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Ion hydration plays a crucial role in numerous fundamental processes. Various spectroscopic methods are employed to investigate the slowing down of hydration bond dynamics in the proximity of both anions and cations. To date, most of these studies have primarily focused on the properties of binary systems. However, in comparison to ion-water binary systems, ternary systems that involve ions, water, and organic matter are more prevalent in nature and provide more realistic insights into biological processes. This study focuses on ion hydration in water and alcohol mixture using terahertz spectroscopy and x-ray diffraction (XRD). The results reveal a distinct behavior depending on the type of alcohol used. Specifically, the presence of both methanol and ethanol results in the disappearance of absorption peaks associated with NaCl hydrate at low temperatures. In contrast, tert-butanol does not exhibit such an effect, and isopropanol demonstrates a more complex response. By combining these terahertz spectroscopic findings with low-temperature XRD data, we gain insights into the formation, or lack thereof, of NaCl · 2H2O hydrate crystals. Crucially, our observations suggest a dominant correlation between the polarity of the alcohol molecules and its impact on the Na+ hydration. Strongly polar alcohols preferentially solvating the Na+ ion lead to the failure of hydrate formation, while weakly polar alcohols do not have this effect.
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The electromagnetically induced transparency (EIT) effect realized by metasurfaces have potential for narrowband filtering due to their narrow bandwidth. In optics, bound states in the continuum (BIC) can produce strong localized resonances, which means that light can be trapped and stored for long periods of time to produce very high Q-factors. This has potential applications in designing highly efficient sensors and narrow bandpass filters. Here, we present two metal-flexible dielectric metasurfaces consisting of copper structures and polyimide substrates. Quasi BICs are obtained by breaking C2 symmetry of the metal structures. Resonance-captured quasi-BICs with ultra-high q-factor resonances satisfy the dark modes required to realize the EIT and couple to the bright modes in the structure to achieve narrowband filtering. The peak transmission rates are around 0.9 at 0.29 THz-0.32 THz and 0.23 THz-0.27 THz, respectively. Our results have practical implications for the realization of low-frequency terahertz communications.
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The terahertz (THz) band has a great potential for the development of communication technology, but it has not been fully utilized due to the lack of practical devices, especially actively controllable multifunctional devices. Here, we propose and demonstrate a Ge2Sb2Te5 (GST)-based metamaterial device, where an actively controllable function is experimentally verified by inducing the crystallization process with thermal activation. Cross-polarization conversion in the reflection mode and circular-to-linear polarization conversion in the transmission mode are obtained under crystalline and amorphous GST conditions, respectively. The combination of GST and THz waves has a wide range of applications and will further advance the THz field.
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In this work, GHz and THz complex dielectric spectra of a polyethylene glycol dimethyl ether (2000 g/mol) aqueous solution were studied. The reorientation relaxation of water in this kind of macro-amphiphilic molecule solution can be well described by three Debye models, including under-coordinated water, bulk-like water [water molecules in a tetrahedral hydrogen bond network (bulk water) and bulk water molecules affected by hydrophobic groups], and slow hydrating water (water molecules donating hydrogen bonds to hydrophilic ether groups). The reorientation relaxation timescales of bulk-like water and slow hydration water both show increases with concentration from 9.8 to 26.7 ps and from 46.9 to 100.1 ps, respectively. By estimating the ratios of the dipole moment of slow hydration water to the dipole moment of bulk-like water, we calculated the experimental Kirkwood factors of bulk-like and slow hydrating water. The experimental Kirkwood factor of bulk-like water increased from 3.17 to 3.44 with concentrations, while the experimental Kirkwood factor of slow hydrating water roughly remained constant at 4.13 from concentrations of 15%-60%. The estimated water molecule numbers of three water components around monomers also confirm our sorting for water components.
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Moiré configurations have recently attracted much attention due to their ability to enhance photonic responses and manipulate surface waves in the subwavelength ranges. However, previous studies have usually been focused on natural hyperbolic materials with limitations on patterning procedures, controlling rotation angles, and merely manipulating electric surface plasmons. Here, we theoretically and numerically investigate a novel magnetic moiré hyperbolic metasurface in the terahertz region, which enables two types of topological transition and a plethora of unusual magnetic moiré effects (magnetic surface wave manipulation, dispersion engineering, magic angles, spacer-dependent topological transition, and local field enhancement). This work extends twistronics and moiré physics to the terahertz region and magnetic polaritons, with potential applications in quantum physics, energy transfer, and planarized magnetic plasmonic devices.
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Various kinds of metasurfaces have been proposed because they can be tailored to achieve the desired modulations on electromagnetic wave that do not occur in nature. Compared to conventional metamaterials, coding metasurfaces integrated with information science theory possess numerous distinctive advantages - simple design, time-saving and compatibility with digital devices. Here we propose terahertz multifunctional anisotropic reflective metasurfaces with a metal-insulator-metal cavity structure whose top constructional layer consists of a pair of gold arc-rings and a gold cut-wire located between them. Two different functions of narrow-band absorption and broadband polarization conversion are realized based on different coding matrices using the binary codes '0' and '1'. Furthermore, we integrate a specific coding metasurface with vanadium dioxide (VO2) to realize a temperature-controlled active metasurface. Through the temperature change, dynamic functionalities switching between a narrow-band polarization converter with a polarization conversion ratio over 94% and an efficient low-pass filter are achieved under the phase transition of VO2, and the active metasurface is polarization independent. The proposed coding metasurfaces are verified numerically and experimentally, and have promising applications in terahertz modulation and functional devices.
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The interaction of MgCl2 with H2O is heavily involved in biological and chemical processes. In this work, freezing-induced hydrate formation from MgCl2 aqueous solution was monitored using terahertz time-domain spectroscopy. At low temperatures, two phase transitions from brine to hydrate formation could be clearly observed, and the formation of hydrate was accompanied by the emergence of new THz fingerprint peaks at 1.02, 1.56, and 1.84 THz, respectively. Integrating XRD and quantum chemical calculations, we attributed the absorption peaks to the vibrational modes of the formed MgCl2·12H2O. This demonstrates the potential of THz spectroscopy for application in the detection of biological processes in low-temperature environments, such as cell freezing.
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Espectroscopía de Terahertz , Análisis Espectral , VibraciónRESUMEN
We performed THz and GHz dielectric relaxation spectroscopy to investigate the reorientational dynamics of water molecules in the hydration shell of amphiphilic hyper-branched poly-ethylenimine (HPEI). Four Debye equations were employed to describe four types of water in the hydration shell, including bulk-like water, under-coordinated water, slow water (water molecules hydrating the hydrophobic groups and water molecules accepting hydrogen bonds from the NH2 groups) and super slow water (water molecules donating hydrogen bonds to and accepting hydrogen bonds from NH groups). The time scales of undercoordinated and bulk-like water show a slight decline from 0.4 to 0.1 ps and from 8 to 2 ps, respectively. Because of hydrophilic amino groups, HPEI molecules exhibit a strong retardation effect, where the time scales of slow and super slow water increase with concentration from 17 to 39.9 ps and from 88 to 225 ps, respectively.
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In terahertz (THz) technologies, generation and manipulation of THz waves are two key processes usually implemented by different device modules. Integrating THz generation and manipulation into a single compact device will advance the applications of THz technologies in various fields. Here, we demonstrate a hybrid nonlinear plasmonic metasurface incorporating an epsilon-near-zero (ENZ) indium tin oxide (ITO) layer to seamlessly combine efficient generation and manipulation of THz waves across a wide frequency band. The coupling between the plasmonic resonance of the metasurface and the ENZ mode of the ITO thin film enhances the THz conversion efficiency by more than 4 orders of magnitude. Meanwhile, such a hybrid device is capable of shaping the polarization and wavefront of the emitted THz beam via the engineered nonlinear Pancharatnam-Berry (PB) phases of the plasmonic meta-atoms. The presented hybrid nonlinear metasurface opens a new avenue toward miniaturized integrated THz devices and systems with advanced functionalities.
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Active control of metasurfaces has attracted widespread attention because of the adjustable electromagnetic properties obtained. Here we designed and experimentally studied a dynamically controllable polarization converter in the terahertz band. By designing the structural parameters and utilizing the insulator-to-metal phase transition of vanadium dioxide and principle of current resonance, dynamic tunability of the polarization conversion function from dual-broadband (0.45â¼0.77 THz and 0.97â¼1.2 THz) to ultra-broadband (0.38â¼1.20 THz) can be realized with a high polarization conversion ratio. The scheme proposed here can find potential applications in integrated terahertz systems, sensing, imaging and communications areas.
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Originating from the study of topological photonic crystals (TPCs), analogues of the quantum spin Hall effect have been used as a potential way to control the propagation of electromagnetic waves. Due to the topological robustness of the spin TPCs, the edge states along the interface between the trivial and topological areas are topologically protected and not reflected from structural defects and disorders. Here, on the basis of the time-spatial reversal symmetry and topological defect theory, we demonstrate broadening of the edge state bandwidth in spin TPCs made of regular metallic cross structures by simultaneously deforming the hexagonal honeycomb lattice and adjusting the rotation angle. Due to the simultaneous tuning of the two parameters, the designed spin TPCs possess more flexibility. Topologically protected one-way propagating edge states are observed in the terahertz regime, where electromagnetic waves propagate along sharp corners without backscattering. Our findings offer the potential application for topological devices in terahertz technology and are beneficial for the development of 6G mobile communications.
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Interest in asymmetric transmission (AT) at terahertz frequencies has increased dramatically in recent years. We present an all-silicon metamaterial to achieve the AT effect for linearly polarized electromagnetic waves in the terahertz regime. The metamaterial is constructed by rectangular silicon pillars and a thick silicon substrate. The magnetic Mie resonance excited by the incident polarized terahertz wave contributes to the AT effect, which is verified by the field distributions. In addition, the rotation angle and dimensions of the silicon pillars are shown to have a great influence on the AT efficiency. The proposed metamaterial with straightforward design has promising applications in polarization control scenarios.
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Photoconductive antenna (PCA) is a widely used terahertz (THz) radiation source, but its low radiated power limits the signal-to-noise ratio and bandwidth in THz imaging and spectroscopy applications. Here, we achieved significant PCA power enhancement through etching nanograting directly on the surface of the PCA substrate. The integrated nanograting not only maximizes the generation of photocarriers, but also benefits the bias electric field loaded on the photocarriers. Comparing with the conventional PCA, our PCA realizes a frequency independent THz power enhancement of 3.92 times in the range of 0.05-1.6 THz. Our results reported here not only provide a new method for increasing the THz power of PCAs, but also reveal another way that artificial nanostructures affect the PCAs, which paves the way for the subsequent researches of next-generation PCAs.
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The absorption region of a water-based absorber was expanded by introducing tetramethylurea (TMU) into the inclusion, whose dielectric properties are tunable through the concentration of TMU. The dielectric spectroscopy of a TMU/water mixture was deconstructed using a Debye model. We designed a four-layer ultra-broadband microwave absorber with a supernatant micro-structure. Simulation and experiment results indicate that the absorber can achieve 90% perfect absorption, covering a broad frequency range of 4-40 GHz. The concentration dependence of the absorber was also studied experimentally and numerically. The concentration control provides a more practical and large frequency-region modulation of perfect absorption.
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A rotation-angle variable polarization rotator is proposed and demonstrated using an all-dielectric metasurface doublet. Such a transmissive device can conveniently rotate the polarization of incident light by any desired angles by mechanically changing the relative angle of the double metasurface layers regardless of the incident state of polarization. Under certain conditions the device acts as a full phase modulator for the circularly polarized incident wave. Hence, it has a promising application in polarization and phase control.
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Taking advantage of the tunable conductivity of graphene under high terahertz (THz) electric field, a graphene-metal hybrid metamaterial consisting of an array of three adjoined orthogonally oriented split-ring resonators (SRRs) is proposed and experimentally demonstrated to show a maximum modulation depth of 23% in transmission when the THz peak field reaches 305 kV/cm. The transmission of the sample is dominated by the antisymmetric and symmetric resonant modes originating from the strong magneto-inductive and conductive coupling among the three SRRs, respectively. Numerical simulations and model calculations based on a coupled oscillator theory were performed to explain the modulation process. It is found that the graphene coating impairs the resonances by increasing the damping of the modes and decreasing the coupling between the SRRs whereas the strong THz field restores the resonances by decreasing the conductivity of graphene.
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OBJECTIVE: This study aimed to investigate the effectiveness and safety of a method combining double-balloon catheter for cervical ripening and intravenous drip of oxytocin on the induction of term labor, providing the reference for clinical safety. METHODS: A total of 120 pregnant women with a gestation between 37+0 and 41+6 weeks, indications of labor induction, singleton pregnancy with cephalic presentation were enrolled. The patients were divided into the research group receiving cervical dilation balloon combined with intravenous drip of oxytocin and the control group receiving an intravenous drip of oxytocin at a concentration of 0.5% for labor induction (n = 60 for each). The effectiveness and safety of labor induction were evaluated by the rates of successful cervical ripening promotion and labor induction, as well as the vaginal delivery rate, induced labor time, total duration of labor, the total amount of postpartum hemorrhage within 24 h after giving birth, the incidences of postpartum hemorrhage, cervical laceration, puerperal infection and neonatal outcomes. RESULTS: There was no statistical difference in the basal demographic and clinical characteristics, including ages, gestational weeks, delivery times and Bishop scores at admission between two groups. The rate of successful cervical ripening promotion (research vs. control = 90.00% vs. 55.00%), the rate of successful induction (95.00% vs. 40.00%), the vaginal delivery rate (93.33% vs. 63.33%), the induced labor time (15.03 ± 5.40 vs. 30.68 ± 10.82 h), and the total duration of labor (8.12 ± 2.65 vs. 15.01 ± 6.06 h) were significantly different between two groups (all P < 0.05). There was no significant difference in the total amount of postpartum hemorrhage, incidences of postpartum hemorrhage, cervical laceration, puerperal infection as well as the neonatal outcomes, including neonatal weight, neonatal asphyxia and incidence of meconium aspiration syndrome between two groups. CONCLUSIONS: Compared to labor induction of oxytocin, the method combining double-balloon catheter for cervical ripening and intravenous drip of oxytocin for the induction of term labor has a higher vaginal delivery rate, shorter total duration of labor, and does not increase the incidences of postpartum hemorrhage and neonatal infection, which is a more effective and safer method for induction of term labor.
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Cateterismo , Dilatación , Trabajo de Parto Inducido/métodos , Oxitócicos/administración & dosificación , Oxitocina/administración & dosificación , Administración Intravaginal , Adulto , Cateterismo/métodos , Maduración Cervical , Parto Obstétrico , Femenino , Humanos , Infusiones Intravenosas , Inicio del Trabajo de Parto , Oxitocina/farmacología , Hemorragia Posparto/tratamiento farmacológico , Embarazo , Nacimiento a Término , Factores de Tiempo , Enfermedades del Cuello del Útero/etiologíaRESUMEN
We experimentally demonstrate that a coupled metamaterial composed of sub-wavelength split-ring-resonators (SRRs) and closed-ring-resonators (CRRs) can tailor the plasmon-induced-transparency (PIT) resonances when the external electric field is parallel to the gaps of SRRs. Rotating or moving SRRs in vertical direction plays a critical role in the EIT functionality, while an excellent robust performance can be acquired via moving SRRs in the horizontal direction. Based on the results, a polarization-independent and polarization-dependent planar metamaterial are designed, fabricated and measured. In contrast to the spectral property of the polarization-independent medium, the polarization-dependent one is featured by isolated PIT phenomena in the frequency-domain, with respect to the horizontal and vertical polarized incident beam. Transmission responses of the PIT metamaterial are characterized with terahertz time-domain spectroscopy, showing a good agreement with the rigorous numerical simulation results. The presented work delivers a unique way to excite and modulate the PIT response, toward developing polarization-independent and polarization-dependent slow-light building blocks, ultrasensitive sensors and narrow-band filters functioning in the THz regime.
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The control of light-matter interaction in metasurfaces offers an unexplored potential for the excitation and manipulation of light. Here, we combine experimental terahertz time-domain spectroscopy and near-field scanning terahertz microscopy to demonstrate the role of reciprocal vectors in the transmission and plasmonic resonances of quasicrystal metasurfaces. An investigation of two-dimensional metasurface structures with different rotationally symmetric quasicrystal arrangements demonstrates that the transmission minima resulting from Wood's anomaly are directly related to the surface plasmon resonances. We also find that the surface plasmon resonances of the quasicrystal metasurface were determined by the reciprocal vectors, which could be well explained by the coupling condition of the resonances, and the characteristic frequencies remain un-shifted under various slit sizes. Our findings demonstrate a new potential in developing novel plasmonic metasurfaces.
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We demonstrated a structure with periodic cylinders arranged bilaterally and a thin dielectric layer covered inside that supports bound modes of surface plasmon polaritons at terahertz frequencies. This structure can confine the surface plasmon polaritons in the lateral direction, and at the same time reduce the field expansion into space. We examined and explored the characteristics of several different structures using scanning near-field terahertz microscopy. The proposed designs pave a novel way to terahertz waveguiding and may have important applications in the development of flexible, wideband and compact photonic circuits operating at terahertz frequencies.