RESUMEN
Newly synthesized donor-acceptor (D-A) type of conjugated copolymer (PCTV-BTzF) with semi-fluorinated alkyl side chains, which has good solubility in common organic solvents, is described. Unlike polymers with hydrocarbon-based alkyl side chains, semi-fluorocabonated polymer leads to intriguing results. First, the self-organization behavior of the semi-fluoroalkyl side chains by the self-aggregate propensity between hydrocarbon and fluorocarbon induces patterned microstructural morphology in polymer films; second, it dominates the molecular orientation of polymers with planar back structure. Such unusual properties of the polymer with semi-fluoroalkyl side chains compared to that with the hydrocarbon ones are verified and characterized though various systematic characterizations, including temperature-dependent UV-Vis absorption spectroscopy, atomic force microscopy, and 2D-grazing incident X-ray diffraction measurement. As a result, PCTV-BTzF-based OFETs show the maximum p-type field-effect mobility of 1.02 cm2 V-1 s-1 in the 200 °C annealed films.
Asunto(s)
Furanos/química , Hidrocarburos Fluorados/química , Polímeros/química , Estructura Molecular , Tamaño de la Partícula , Polímeros/síntesis química , Solubilidad , Propiedades de SuperficieRESUMEN
The semi-fluorinated alkyl (SFA) side chain introduced thienylenevinylene (TV)-based p-type polymer, PC12TVC5F7T, was synthesized for use in organic thin-film transistors (OTFTs). Herein, we investigated the influence of SFA side chains on the morphology, molecular orientation, and crystalline structure using a combination of atomic force microscopy (AFM), scanning electron microscopy (SEM), two-dimensional (2D) grazing-incidence wide-angle X-ray scattering (GIWAXS), and density functional theory (DFT) calculations. Interestingly, the incorporation of SFA side chains led to the evolution of plate-like large-sized domains and also strongly intermolecular stacked high crystalline structures. Furthermore, due to the strong interactions between SFA side chains, several (00h) peaks could be observed for PC12TVC5F7T, in spite of their fairly large dihedral angle. As a result, due to the well-developed microstructure of PC12TVC5F7T, the OTFT devices based on it exhibited a high hole mobility of 1.91 cm2 V-1 s-1, which is an outstanding value among the poly(thiophene) derivative polymers. These observations indicate that large-sized domains and strongly intermolecular stacked high crystalline structures, which are beneficial for charge carrier transport, could be attained by the introduction of SFA side chains, further enhancing the performance of the OTFTs.
RESUMEN
SFA-PQT exhibits self-assembly via a fluorophobic effect in a non-fluorous solvent, which leads to an enhanced electrical performance. Ambipolar transistors and inverters with p- and n- type bilayers are enabled by the unique thermally reversible soluble-insoluble properties of SFA-PQT. More importantly, the hydrophobicity of SFA-PQT facilitates orthogonal hydrophobic patterning and a patterned inverter exhibits low voltage dissipation, a narrow transition zone, a high gain value, and negligible hysteresis.