Interfacially Confined Dynamic Reaction Resulted to Fluorescent Nanofilms Depicting High-Performance Ammonia Sensing.

Sensing materials innovation plays a crucial role in the development of high-performance film-based fluorescent sensors (FFSs). In our current study, we present the innovative fabrication of four fluorescent nanofilms via interfacially confined dynamic reaction of a specially designed fluorescent building block, a new boron-coordinated compound (NI-CHO), with a chosen one, benzene-1,3,5-tricarbohydrazide (BTH). The nanofilms as prepared are robust, uniform, flexible, and thickness tunable, at least from 40 to 1500 nm. The fabricated FFSs based on Film 3, one of the four nanofilms, shows highly selective and fully reversible response to NH3 vapor with an experimental detection limit of <0.1 ppm and a response time of 0.2 s. The unprecedented high performance of the nanofilm is ascribed to the specific quenching of its fluorescence emission owing to formation of an excited-state complex between the sensing unit and the analyte molecule. Efficient mass transfer also contributes to the high performance owing to the porous adlayer structure of the nanofilm. This work provides an example to show how to develop a high-performance sensing film via controlling the film's structure, especially the thickness.

Ultrathin near-infrared transmitting films enabled by deprotonation-induced intramolecular charge transfer of a dopant.

Near-infrared transparent films demonstrate important applications in many fields, but how to eliminate light interference from ultraviolet-visible region and how to tackle the trade-off effect between film thickness and transmittance remain as challenges. Herein, we report a near-infrared transparent film that achieves high-efficient combination of thin thickness (16 µm), suitable cut-off wavelength (890 nm), and ideal transmittance (TNIR > 90%, TVis < 1%). Moreover, the film is photo-chemically stable, heating resistance and moisture insensitive. The key component of the film is a complex of a specially designed boron compound containing a perylene monoimide unit (PMI-CBN) with an organic base 1,8-diazabicyclo[5,4,0]undec-7-ene. The complex depicts red-shifted absorption from 709 to 943 nm owing to deprotonation of the N-H group of PMI-CBN. Dispersion of the complex in polymethyl methacrylate results in the high-performance film. As demos, the film is successfully used for night vision imaging and information encryption.

Insight into the Clustering-Triggered Emission and Aggregation-Induced Emission Exhibited by an Adamantane-Based Molecular System.

Chemical clustering of a nonemissive and non-AIEgen of Cb-Ph endowed a molecular system (Ad-4CP) with unique dual emissions in the solution state, a typical clustering-triggered emission (CTE), and high emission efficiency in the aggregated state, an aggregation-induced emission (AIE). The CTE was ascribed to intramolecular charge transfer (CT); however, the AIE was ascribed to both intra- and intermolecular CTs. The two-level CTs make the Ad-4CP exhibit remarkable excitation-dependent emissions. We believe that the present work not only delivers a peculiar molecular system with both CTE and AIE properties but also provides an example on how molecular engineering promotes the rational design of CTE and AIE systems via clusterization of suitable structural units.