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1.
J Am Chem Soc ; 146(27): 18418-18426, 2024 Jul 10.
Artículo en Inglés | MEDLINE | ID: mdl-38812275

RESUMEN

Zeolite nanosheets with an extremely thin thickness featuring both unique pore systems and low diffusion resistance have the potential to achieve enhanced catalytic performance in the conversion of bulky molecular biomass. The preparation of unit-cell level nanosheets generally requires complex and costly multifunctional surfactants or an organic structure-directing agent (OSDA). Commercially available and environmentally friendly ionic liquids can also direct the structure of zeolite nanosheets by π-π stacking when these kinds of OSDA are used in large amount. Herein, we first report unit-cell-sized silicogermanate nanosheets of NS-IM-20 (UWY topology), 5 nm in thickness, which were synthesized at a relatively low ionic liquid concentration with the assistance of halide ion (Cl-). The Pd-loaded NS-IM-20 nanosheets with a hierarchical porosity and moderate acidity act as promising bifunctional catalysts for selective biomass conversion.

2.
Small ; 20(28): e2307323, 2024 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-38349049

RESUMEN

Layered zeolitic silicates and corresponding interlayer-expanded porous materials exhibit attractive application potential in wide fields. Nonetheless, designable synthesis and structure analysis of layered silicates remain challenging. Herein, two kinds of layered silicates are synthesized using different di-quaternary ammonium-type organic structure-directing agents (OSDAs). Their crystal structures are analyzed and verified by 3D electron diffraction (3D ED) and high-resolution TEM imaging. The suitable configurations of OSDA can lead to desirable interlayer states. Additionally, two new zeolite structures both with 12-membered ring (MR) channels intersected by 8 MR channels and larger interlayer spaces are constructed from layered silicate precursors by interlayer silylation. The new zeolitic material exhibits potential application in adsorption of organic pollution and catalytic reaction. This study is expected to develop versatile ways for the design and synthesis of layered silicates even zeolites and provide references in characterizing layered materials and zeolites as well.

3.
Chemistry ; 30(15): e202303657, 2024 Mar 12.
Artículo en Inglés | MEDLINE | ID: mdl-38116930

RESUMEN

In zeolite frameworks, double four-ring (d4r) configurations are among the most frequent composite building units. The composition variations in d4r units greatly influence the energy and structural modifiability of the zeolitic framework. The introduction of germanium, with a larger ionic radius than silicon or aluminum, not only reduces the energy constraints of d4r in the nucleation and crystal growth of zeolites, but also opens a new window for constructing novel crystalline structures, especially with large or extra-large pores and channels. Ge-enriched d4r units endow germanosilicates with structure diversity readily for post treatments. Promising catalytic materials have been gradually developed and increasingly studied by direct synthesis or post-synthetic isomorphous substitution for Ge. This review focuses on the recent progress in the synthesis, modification, and catalytic application of d4r-containing zeolites, including germanosilicates, aluminosilicates, and silicates.

4.
BMC Oral Health ; 24(1): 827, 2024 Jul 22.
Artículo en Inglés | MEDLINE | ID: mdl-39034391

RESUMEN

BACKGROUND AND AIM: 3D fusion model of cone-beam computed tomography (CBCT) and oral scanned data can be used for the accurate design of root canal access and guide plates in root canal therapy (RCT). However, the pose accuracy of the dental pulp and crown in data registration has not been investigated, which affects the precise implementation of clinical planning goals. We aimed to establish a novel registration method based on pulp horn mapping surface (PHMSR), to evaluate the accuracy of PHMSR versus traditional methods for crown-pulp registration of CBCT and oral scan data. MATERIALS AND METHODS: This vitro study collected 8 groups of oral scanned and CBCT data in which the left mandibular teeth were not missing, No. 35 and No. 36 teeth were selected as the target teeth. The CBCT and scanned model were processed to generate equivalent point clouds. For the PHMSR method, the similarity between the feature directions of the pulp horn and the surface normal vectors of the crown were used to determine the mapping points in the CBCT point cloud that have a great influence on the pulp pose. The small surface with adjustable parameters is reconstructed near the mapping point of the crown, and the new matching point pairs between the point and the mapping surface are searched. The sparse iterative closest point (ICP) algorithm is used to solve the new matching point pairs. Then, in the C + + programming environment with a point cloud library (PCL), the PHMSR, the traditional sparse ICP, ICP, and coherent point drift (CPD) algorithms are used to register the point clouds under two different initial deviations. The root square mean error (RSME) of the crown, crown-pulp orientation deviation (CPOD), and position deviation (CPPD) were calculated to evaluate the registration accuracy. The significance between the groups was tested by a two-tailed paired t-test (p < 0.05). RESULTS: The crown RSME values of the sparse ICP method (0.257), the ICP method (0.217), and the CPD method (0.209) were not significantly different from the PHMSR method (0.250). The CPOD and CPPD values of the sparse ICP method (4.089 and 0.133), the ICP method (1.787 and 0.700), and the CPD method (1.665 and 0.718) than for the PHMSR method, which suggests that the accuracy of crown-pulp registration is higher with the PHMSR method. CONCLUSION: Compared with the traditional method, the PHMSR method has a smaller crown-pulp registration accuracy and a clinically acceptable deviation range, these results support the use of PHMSR method instead of the traditional method for clinical planning of root canal therapy.


Asunto(s)
Tomografía Computarizada de Haz Cónico , Pulpa Dental , Imagenología Tridimensional , Tomografía Computarizada de Haz Cónico/métodos , Humanos , Pulpa Dental/diagnóstico por imagen , Técnicas In Vitro , Imagenología Tridimensional/métodos , Corona del Diente/diagnóstico por imagen , Corona del Diente/anatomía & histología , Modelos Dentales , Tratamiento del Conducto Radicular/métodos , Prueba de Estudio Conceptual
5.
Angew Chem Int Ed Engl ; 63(10): e202318298, 2024 Mar 04.
Artículo en Inglés | MEDLINE | ID: mdl-38240576

RESUMEN

A multidimensional extra-large pore zeolite with highly hydrothermal stability, denoted as -IRT-HS, has been developed successfully, starting from Ge-rich germanosilicate precursor hydrothermally directed by a small and commercially available piperidinium-type organic structure-directing agent (OSDA). -IRT-HS, with the supermicropores, is structurally analogues to 28-membered ring -IRT topology as confirmed by various spectroscopic techniques. And it is the high-silica (Si/Ge=58) zeolite with the largest pore size as well. Notably, using acid-washed as-made Ge-rich -IRT precursor as the silicon source is crucial to restore partially collapsed structure into a stable framework by OSDA-assisted recrystallization. The calcined -IRT-HS maintains a high crystallinity, even when stored in a humid environment for extended periods or directly exposed to water. Additionally, high silica Al-containing analogue is also readily synthesized, serving as an active solid-acid catalyst in 1,3,5-triisopropylbenzene cracking reaction, yielding an impressive initial conversion up to 76.1 % much higher than conventional large-pore Beta zeolite (30.4 %). This work will pave the way for the designed synthesis of targeted high-silica zeolites with stable and extra-large pore frameworks, mimicking the structures of existing Ge-rich counterparts.

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