Dataset on onshore groundwaters and offshore submarine spring of a Mediterranean karst aquifer during flow reversal and saltwater intrusion.

Groundwater from various shallow and deep reservoirs converges in interaction with marine waters into the limestone aquifer of the Balaruc peninsula (Thau lagoon, southern France). This aquifer faces temporary phenomena of marine water intrusion through the Vise submarine spring located at -29.5 m below the lagoon level. Since the 1960s, seven flow reversal phenomena have occurred, the last one occurring between 11/28/2020 and 03/14/2022. During these phenomena, which can last from a few weeks to several months, the salty water is absorbed from the lagoon to the conduit of the submarine spring, which leads to the salinization of the underlying karst aquifer. The monitoring of flow, water specific conductivity and water temperature data from the karst submarine spring is a key element of the research project to understand the hydrogeological functioning of the karst aquifer under normal conditions or during flow reversal periods. This monitoring allows the characterization of the (in- or out-) flows at the submarine spring, the evaluation of the volume or mass balances, the identification of the hydrogeological and physico-chemical responses (water temperature, specific conductivity) observed within the karstic aquifer. Here, we present the means implemented offshore to acquire data at the submarine spring over the 06/25/2019 - 12/31/2022 time period together with lagoon water's physico-chemical parameters and levels and onshore groundwater's physico-chemical parameters and levels acquired at springs and boreholes from the karst aquifer.

Effects of agricultural land use on fluvial carbon dioxide, methane and nitrous oxide concentrations in a large European river, the Meuse (Belgium).

We report a data-set of CO2, CH4, and N2O concentrations in the surface waters of the Meuse river network in Belgium, obtained during four surveys covering 50 stations (summer 2013 and late winter 2013, 2014 and 2015), from yearly cycles in four rivers of variable size and catchment land cover, and from 111 groundwater samples. Surface waters of the Meuse river network were over-saturated in CO2, CH4, N2O with respect to atmospheric equilibrium, acting as sources of these greenhouse gases to the atmosphere, although the dissolved gases also showed marked seasonal and spatial variations. Seasonal variations were related to changes in freshwater discharge following the hydrological cycle, with highest concentrations of CO2, CH4, N2O during low water owing to a longer water residence time and lower currents (i.e. lower gas transfer velocities), both contributing to the accumulation of gases in the water column, combined with higher temperatures favourable to microbial processes. Inter-annual differences of discharge also led to differences in CH4 and N2O that were higher in years with prolonged low water periods. Spatial variations were mostly due to differences in land cover over the catchments, with systems dominated by agriculture (croplands and pastures) having higher CO2, CH4, N2O levels than forested systems. This seemed to be related to higher levels of dissolved and particulate organic matter, as well as dissolved inorganic nitrogen in agriculture dominated systems compared to forested ones. Groundwater had very low CH4 concentrations in the shallow and unconfined aquifers (mostly fractured limestones) of the Meuse basin, hence, should not contribute significantly to the high CH4 levels in surface riverine waters. Owing to high dissolved concentrations, groundwater could potentially transfer important quantities of CO2 and N2O to surface waters of the Meuse basin, although this hypothesis remains to be tested.