.

The nonlinear relationship between the input process parameters and in-flight particle characteristics of the atmospheric plasma spray (APS) is of paramount importance for coating properties design and quality. It is also known that the ageing of torch electrodes affects this relationship. In recent years, machine learning algorithms have proven to be able to take into account such complex nonlinear interactions. This work illustrates the application of ensemble methods to predict the in-flight particle temperature and velocity during an APS process considering torch electrodes ageing. Experiments were performed to record simultaneously the input process parameters, the in-flight powder particle characteristics and the electrodes usage time. Random Forest (RF) and Gradient Boosting (GB) were used to rank and select the features for the APS process data recorded as the electrodes aged and the corresponding predictive models were compared. The time series aspect of the multivariate APS in-flight particle characteristics data is explored. Two strategies of time series embedding are considered. The first one simply embeds the attributes and the targets from the previous n time segments considered without any modification; whereas the second strategy first performs differencing to make the time series stationary before embedding. For the present application, RF is found to be more suitable than GB since RF can predict both the in-flight particle velocity and temperature simultaneously, properly considering the interactions between the two targets. On the other hand, GB can only predict these two targets one at a time. The superior performance of both embedded predictive models and the feature rankings of them suggest that it is better to consider the APS data as time series for the in-flight particle characteristic prediction. In particular, it is demonstrated that it is advantageous to first make the time series stationary using the traditional differencing technique, even when modeling using RF.

Mechanisms, time course and predictability of premature ventricular contractions cardiomyopathy-an update on its development and resolution.

Frequent premature ventricular contractions (PVCs) associated left ventricular systolic dysfunction (LVSD) is a well-known clinical scenario and numerous predictors for cardiomyopathy (CMP) development have been already thoroughly described. It may present as a "pure" form of dissynchrony-induced cardiomyopathy or it may be an aggravating component of a multifactorial structural heart disease. However, the precise risk to develop PVC-induced CMP (which would allow for tailored-patient monitoring and/or early treatment) and the degree of CMP reversibility after PVC suppression/elimination (which may permit appropriate candidate selection for therapy) are unclear. Moreover, there is limited data regarding the time course of CMP development and resolution after arrhythmia suppression. Even less known are the other components of PVC-induced CMP, such as right ventricular (RV) and atrial myopathies. This review targets to synthetize the most recent information in this regard and bring a deeper understanding of this heart failure scenario. The mechanisms, time course (both in experimental models and clinical experiences) and predictors of reverse-remodelling after arrhythmia suppression are described. The novel experience hereby presented may aid everyday clinical practice, promoting a new paradigm involving more complex, multi-level and multi-modality evaluation and possible earlier intervention at least in some patient subsets.

Harmonic generation from gold nanolayers: bound and hot electron contributions to nonlinear dispersion.

Understanding how light interacts with matter at the nanoscale is pivotal if one is to properly engineer nano-antennas, filters and other devices whose geometrical features approach atomic size. We report experimental results on second and third harmonic generation from 20 nm- and 70 nm-thick gold layers, for TE- and TM-polarized incident light pulses. We discuss the relative roles that bound electrons and an intensity dependent free electron density (hot electrons) play in third harmonic generation. While planar structures are generally the simplest to fabricate, metal layers that are only a few nanometers thick and partially transparent are almost never studied. Yet, transmission offers an additional reference point to compare experimental measurements with theoretical models. Our experimental results are explained well within the context of the microscopic hydrodynamic model that we employ to simulate second and third harmonic conversion efficiencies. Using our experimental observations we estimate ∣χ1064nm(3)∣≈10-18 (m/V)2, triggered mostly by hot electrons.

Single-shot d-scan technique for ultrashort laser pulse characterization using transverse second-harmonic generation in random nonlinear crystals.

We demonstrate a novel dispersion-scan (d-scan) scheme for single-shot temporal characterization of ultrashort laser pulses. The novelty of this method relies on the use of a highly dispersive crystal featuring antiparallel nonlinear domains with a random distribution and size. This crystal, capable of generating a transverse second-harmonic signal, acts simultaneously as the dispersive element and the nonlinear medium of the d-scan device. The resulting in-line architecture makes the technique very simple and robust, allowing the acquisition of single-shot d-scan traces in real time. The retrieved pulses are in very good agreement with independent frequency-resolved optical grating measurements. We also apply the new single-shot d-scan to a terawatt-class laser equipped with a programmable pulse shaper, obtaining an excellent agreement between the applied and the d-scan retrieved dispersions.

Harmonic generation in the opaque region of GaAs: the role of the surface and magnetic nonlinearities.

Phase-locked second and third harmonic generation in the opaque region of a GaAs wafer is experimentally observed and analyzed both in transmission and reflection. These harmonic components, which are generated close to the surface, can propagate through an opaque material as long as the pump is tuned to a region of transparency or semitransparency and correspond to the inhomogeneous solutions of Maxwell's equations with nonlinear polarization sources. We show that measurement of the angular and polarization dependence of the observed harmonic components allows one to infer the different nonlinear mechanisms that trigger these processes, including not only the bulk nonlinearity but also the surface and magnetic Lorentz contributions, which usually are either hidden by the bulk contributions or assumed to be negligible. The experimental results are compared with a detailed numerical model that takes into account these different effects, including for the first time combined linear and nonlinear material dispersions in a nonlinear Lorentz oscillator model of the bulk nonlinearities. Our results suggest that the intensity of the second harmonic signal generated by the surface can be more intense than the signal generated by the bulk. These findings have significant repercussions and are consequential in nanoscale systems, which are usually investigated using only dispersionless bulk nonlinearities, with near-complete disregard of surface and magnetic contributions and their microscopic origins.

Reevaluation of radiation reaction and consequences for light-matter interactions at the nanoscale.

In the context of electromagnetism and nonlinear optical interactions, damping is generally introduced as a phenomenological, viscous term that dissipates energy, proportional to the temporal derivative of the polarization. Here, we follow the radiation reaction method presented in [Phys. Lett. A157, 217 (1991)], which applies to non-relativistic electrons of finite size, to introduce an explicit reaction force in the Newtonian equation of motion, and derive a hydrodynamic equation that offers new insight on the influence of damping in generic plasmas, metal-based and/or dielectric structures. In these settings, we find new damping-dependent linear and nonlinear source terms that suggest the damping coefficient is proportional to the local charge density and nonlocal contributions that stem from the spatial derivative of the magnetic field. We discuss the conditions that could modify both linear and nonlinear electromagnetic responses.

Comparative analysis of ferroelectric domain statistics via nonlinear diffraction in random nonlinear materials.

We present an indirect, non-destructive optical method for domain statistic characterization in disordered nonlinear crystals having homogeneous refractive index and spatially random distribution of ferroelectric domains. This method relies on the analysis of the wave-dependent spatial distribution of the second harmonic, in the plane perpendicular to the optical axis in combination with numerical simulations. We apply this technique to the characterization of two different media, Calcium Barium Niobate and Strontium Barium Niobate, with drastically different statistical distributions of ferroelectric domains.

Transverse single-shot cross-correlation scheme for laser pulse temporal measurement via planar second harmonic generation.

We present a novel single-shot cross-correlation technique based on the analysis of the transversally emitted second harmonic generation in crystals with random distribution and size of anti-parallel nonlinear domains. We implement it to the measurement of ultrashort laser pulses with unknown temporal duration and shape. We optimize the error of the pulse measurement by controlling the incident angle and beam width. As novelty and unlike the other well-known cross correlation schemes, this technique can be implemented for the temporal characterization of pulses over a very wide dynamic range (30 fs-1ps) and wavelengths (800-2200 nm), using the same crystal and without critical angular or temperature alignment.

Beam focalization in reflection from flat dielectric subwavelength gratings.

We experimentally demonstrate the recently predicted effect of near-field focusing for light beams from flat dielectric subwavelength gratings (SWGs). This SWGs were designed for visible light 532 nm and fabricated by direct laser writing in a negative photoresist, with the refractive index n=1.5 and the period d=314 nm. The laterally invariant gratings can focus light beams without any optical axis to achieve the transversal invariance. We show that focal distances can be obtained up to 13 µm at normal reflection for TE polarization.

Flat lensing in the visible frequency range by woodpile photonic crystals.

We experimentally demonstrate full two-dimensional focalization of light beams at visible frequencies by a three-dimensional woodpile photonic crystal. The focalization (the flat lensing) with focal distances of the order of 50-70 µm is experimentally demonstrated. Experimental results are compared with numerical calculations and interpreted by harmonic expansion studies.

Modified Stranski-Krastanov growth in Ge/Si heterostructures via nanostenciled pulsed laser deposition.

The combination of nanostenciling with pulsed laser deposition (PLD) provides a flexible, fast approach for patterning the growth of Ge on Si. Within each stencilled site, the morphological evolution of the Ge structures with deposition follows a modified Stranski-Krastanov (SK) growth mode. By systematically varying the PLD parameters (laser repetition rate and number of pulses) on two different substrate orientations (111 and 100), we have observed corresponding changes in growth morphology, strain and elemental composition using scanning electron microscopy, atomic force microscopy and µ-Raman spectroscopy. The growth behaviour is well predicted within a classical SK scheme, although the Si(100) growth exhibits significant relaxation and ripening with increasing coverage. Other novel aspects of the growth include the increased thickness of the wetting layer and the kinetic control of Si/Ge intermixing via the PLD repetition rate.

Enhanced efficiency of the second harmonic inhomogeneous component in an opaque cavity.

In this Letter, we experimentally demonstrate the enhancement of the inhomogeneous second harmonic conversion in the opaque region of a GaAs cavity with efficiencies of the order of 0.1% at 612 nm, using 3 ps pump pulses having peak intensities of the order of 10 MW/cm(2). We show that the conversion efficiency of the inhomogeneous, phase-locked second harmonic component is a quadratic function of the cavity factor Q.

The role of ferroelectric domain structure in second harmonic generation in random quadratic media.

We study theoretically and numerically the second harmonic generation in a nonlinear crystal with random distribution of ferroelectric domains. We show that the specific features of disordered domain structure greatly affect the emission pattern of the generated harmonics. This phenomena can be used to characterize the degree of disorder in nonlinear photonic structures.

Third-harmonic generation via broadband cascading in disordered quadratic nonlinear media.

We study parametric frequency conversion in quadratic nonlinear media with disordered ferroelectric domains. We demonstrate that disorder allows realizing broadband third-harmonic generation via cascading of two second-order quasi-phase matched nonlinear processes. We analyze both spatial and polarization properties of the emitted radiation and find the results in agreement with our theoretical predictions.

Measurement of multiple scattering of 13 and 20 MeV electrons by thin foils.

To model the transport of electrons through material requires knowledge of how the electrons lose energy and scatter. Theoretical models are used to describe electron energy loss and scatter and these models are supported by a limited amount of measured data. The purpose of this work was to obtain additional data that can be used to test models of electron scattering. Measurements were carried out using 13 and 20 MeV pencil beams of electrons produced by the National Research Council of Canada research accelerator. The electron fluence was measured at several angular positions from 0 degree to 90 degrees for scattering foils of different thicknesses and with atomic numbers ranging from 4 to 79. The angle, theta 1/e at which the fluence has decreased to 1/e of its value on the central axis was used to characterize the distributions. Measured values of theta 1/e ranged from 1.5 degrees to 8 degrees with a typical uncertainty of about 1%. Distributions calculated using the EGSnrc Monte Carlo code were compared to the measured distributions. In general, the calculated distributions are narrower than the measured ones. Typically, the difference between the measured and calculated values of theta 1/e is about 1.5%, with the maximum difference being 4%. The measured and calculated distributions are related through a simple scaling of the angle, indicating that they have the same shape. No significant trends with atomic number were observed.

Localized CVD growth of oriented and individual carbon nanotubes from nanoscaled dots prepared by lithographic sequences.

Using a combination of top-down lithographic techniques, isolated, individual and oriented multi-wall carbon nanotubes (MWNTs) were grown on nickel or iron nanoscaled dots. In the first step of the process, micron-sized catalytic metallic dots (either iron or nickel) were prepared using UV lithography. MWNTs were then synthesized from these catalysts using a direct current plasma-assistance and hot-filament-enhanced chemical vapor deposition (CVD) reactor. Samples were characterized by means of scanning electron microscopy. It turns out that the splitting up of the micron-sized dot is favored in the iron case and that the surface diffusion of the metal is enhanced using ammonia in the gaseous mixture during the CVD process. The results are discussed giving arguments for the understanding of the MWNT growth mechanism. In a second step, a focused ion beam (FIB) procedure is carried out in order to reduce the initial dot size down to submicronic scale and subsequently to grow one single MWNT per dot. It is found that nickel is most appropriate to control the size of the dot. Dots of size 200 nm +/- 40 nm are then required to grow individual MWNTs.

A nucleation and growth model of vertically-oriented carbon nanofibers or nanotubes by plasma-enhanced catalytic chemical vapor deposition.

Carbon nanofibers are grown by direct current and hot filaments-activated catalytic chemical vapor deposition while varying the power of the hot filaments. Observations of these carbon nanofibers vertically oriented on a SiO2 (8 nm thick)/Si(100) substrate covered with Co nanoparticles (10-15 nm particle size) by Scanning Electron and Transmission Electron Microscopies show the presence of a graphitic "nest" either on the surface of the substrate or at the end of the specific nanofiber that does not encapsulate the catalytic particle. Strictly in our conditions, the activation by hot filaments is required to grow nanofibers with a C2H2 - H2 gas mixture, as large amounts of amorphous carbon cover the surface of the substrate without using hot filaments. From these observations as well as data of the literature, it is proposed that the nucleation of carbon nanofibers occurs through a complex process involving several steps: carbon concentration gradient starting from the catalytic carbon decomposition and diffusion from the surface of the catalytic nanoparticles exposed to the activated gas and promoted by energetic ionic species of the gas phase; subsequent graphitic condensation of a "nest" at the interface of the Co particle and substrate. The large concentration of highly reactive hydrogen radicals mainly provided by activation with hot filaments precludes further spreading out of this interfacial carbon nest over the entire surface of the substrate and thus selectively orientates the growth towards the condensation of graphene over facets that are perpendicular to the surface. Carbon nanofibers can then be grown within the well-known Vapor-Liquid-Solid process. Thus the effect of energetic ions and highly reactive neutrals like atomic hydrogen in the preferential etching of carbon on the edge of graphene shells and on the broadening of the carbon nanofiber is underlined.

Subdiffractive light pulses in photonic crystals.

We investigate propagation of light pulses in photonic crystals in the vicinity of the zero diffraction point. We show that Gaussian pulses due to nonzero width of their temporal spectrum spread weakly in space and time during the propagation. We also find the family of nonspreading pulses, propagating invariantly in the vicinity of the zero diffraction point of photonic crystals.

Ni and Ni/Pt filling inside multiwalled carbon nanotubes.

Multiwalled carbon nanotubes are grown by microwave plasma chemical vapor deposition with CH4 and H2 as precursor gases. Ni and Ni/Pt electroplated layers are used as catalysts for the synthesis of the tubes. We observe that a very efficient filling of the tubes takes place with Ni. In some cases Ni/Pt filling is also observed inside the tubes. High-resolution transmission electron microscopy (HRTEM) studies, coupled with energy-dispersive X-ray analyses of the tubes, indicate Ni nanorods with a highly symmetrical cylindrical structure. The diameter of the cylindrical nanorods is on the order of 40 nm, and their length is 660 nm. The nano area diffraction pattern of the nanorods reveals the cubic structure of nickel, and electron diffraction spots corresponding to (111), (200), (220) planes are evident. The lattice constant of Ni measured from the diffraction spots was found to be 0.347 +/- 0.0013 nm. This should be compared with 0.352 nm, the value of "a" in bulk Ni. The decrease in the lattice constant may be due to the strain experienced inside the tubes. Raman spectroscopy shows the typical signature of the tangential breathing mode present in the tubes at 1580 cm-1 that shifts to a new position when the C12 is replaced by 13C. The shift, however, is too small and is difficult to explain on the basis of mass difference. HRTEM experiments indicate the presence of Ni3C in the samples dominantly in the interfacial region.