Harnessing bio and (Photo)catalysts for microplastics degradation and remediation in soil environment.

Soil pollution by microplastics (MPs) is an escalating environmental crisis with far-reaching consequences. However, current research on the degradation and/or remediation of MPs has mainly focused on water-simulated environments, with little attention given to soil MPs. Therefore, the review explores such terrestrial territory, exploring the potential of biodegradation and novel photocatalytic technologies for MPs degradation/remediation in soil. This review comprehensively investigates the potential of biological and photocatalytic approaches for soil MPs degradation and remediation. A temporal analysis of research from 2004 to 2024 highlights the increasing focus on this critical issue. The review explores the biocatalytic roles of diverse enzymes, including cutinase, PETase, MHETase, hydrolase, lipase, laccase, lignin peroxidase, and Mn-peroxidase, in MPs degradation. Strategies for enzyme engineering, such as protein engineering and immobilization, are explored to enhance catalytic efficiency. The potential for developing enzyme consortia for optimized MP degradation is also discussed. Photocatalytic remediation using TiO2, ZnO, clay, hydrogel, and other photocatalysts is examined, emphasizing their mechanisms and effectiveness. Computational modeling is proposed to deepen understanding of soil MPs-catalyst interactions, primarily aiming to develop novel catalysts tailored for soil environments for environmental safety and sustainable restoration. A comparative analysis of biological and photocatalytic approaches evaluates their environmental implications and the potential for synergistic combinations, with emphasis on soil quality protection, restoration and impact on soil ecosystems. Hence, this review accentuates the urgent need for innovative solutions to address MPs pollution in soil and provides a foundational understanding of the current knowledge gaps, as well as paves the way for future research and development.

Advanced Strategies in Metal-Organic Frameworks for CO2 Capture and Separation.

The continuous carbon dioxide (CO2 ) gas emissions associated with fossil fuel production, valorization, and utilization are serious challenges to the global environment. Therefore, several developments of CO2 capture, separation, transportation, storage, and valorization have been explored. Consequently, we documented a comprehensive review of the most advanced strategies adopted in metal-organic frameworks (MOFs) for CO2 capture and separation. The enhancements in CO2 capture and separation are generally achieved due to the chemistry of MOFs by controlling pore window, pore size, open-metal sites, acidity, chemical doping, post or pre-synthetic modifications. The chemistry of defects engineering, breathing in MOFs, functionalization in MOFs, hydrophobicity, and topology are the salient advanced strategies, recently reported in MOFs for CO2 capture and separation. Therefore, this review summarizes MOF materials' advancement explaining different strategies and their role in the CO2 mitigations. The study also provided useful insights into key areas for further investigations.

Catalyst development for tar reduction in biomass gasification: Recent progress and the way forward.

Biomass valorization via catalytic gasification is a potential technology for commercizalization to industrial scale. However, the generated tar during biomass valorization posing numerous problems to the overall reaction process. Thus, catalytic tar removal via reforming, cracking and allied processes was among the priority areas to researchers in the recent decades. This paper reports new updates on the areas of catalyst development for tar reduction. The catalyst survey include metallic and metal-promoted materials, nano-structured systems, mesoporous supports like zeolites and oxides, group IA and IIA compounds and natural catalysts based on dolomite, palygorskite, olivine, ilmenite, goethite and their modified derivatives. The influence of catalyst properties and parameters such as reaction conditions, catalyst preparation procedures and feedstock nature on the overall activity/selectivity/stability properties were simultaneously discussed. This paper not only cover to model compounds, but also explore to real biomass-derived tar for consistency. The area that require further investigation was identified in the last part of this review.