Pillar[5]arene-based Polymer Network for Efficiently Removing Perfluorooctanoic Acid through Synergistic Binding Interactions.

Perfluorooctanoic acid (PFOA) is currently one of the most important chemicals posing environmental risks, and there is an urgent need to find methods to efficiently remove PFOA from environmental media. Here, two decaamino-pillar[5]arene-based fluorine-rich polymer networks, called FA2P-P and FA6P-P, were constructed using a convenient method. FA6P-P had an excellent ability to take up PFOA, and had a capacity of 1423 (mg PFOA) (g FA6P-P) -1, which is the second highest adsorption capacity reported for any PFOA sorbent. FA6P-P removed >99% of the PFOA from a solution and decreased the PFOA concentration from 1000 µg L-1 in 5 min at an exceedingly low adsorbent loading of 0.7 mg L-1, giving a final PFOA concentration <4 ng L-1, which is lower than the most recent enforceable maximum concentration set by the United States Environmental Protection Agency. A high rate constant (kobs) of 55.8 g mg-1 h-1 was observed. Pillar[5]arene gives the material hydrophobic properties and also amino sites and hydrophobic chains, which are synergistic PFOA binding sites. The polymer was very stable and readily regenerated. The results indicated that pillar[5]arene-based porous organic polymer sorbents are excellent candidates for capturing PFOA.

Effectively removing gaseous polycyclic aromatic hydrocarbons (PAHs) by willow catkins: Do you still dislike the catkins floating?

The floating catkins generated by willow and poplar trees have been criticized for spreading germ and causing fire for decades. It has been found that catkins are with a hollow tubular structure, which made us wonder if the floating catkins can adsorb atmospheric pollutions. Thus, we conducted a project in Harbin, China to investigate whether and how willow catkins could adsorb atmospheric polycyclic aromatic hydrocarbons (PAHs). The results suggest that both the catkins floating in the air and on the ground preferred to adsorb gaseous PAHs rather than particulate PAHs. Moreover, 3- and 4-ring PAHs were the dominating compositions adsorbed by catkins, which significantly increased with exposure time. The gas/catkins partition (KCG) was defined, which explained why 3-ring PAHs are more easily adsorbed by catkins than by airborne particles when their subcooled liquid vapor pressure is high (log PL > -1.73). The removal loading of atmospheric PAHs by catkins were estimated as 1.03 kg/year in the center city of Harbin, which may well explain the phenomenon that levels of gaseous and total (particle + gas) PAHs are relatively low in the months with catkins floating reported in peer-reviewed papers.

[Distribution Characteristics and Source Apportionment of n-Alkanes in Water from Yellow River in Henan Section].

To investigate the distributions and possible sources of n-alkanes in water and suspended particulate matter from Yellow River in Henan section, 26 water and suspended particulate matter samples were collected in August 2010 and 22 n-alkanes (C14-C36) were quantitatively determined by gas chromatography-mass spectrometer (GC-MS). Potential sources of n-alkanes were analyzed using different characteristic parameters. The results indicated that total concentrations of 22 n-alkanes were 521-5,843 ng · L⁻¹ with a mean concentration of 1,409 ng · L⁻¹, while the total amounts of n-alkanes in the suspended particulate matter were 463-11,142 ng · L⁻¹ with a mean value of 1,951 ng · L⁻¹. The composition profiles of n-alkanes in water showed unimodal distribution with a peak at C25 in water. However, the composition characteristics of n-alkanes in SPM were of bimodal type, but still with the advantage of high carbon hydrocarbons peak at C25. Results of characteristic parameters including CPI, TAR, OEP and % WaxCn showed that n-alkanes in the studied area were derived mainly from combustion of fossil fuel, while terrestrial higher plant played a role in the existence of n-alkanes in water and suspended particulate matter from Yellow River in Henan section.

[Particle Size Distribution, Seasonal Variation Characteristics and Human Exposure Assessment of Heavy Metals in Typical Settled Dust from Beijing].

Four types of dust from dormitories, offices, hotels and roads in Beijing were collected and fractionated into 9 fractions, respectively. Totally 36 samples were obtained and analyzed for heavy metals including Cu, Zn, Cr, Pb, Cd and Ni. Particle size distributions of those heavy metals in these four types of dust were investigated and the influencing mechanisms were discussed. Distribution patterns of the same heavy metal in different types of dust showed various characteristics. Also different metals in the same type of dust represented different distribution patterns. Heavy metals in road dust tended to concentrate in finer particles. Two offices from the same building, located in Beijing, China, were selected to study the seasonality of heavy metals in dust. Dust sampling from Office A was conducted at weekly intervals between March 2012 and August 2012, while dust from Office B was sampled fortnightly from March 2012 to December 2012. Generally, levels of all heavy metals remained stable among different seasons, however, Cr and Pb represented more significant fluctuations than other four heavy metals. Based on the geo-accumulation index method, the pollution of Zn, Cu and Pb was more serious in the investigated samples, and dust from offices and hotels were moderately polluted by Zn. According to the risk assessment results, the carcinogenic health risks of the six heavy metals in the four types of dust were negligible.

[Distribution Characteristics and Ecological Risk Assessment of HCHs and DDTs in Surface Water Bodies in Xinxiang].

In order to investigate the distribution characteristics and ecological risk of HCHs and DDTs in the surface water of Xinxiang, 18 surface water samples were collected from from Xinxiang and the concentrations of HCHs and DDTs were determined. The ecological risk of HCHs and DDTs was evaluated using the overlapping areas of probability density function and safety threshold methods. The results showed that the levels of total HCHs (sum of 2 HCHs) and total DDTs (sum of DDTs) in 18 samples detected by GC-ECD ranged from 1.28 ng x L(-1) to 49.2 ng x L(-1) and from 0.42 ng x L(-1) to 12.3 ng x L(-1), respectively. In comparison with those reported for other rivers around the world, the levels of HCHs and DDTs in surface water from Xinxiang ranked middle. The main cause for HCHs and DDTs residues in the studied area was usage of lindane and technical DDTs as revealed by the isomer ratios. The ecological risk evaluation was based on the exposure concentration and available chronic toxicity data of p,p'-DDT, gamma-HCHs and DDD, and the overlapping areas of probability density function and safety threshold methods both showed that the ecological risk of these three OCPs to aquatic organism was in the order of DDD > gamma-HCHs > p,p'-DDT. And the probability of exposure concentration exceeding the 10% value of the toxicity data for DDD. Gamma-HCHs and p,p'-DDT was 10.2%, 5.94%, 0.01%, respectively.

Microwave-assisted preparation, characterization and photocatalytic properties of a dumbbell-shaped ZnO photocatalyst.

A novel dumbbell-shaped ZnO photocatalyst was successfully synthesized by microwave heating in the present study. The prepared ZnO photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-Vis absorption spectrum (UV-Vis). The results indicated that the prepared ZnO photocatalyst shows a united dumbbell shape with 2 microm diameter and 5 microm length. The photocatalytic activity of the prepared dumbbell-shaped ZnO photocatalyst was evaluated by the degradation of Methylene Blue (MB) in aqueous solution. The effects of pH, catalyst dosage ([ZnO]) and initial concentration of MB ([MB]) on the photocatalytic degradation efficiency of MB were investigated. An optimum condition was determined as pH 7-8, [ZnO]=1.0 g-ZnO L(-1) and [MB]=15 mg-MB L(-1). Under the optimum condition, the decolorization and TOC removal efficiencies of MB at 75 min reaction time were achieved 99.6% and 74.3%, respectively, which were higher than that by the commercial ZnO powder. In addition, the photocatalytic degradation kinetics of MB was also investigated. The results showed that the photocatalytic degradation kinetics of MB fitted the pseudo-first-order kinetics and the Langmuir-Hinshelwood model.

[Study on the grain-size distribution of polycyclic aromatic hydrocarbons in Yangtze River sediment].

Sediments collected from Yangtze River were separated into five size fractions ( > 200 microm, 200 - 125 microm, 125 - 63 microm, 63 - 25 microm, <25 microm) by wet sieving. The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. EPA priority pollutants were determined in the fractionated sediments. Sigma PAHs concentrations ranged from 26.1 to 7135.9 ng/g and varied largely among the different size fractions. The highest Sigma PAHs concentration (7135.9 ng/g) was associated with the largest size fraction ( > 200 microm) while the fine silt fraction (63 - 25 microm) contained the lowest Sigma PAHs concentration, 26.1 ng/g. Although the PAHs concentrations difference among different fractions was great, the composition of PAHs in the five size fractions showed similar pattern dominated by PAHs with three or more rings. Sediment particles less than 25 microm contributed 75% of the Sigma PAHs, while comprising 38.6% of bulk sediment dry weight. A significant positive correlation (p < 0.01) between PAHs and total organic carbon (TOC) existing for all size fractions demonstrated that TOC was important for PAHs distribution in sediments. Additionally, sediment organic matter type and structure also played an important role in PAHs distribution in different grain size fractions.