Intelligent Path-Selection-Aided Decoding of Polar Codes.

CRC-aided successive cancellation list (CA-SCL) decoding is a powerful algorithm that dramatically improves the error performance of polar codes. Path selection is a major issue that affects the decoding latency of SCL decoders. Generally, path selection is implemented using a metric sorter, which causes its latency to increase as the list grows. In this paper, intelligent path selection (IPS) is proposed as an alternative to the traditional metric sorter. First, we found that in the path selection, only the most reliable paths need to be selected, and it is not necessary to completely sort all paths. Second, based on a neural network model, an intelligent path selection scheme is proposed, including a fully connected network construction, a threshold and a post-processing unit. Simulation results show that the proposed path-selection method can achieve comparable performance gain to the existing methods under SCL/CA-SCL decoding. Compared with the conventional methods, IPS has lower latency for medium and large list sizes. For the proposed hardware structure, IPS's time complexity is O(klog2(L)) where k is the number of hidden layers of the network and L is the list size.

Substituent effect on the meso-substituted porphyrins: theoretical screening of sensitizer candidates for dye-sensitized solar cells.

According to the concepts of attribute axis and attribute coordinate system, porphine and 11 kinds of bridge carbon substituted porphyrins as donors and 9 common acceptors A-I have been designed and calculated at the density functional B3LYP level. The substituent effects on the molecular orbital energy levels of the porphyrin derivatives have been discussed and promising donor-acceptor combinations are screened. Several novel zinc metalloporphyrins selected were then calculated by means of the DFT/TDDFT method in THF solvent. The electronic and spectroscopic properties of ZnTPP and the selected novel zinc porphyrin complexes have been investigated as solar cell sensitizers. The results show that the candidates selected are very promising to provide good performances as sensitizers, in which ZnTPPG is promising to challenge the current photo-electric conversion efficiency record 7.1% of porphyrin-sensitized solar cells. The concepts of attribute axis and attribute coordinate system are shown very helpful for tuning the molecular properties and the rational design of functional molecules with anticipated good properties.

Molecule design and screening of novel unsymmetrical zinc phthalocyanine sensitizers for dye-sensitized solar cells.

The molecular orbital and optical properties of the dyes PCH001 and TT1 reported previously were studied using the density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations. The results show that the electronic spectra simulated for PCH001 and TT1 in ethanol were in good agreement with the experimental data. The molecular orbital spatial orientation was used to interpret the discrepancy of the photovoltaic performances of the PCH001 and TT1 sensitized solar cells. The conjugation between the carboxyl group and the phthalocyanine ring in TT1 was found to be better than that through the C-C single bond in PCH001, which may contribute to TT1's improved performance. Four new unsymmetrical phthalocyanine molecules with the peripheral substituents as donors and anchoring groups as acceptors, namely CZ1, CZ2, trans- and cis-CZ3, were designed and compared to PCH001 and TT1. The new molecules CZ2 and cis-CZ3 were promising and may challenge the current record of PCH001 and TT1 in phthalocyanine-sensitized solar cells.