Tailored magnetic carbon allotrope catalytic micromotors for 'on-chip' operations.

Carbon allotrope micromotors are proposed as active components in lab-on-a-chip systems. Highly rough carbon black tubular engines are used for fluorescence detection operations. The potential of ultrafast lectin carbon nanonotube micromotors with an inner anti-biofouling layer for selective transport of sugar modified particles (as cell mimics) in human plasma is illustrated.

Labs-on-a-chip meet self-propelled micromotors.

This frontier review covers recent advances in the field of nanomaterial-based micromotors for the development of novel labs-on-a-chip (LOCs). In this review, we will discuss how carbon nanomaterials "on-board" of micromotors offer particular promise for diverse LOC applications. New trends in the field, directed towards the use of quantum dots and nanoparticles as functional materials for sophisticated micromotors, will be reviewed. Micromotor strategies using functionalized catalytic microengines to capture and transport (bio)molecules between the different reservoirs of LOC devices will also be covered. These recent advances are bringing closer our hopes for personalized medicine and food safety assurance, among others.

Multiparametric optimization of a new high-sensitive and disposable mercury (II) electrochemical sensor.

An electrochemical sensor for mercury (II) determination was developed by modifying the surface of a commercial screen-printed carbon electrode (SPCE) with a polystyrene sulfonate-NiO-carbon nanopowder composite material. Mercury measurements were performed by differential pulse anodic stripping voltammetry (DPASV). Sensor composition and measurement conditions were optimized using a multivariate experiment design. A screening experiment by using a Plackett-Burman design was first performed in order to determine the main contributing factors to the electrochemical response. The most important factors were employed to establish the interactions between different experimental variables and get the best conditions for mercury determination. For this purpose, a five level central composite design and a response surface methodology were used. The optimized method using the developed NiO-PSS-SPCE sensor presents a very low limit of detection of 0.021 µg L(-1) and a linear response over two concentration ranges with two different slopes, from 0.05 to 2.0 µg L(-1) and between 2.0 and 75 µg L(-1). The sensor was successfully applied to mercury determination in water samples.