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1.
Environ Sci Technol ; 48(3): 1475-83, 2014.
Artículo en Inglés | MEDLINE | ID: mdl-24387296

RESUMEN

Measurements on truck-dominated freeways in southern California have offered a unique opportunity to track emission changes that have occurred due to the implementation of local and state regulations affecting heavy-duty diesel trucks. These regulations have accelerated fleet turnover to cleaner and newer trucks. In this study, a mobile platform was used to measure nitrogen oxides (NOX), black carbon (BC), and ultrafine particles (UFPs) on diesel-dominated southern California freeways. Fleet-averaged fuel-based emission factors were calculated for diesel trucks and the results showed NOX and BC emissions were reduced by 40% or more between 2009 and 2011, but there were no statistically significant reductions for UFP. Technologies associated with these new trucks, mainly diesel particulate filters, have changed the physical characteristics of diesel particulate, shifting the size distribution of such particles to smaller modes (10-20 nm). In addition, integration of 2007 MY trucks into the fleet was also observed in on-road ratios of nitrogen dioxide (NO2) and NOX. NO2/NOX ratios steadily increased from 0.23 ± 0.06 in 2009 to 0.30 ± 0.03 in 2010 but plateaued and declined in 2011.


Asunto(s)
Contaminantes Atmosféricos/análisis , Contaminación del Aire/prevención & control , Monitoreo del Ambiente/métodos , Vehículos a Motor/normas , Material Particulado/análisis , Emisiones de Vehículos/análisis , Contaminación del Aire/legislación & jurisprudencia , California , Monitoreo del Ambiente/legislación & jurisprudencia , Filtración , Regulación Gubernamental , Vehículos a Motor/legislación & jurisprudencia , Óxidos de Nitrógeno/análisis , Hollín/análisis
2.
Atmos Environ (1994) ; 63: 250-260, 2012 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-24415904

RESUMEN

High ambient ultrafine particle (UFP) concentrations may play an important role in the adverse health effects associated with living near busy roadways. However, UFP size distributions change rapidly as vehicle emissions dilute and age. These size changes can influence UFP lung deposition rates and dose because deposition in the respiratory system is a strong function of particle size. Few studies to date have measured and characterized changes in near-road UFP size distributions in real-time, thus missing transient variations in size distribution due to short-term fluctuations in wind speed, direction, or particle dynamics. In this study we measured important wind direction effects on near-freeway UFP size distributions and gradients using a mobile platform with 5-s time resolution. Compared to more commonly measured perpendicular (downwind) conditions, parallel wind conditions appeared to promote formation of broader and larger size distributions of roughly one-half the particle concentration. Particles during more parallel wind conditions also changed less in size with downwind distance and the fraction of lung-deposited particle number was calculated to be 15% lower than for downwind conditions, giving a combined decrease of about 60%. In addition, a multivariate analysis of several variables found meteorology, particularly wind direction and temperature, to be important in predicting UFP concentrations within 150 m of a freeway (R2 = 0.46, p = 0.014).

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