RESUMEN
Ultrasonic force microscopy (UFM) is used to resolve the elastic nanostructure of strained antimony (Sb) particles. These nanoparticles were formed by aggregation and spontaneous rapid crystallization of thermally deposited Sb onto the (0001) basal planes of highly oriented pyrolytic graphite (HOPG) and molybdenum disulfide (MoS(2)). UFM reveals clear contrast within individual nanoparticles, which can be attributed to differences in the local stiffness. This interpretation is confirmed by transmission electron microscopy (TEM) images, in which bending contours prove the existence of strained regions within the nanocrystals.
RESUMEN
We have manipulated raw and functionalized gold nanoparticles (with a mean diameter of 25 nm) on silicon substrates with dynamic atomic force microscopy (AFM). Under ambient conditions, the particles stick to silicon until a critical amplitude is reached by the oscillations of the probing tip. Beyond that threshold, the particles start to follow different directions, depending on their geometry and adhesion to the substrate. Higher and lower mobility were observed when the gold particles were coated with methyl- and hydroxyl-terminated thiol groups, respectively, which suggests that the adhesion of the particles to the substrate is strongly reduced by the presence of hydrophobic interfaces. Under ultrahigh vacuum conditions, where the water layer is absent, the particles did not move, even when operating the atomic force microscope in contact mode. We have also investigated the influence of the temperature (up to 150 degrees C) and of the geometrical arrangement of the particles on the manipulation process. Whereas thermal activation has an important effect in enhancing the mobility of the particles, we did not find differences when manipulating ordered versus random distributions of particles.