RESUMEN
Chemical reconstruction of bismuth oxyiodides using bicarbonates is tried to selectively grow (BiO)2 CO3 edge side. Orthorhombic o-Bi5 O7 I undergoes a total reconstruction process by its phase transformation into tetragonal (BiO)2 CO3 (BOC-o) to form a well-aligned nanosheet array with maximally exposing CO3 2- moiety at the edge side. The post-reconstruction BOC-o catalyst achieved 100 % Faradaic efficiency at -0.86â V vs. RHE for CO2 -to-formate conversion. However, another conservative reconstruction of tetragonal t-BiOI into tetragonal (BiO)2 CO3 (BOC-t) exposed majorly a less reactive [BiO]+ layer. At low overpotential regions, the catalytic cycle of BOC-o begins with the initial conversion of the CO3 2- moiety into formate at the [-OBi-(CO3 )-BiO-] site, but at high overpotential regions, the [BiO]+ layer undergoes reduction to metallic Bi and multi-catalytic species proceed with CO2 reduction. Otherwise, the deactivation of Bi+ site by an organic molecule switched on another catalysis of proton reduction, preventing CO2 reduction.