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1.
Knee ; 36: 27-32, 2022 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-35447466

RESUMEN

BACKGROUND: Femoral component fracture is a rare complication of total knee arthroplasty (TKA). CASE: We report a case of oxidized zirconium (Oxinium) femoral component fracture after total knee arthroplasty. The fracture site was the junction of the central and medial flanges. The patellar component and polyethylene insert had delamination at the contact point of the fracture line, and the tibial tray had loosening at the medial side. There was no cement adherence at the component fracture site, suggesting that debonding had occurred at the cement-implant interface in this area. Examination with a scanning electron microscope revealed beach marks, which are characteristic findings of metal fatigue. CONCLUSION: We considered that the cause of femoral component fracture was a fatigue fracture due to poor fixation of the component to the bone caused by poor osteotomy technique or poor cementing technique. To our knowledge, this is the first case of Oxinium femoral component fracture.


Asunto(s)
Artroplastia de Reemplazo de Rodilla , Fracturas del Fémur , Prótesis de la Rodilla , Artroplastia de Reemplazo de Rodilla/efectos adversos , Artroplastia de Reemplazo de Rodilla/métodos , Humanos , Prótesis de la Rodilla/efectos adversos , Polietileno , Falla de Prótesis , Circonio
2.
Chem Commun (Camb) ; (36): 3794-6, 2006 Sep 28.
Artículo en Inglés | MEDLINE | ID: mdl-16969460

RESUMEN

Selective monoiodination of aromatic compounds such as dimethoxybenzene has been successfully achieved with I+, which is generated by anodic oxidation of I2 in acetonitrile, using micromixing.


Asunto(s)
Electroquímica , Hidrocarburos Aromáticos/química , Hidrocarburos Yodados/síntesis química , Yodo/química , Microfluídica , Acetonitrilos/química , Anisoles/química , Electrodos , Espectrometría de Masas , Oxidación-Reducción
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