Sustainable strategies towards better utilization of synthetic polymers.

The abstract provides an overview of a study focused on analyzing diverse strategies to achieve sustainable utilization of synthetic polymers through effective waste management. The escalating global consumption of synthetic polymers has precipitated a concerning increase in plastic waste and environmental degradation. To address this challenge, novel materials with specified application goals, such as engineered plastic, have been developed and are intended for recycling and reuse. Despite the reuse and recycling, when plastic gets disposed into the environment, the degradation properties of plastics render a direct disposal hazard, posing a significant environmental threat. To mitigate these issues, the concept of replacing specific monomers of engineered synthetic plastics with bio-alternatives or blending them with other polymers to enhance sustainability and environmental compatibility has emerged. In this study, Acrylonitrile Butadiene Styrene (ABS) plastic is the focal material, and three distinct investigations were conducted. First, replacing ABS plastic's butadiene monomer with natural rubber was explored for its properties and environmental impact. Second, ABS plastic was blended with virgin, recycled, and bio-alternatives of PET (polyethylene terephthalate) and PVC (polyvinyl chloride) polymers. Lastly, recycled ABS blended with recycled PET and PVC was analyzed for mechanical properties. Comparative assessments of these blends were made based on mechanical properties, carbon emissions, and cost-effectiveness. The study determined that the r-ABS/r-PVC (recycled) blend exhibited the most favorable characteristics for practical application.

Multifarious extraction methodologies for ameliorating lipid recovery from algae.

Amongst the current alternatives, algae were proven to be a promising source of biofuel, which is renewable and capable of meeting world demand for transportation fuels. However, a suitable lipid extraction method that efficiently releases the lipids from different algal strains remains a bottleneck. The multifarious pretreatment methods are prevalent in this field of lipid extraction, and therefore, this article has critically reviewed the various lipid extraction methods for ameliorating the lipid yield from algae, irrespective of the strains/species. Physical, mechanical, and chemical are the different types of pretreatment methods. In this review, methodologies such as homogenization, sonication, Soxhlet extraction, microwave treatment, and bead-beating, have been studied in detail and are the most commonly used methods for lipid extraction. Specific advanced/emerging processes such as supercritical CO2 extraction, ionic liquid, and CO2 switchable solvent-based algal lipid extraction are yet to be demonstrated at pilot-scale, though promising. The extraction of lipids has to be financially conducive, environmentally sustainable, and industrially applicable for further conversion into biodiesel. Hence, this paper discusses variable pretreatment for lipid extraction and imparts a comparative analysis to elect an efficient, economically sound lipid extraction method for pilot-scale biodiesel production.

Design and analysis of flow velocity distribution inside a raceway pond using computational fluid dynamics.

Open raceway ponds are widely adopted for cultivating microalgae on a large scale. Working depth of the raceway pond is the major component to be analysed for increasing the volume to surface area ratio. The working depth is limited up to 5-15 cm in conventional ponds but in this analysis working depth of raceway pond is considered as 25 cm. In this work, positioning of the paddle wheel is analysed and corresponding Vertical Mixing Index are calculated using CFD. Flow pattern along the length of the raceway pond, at three different paddle wheel speeds are analysed for L/W ratio of 6, 8 and 10, respectively. Effect of clearance (C) between rotor blade tip and bottom surface is also analysed by taking four clearance conditions i.e. C = 2, 5, 10 and 15. Moving reference frame method of Fluent is used for the modeling of six blade paddle wheel and realizable k-ε model is used for capturing turbulence characteristics. Overall objective of this work is to analyse the required geometry for maintaining a minimum flow velocity to avoid settling of algae corresponding to 25 cm working depth. Geometry given in [13] is designed using ANSYS Design modular and CFD results are generated using ANSYS FLUENT for the purpose of validation. Good agreement of results is observed between CFD and experimental Particle image velocimetry results with the deviation of 7.23%.

Methane capture from livestock manure.

It has been estimated that livestock manure contributes about 240 million metric tons of carbon dioxide equivalent of methane to the atmosphere and represents one of the biggest anthropogenic sources of methane. Considering that methane is the second biggest contributor to global warming after carbon dioxide, it is imperative that ways and means are developed to capture as much of the anthropogenic methane as possible. There is a major associated advantage of methane capture: its use as a source of energy which is comparable in 'cleanness' to natural gas. The present review dwells upon the traditional ways of methane capture used in India, China, and other developing countries for providing energy to the rural poor. It then reviews the present status of methane capture from livestock manure in developed countries and touches upon the prevalent trends.

Tertiary amine as an efficient CO2 switchable solvent for extracting lipids from hypersaline microalgae.

Considering the momentous cost drivers in energy efficient algal biorefinery processes, a green alternative in extracting lipid from microalgae is anticipated. Switchable solvent system using tertiary amines namely DMBA (Dimethylbenzylamine), DMCHA (Dimethylcyclohexylamine), and DIPEA (Diisopropylethylamine) for lipid extraction from wet hypersaline microalgae was investigated in this study. Interestingly, present study showed that at 1:1 (v/v of fresh DMBA solvent: microalgal biomass), and for 1 h extraction time, the lipid yield was 41.9, 26.6, and 33.3% for Chlorella sp. NITT 05, Chlorella sp. NITT 02, and Picochlorum sp. NITT 04, respectively and for recovered DMBA solvent, at 1:1 (v/v) and for 1 h extraction time, the lipid yield was 40.8, 25.97, and 32%, respectively. Similarly, lipid extraction using DMCHA solvent for Chlorella sp. NITT 05, Chlorella sp. NITT 02, and Picochlorum sp. NITT 04 at 1:1 (v/v of solvent: microalgal biomass) and 1 h extraction time showed 34.28, 24.24 and 23.33% lipids, respectively for fresh solvent and 34.01, 24.24 and 23.18% for recovered solvent respectively; while DIPEA was not competent in lipid extraction from three tested microalgae. FAME profile revealed the presence of saturated fatty acids as 43.04%, 40.98%, 38.45% and monounsaturated fatty acids as 28.38%, 27.05%, 23.3% for Chlorella sp. NITT05, Picochlorum sp. NITT04, Chlorella sp. NITT02, respectively. This study attributes Chlorella sp. NITT05 and Picochlorum sp. NITT04 to be ideal algal species for biodiesel production.

A waste to energy technology for Enrichment of biomethane generation: A review on operating parameters, types of biodigesters, solar assisted heating systems, socio economic benefits and challenges.

Anaerobic Digestion (AD) is one of the promising wastestoenergy (WtE) technologies that convert organic wastes to useful gaseous fuel (biogas). In this process methane is produced in the presence of methanogens (bacteria). The survival and activities of methanogens are based on several parameters such as pH, temperature, organic loading rate, types of biodigester. Moreover, these parameters influence the production of biogas in terms of yield and composition. Maintaining an appropriate temperaturefor AD is highly critical and energy intensive. This study reviews the various hybrid technologies assistedbio gas production schemes particularly from renewable energy sources. Also discuss the direct and indirect solar assisted bio-digester impacts and recommendation to improve its performance. In addition, the performance analysis Solar Photovoltaic (PV) and thermal collector assisted bio gas plants; besides their impact on the performance of anaerobic digesters. Since opportunities of solar energy are attractive, the effective utilization of the same is selected for the discussion. Besides, the various constraints that affect the yield and composition of biogas are also evaluated along with the current biogas technologies and the biodigesters. The environmental benefits, challenges and socio-economic factors are also discussed for the successful implementation of various technologies.

Cultivation of scenedesmus sp. using optimized minimal nutrients and flocculants - a potential platform for mass cultivation.

A major constraint in the microalgal technology is the economics involved in cultivation and harvesting. This work is focussed on the optimization of nutrients for cultivation and harvesting using 'Scenedesmus sp'. Response surface methodology (RSM) using 'Face centered central composite design' (FCCD) available in Design expert 10.0.4 was used to develop the regression model for optimization of nutrients and flocculation conditions. The optimum nutrient conditions were 500 ppm of urea, 250 ppm of potassium dihydrogen phosphate and 1000 ppm of potassium hydrogen carbonate under artificial light conditions and 500 ppm of urea and 2000 ppm of potassium hydrogen carbonate under sunlight conditions. The optimum conditions were predicted using the model and compared with experimental data. The model has an R2 value of 0.9769 and 0.9798 for artificial light and sunlight conditions, respectively. In the case of harvesting studies, 98% flocculation efficiency was obtained for a combination of pH 10.4, temperature 45°C, 200 mg/l of leaf powder of Cassia auriculata. The model has an R2 value of 0.9989. The present studies indicated that cultivation of Scenedesmus sp. with the optimized nutrients and harvesting conditions facilitate a platform for energy efficient mass cultivation.

Batch Sedimentation Studies for Freshwater Green Alga Scenedesmus abundans Using Combination of Flocculants.

Microalga is the only feedstock that has the theoretical potential to completely replace the energy requirements derived from fossil fuels. However, commercialization of this potential source for fuel applications is hampered due to many technical challenges with harvesting of biomass being the most energy intensive process among them. The fresh water microalgal species, Scenedesmus abundans, has been widely recognized as a potential feedstock for production of biodiesel (Mandotra et al., 2014). The present work deals with sedimentation of algal biomass using extracted chitosan and natural bentonite clay powder as flocculant. The effect of flocculant combination and different factors such as temperature, pH, and concentration of algal biomass on sedimentation rates has been analyzed. A high flocculation efficiency of 76.22 ± 7.81% was obtained at an algal biomass concentration of 1 ± 0.05 g/L for a settling time of 1 h at 50 ± 5°C with a settling velocity of 103.2 ± 0.6 cm/h and a maximum surface conductivity of 2,260 ± 2 µS/cm using an optimal design in response surface methodology (RSM). Biopolymer flocculant such as chitosan exhibited better adsorption property along with bentonite clay powder that reduced the settling time significantly.

Investigation of bio polymer electrolyte based on cellulose acetate-ammonium nitrate for potential use in electrochemical devices.

Proton conducting materials create prime interest in electro chemical device development. Present work has been carried out to design environment friendly new biopolymer electrolytes (BPEs) using cellulose acetate (CA) complex with different concentrations of ammonium nitrate (NH4NO3), which have been prepared as film and characterized. The 50mol% CA and 50mol% NH4NO3 complex has highest ionic conductivity (1.02×10-3Scm-1). Differential scanning calorimetry shows the changes in glass transition temperature depends on salt concentration. Structural analysis indicates that the highest ionic conductivity complex exhibits more amorphous nature. Vibrational analysis confirms the complex formation, which has been validated theoretically by Gaussian 09 software. Conducting element in the BPEs has been predicted. Primary proton battery and proton exchange membrane fuel cell have been developed for highest ionic conductivity complex. Output voltage and power performance has been compared for single fuel cell application, which manifests the present BPE holds promise application in electrochemical devices.

Thermo gravimetric and kinetic studies on dried solid waste of post-methanated distillery effluent under oxygen and nitrogen atmosphere.

This work seeks for the possibility of using solid waste generated by drying the post-methanated distillery effluent, as fuel. TGA has been employed to analyse the kinetics of thermal degradation of the solid waste at different heating rates of 10, 20, 30, and 40°Cmin(-1) in pyrolysis and combustion modes. In combustion mode, the activation energy changes from 253.58 to 87.91kJmol(-1), corresponding to the changes in heating rates of 10°Cmin(-1) to 40°Cmin(-1), whereas, there is no significant change of activation energy in pyrolysis mode. The Arrhenius equation based kinetic model with regression analysis using LINEST function is able to predict the kinetic variables of dried solid waste in both the modes. Solid waste almost completely degrades at the end of isothermal condition in pyrolysis mode.

A critical view on the eco-friendliness of small hydroelectric installations.

Renewable energy sources are widely perceived as 'clean', 'green', and 'inexhaustible'. In recent years the spectre of global warming and ocean acidification, which has been primarily attributed to fossil fuel burning, has brought renewable energy at the forefront of most climate change mitigation strategies. There is strong advocacy for large-scale substitution of conventional energy sources with the renewables on the premise that such a move would substantially reduce environmental degradation and global warming. These sentiments are being echoed by scientists and policy makers as well as environmental activists all over the world. 'Small hydro', which generally represents hydroelectric power projects of capacities 25 MW or lower, is one of the renewable energy options which is believed to be clean and sustainable even as its bigger version, large hydro, is known to cause several strongly adverse environmental impacts. This paper brings out that the prevailing perception of 'eco-friendliness' of small hydro is mainly due to the fact that it has only been used to a very small extent so far. But once it is deployed at a scale comparable to fossil fuel use, the resulting impacts would be quite substantially adverse. The purpose is not to denegrade small hydro, less so to advocate use of fossil fuels. It, rather, is to bring home the point that a much more realistic and elaborate assessment of the likely direct as well as indirect impacts of extensive utilization of this energy source than has been done hitherto is necessary.

Lipoma of the floor of the mouth: report of an unusually large lesion.

Lipomas are among the most common benign tumors affecting the human body. However, they are relatively uncommon in the oral cavity. Oral lipomas are likely to affect cheek, tongue, lips, gingiva and rarely the floor of the mouth. We report a case of huge lipoma of the floor of the mouth, associated with difficulty in speech and mastication in a 72-year-old male. The tumor was completely excised and sent for histopathological examination, which confirmed the tumor to be a simple classical lipoma.

Participatory ergonomics in redesigning a dyeing tub for fabric dyers.

OBJECTIVE: The 'saree' worn by women in India and many South Asian countries is dyed using a tub, usually in small scale units employing low capital and a small number of workers. While using these tubs, workers adopt awkward postures over long periods of time which results in severe discomfort in the neck, shoulders and lower extremities. The purpose of the study was to redesign the dyeing tub using a participatory approach and to study the impact of the newly designed tub on the reported body discomfort and rate of production. METHODS: Redesigning of the dyeing tub was carried out using three parallel participative processes--(1) eliciting the views of workers who use the tub, (2) interacting with the proprietors of the small scale dyeing units (the employers) and the tub manufacturers, and (3) iterative prototype tub development based on inputs from the first two processes. These processes facilitated involvement of the stake-holders and the acceptance of change. The final prototype was tested by nine workers for a period of three months to evaluate the reduction in body discomfort and increase in rate of production (output). RESULTS: Studies on the impact of the new tub showed a reduction in discomfort level from 'severe' to 'moderate', and a mean increase of 7.9% in the output, confirming the benefits of the participative approach to ergonomics intervention. The involvement, trust and credibility generated by the participative process facilitated the acceptance of the final design.

Submental intubation in patients with panfacial fractures: A prospective study.

Submental intubation is an interesting alternative to tracheostomy, especially when short-term postoperative control of airway is desirable with the presence of undisturbed access to oral as well as nasal airways and a good dental occlusion. Submental intubation with midline incision has been used in 10 cases from October 2008 to March 2010 in the Department of Oral and Maxillofacial Surgery, Manipal College of Dental Sciences, Mangalore. All patients had fractures of the jaws disturbing the dental occlusion associated with fracture of the base of the skull, or/and a displaced nasal bone fracture. After standard orotracheal intubation, a passage was created by blunt dissection with a haemostat clamp through the floor of the mouth in the submental area. The proximal end of the orotracheal tube was pulled through the submental incision. Surgery was completed without interference from the endotracheal tube. At the end of surgery, the tube was pulled back to the usual oral route. There were no perioperative complications related to the submental intubation procedure. Average duration of the procedure was less than 6 minutes. Submental intubation is a simple technique associated with low rates of morbidity. It is an attractive alternative to tracheotomy in the surgical management of selected cases of panfacial trauma.

Decolourisation of Red 5 MB dye by microbes isolated from textile dye effluent.

One of the major environmental problems is the presence of dye materials in textile wastewater, which need to be removed before releasing into the environment. Some dyes are toxic and carcinogenic in nature. The discharge of the textile effluent into rivers and lakes leads to higher BOD causing threat to aquatic life. Development of efficient dye degradation requires suitable strain and its use under favorable condition to realize the degradation potential. In this study, three microorganisms were isolated from the Red 5 MB dye containing textile wastewater. They were identified and tested for the dye decolourisation provided with different sugars as carbon source. The percentage of dye decolorized by Bacillus subtilis, Aspergillus flavus and Aspergillus fumigatus were found to be about 40%, 75% and 53.8% respectively.

Investigation of energy recovery from poultry litter and municipal solid waste by thermochemical conversion method in India.

The waste disposal is becoming a major threat to environmental issues and to sustainable development of mankind. The rapid growth in population and enormous developmental activities are the main causes for the generation of waste in many forms. Hence there is need to redress the concern on environment and efforts to be made for effective collection and disposal of wastes. Most of the solid waste is a mix of household wastes, street wastes, commercial and institutional wastes containing organic as well as inorganic matter. This offers better opportunity to recover energy from organic fraction of wastes by adapting suitable processing and treatment technologies. This paper describes the various technologies need to be adopted for the disposal of poultry waste and municipal solid waste. More emphasis has been given on waste disposal technologies for better environment and economics. The advantages and disadvantages of each disposal technology have been briefed.