RESUMEN
Metamaterials and plasmonic structures made from aluminum (Al) have attracted significant interest due to their low cost, long-term stability, and the relative abundance of aluminum compared to the rare metals. Also, aluminum displays distinct dielectric properties allowing for the excitation of surface plasmons in the ultraviolet region with minimal non-radiative losses. Despite these clear advantages, most of the research has been focused on either gold or silver, probably due to difficulties in forming smooth thin films of aluminum. In the present work, we detect and characterize second harmonic generation (SHG) in the optical regime, emanating from triangular hole arrays milled into thin aluminum films in reflection mode, at normal incidence. We report intense nonlinear responses, year-long stability, and overall superior performances with respect to gold. The robustness of the Al structures and high reproducibility of the measured SHG responses allowed us to investigate changes in the directional emission upon tiny modifications in the structure's symmetry. We also demonstrate large-field instantaneous SHG imaging over areas containing several hole arrays using a recent, non-linear single-spinning disk microscope. Such high spatio-temporal resolution imaging has important applications, e.g., when studying chemical transformations occurring at electrode surfaces during charging and discharging cycles, as well as ageing.
RESUMEN
Nanoporous metallic networks are endowed with the distinctive optical properties of strong field enhancement and spatial localization, raising the necessity to map the optical eigenmodes with high spatial resolution. In this work, we used cathodoluminescence (CL) to map the local electric fields of a three-dimensional (3D) silver network made of nanosized ligaments and holes over a broad spectral range. A multitude of neighboring hotspots at different frequencies and intensities are observed at subwavelength distances over the network. In contrast to well-defined plasmonic structures, the hotspots do not necessarily correlate with the network morphology, emphasizing the complexity and energy dissipation through the network. In addition, we show that the inherent connectivity of the networked structure plays a key optical role because a ligament with a single connected linker shows localized modes whereas an octopus-like ligament with multiple connections permits energy propagation through the network.
RESUMEN
While classical liquid droplets are rounded, transitions have recently been discovered which render polyhedral water-suspended droplets of several oils. Yet, the mechanism of these transitions and the role of the droplets' interfacial curvature in inducing these transitions remain controversial. In particular, one of the two mechanisms suggested mandates a convex interface, in a view from the oil side. Here we show that oil-suspended water droplets can spontaneously assume polyhedral shapes, in spite of their concave interface. These results strongly support the alternative mechanism, where the faceting in both oil and water droplets is driven by the elasticity of a crystalline monolayer, known to self-assemble at the oil-water interface, independent of its curvature. The faceting transitions in the water droplets allow the fundamental elastic properties of two-dimensional matter to be probed, enable new strategies in faceted nanoparticle and nanoshell synthesis, and provide insight into the molecular mechanisms of morphogenesis.
RESUMEN
We report a new approach for large-scale alignment of micron-sized J-aggregates of a derivative of porphyrin onto planar glass substrates. We applied a unidirectional nitrogen flow to an aqueous dye drop deposited onto a glass substrate to form an about 5 nm thick film of aligned J-aggregates over macroscopic surface areas up to several millimeters. The inter-aggregate distance is â¼500 nm, and it scales with the nitrogen pressure. We verified the film thickness and J-aggregate alignment using multimodal microscopy and spectroscopy techniques. Our technique is fast, simple, and cost-effective for producing large two-dimensional (2-D) arrays of aligned emitters.
RESUMEN
Nanoporous metallic networks are a group of porous materials made of solid metals with suboptical wavelength sizes of both particles and voids. They are characterized by unique optical properties, as well as high surface area and permeability of guest materials. As such, they attract a great focus as novel materials for photonics, catalysis, sensing, and renewable energy. Their properties together with the ability for scaling-up evoke an increased interest also in the industrial field. Here, fabrication techniques of large-scale metallic networks are discussed, and their interesting optical properties as well as their applications are considered. In particular, the focus is on disordered systems, which may facilitate the fabrication technique, yet, endow the three-dimensional (3D) network with distinct optical properties. These metallic networks bridge the nanoworld into the macroscopic world, and therefore pave the way to the fabrication of innovative materials with unique optoelectronic properties.
RESUMEN
Fabrication of macroscopic nanoporous metallic networks is challenging, because it demands fine structures at the nanoscale over a large-scale. A technique to form pure scalable networks is introduced. The networked-metals ("Netals") exhibit a strong interaction with light and indicate a large fraction of hot-electrons generation. These hot-electrons are available to derive photocatalytic processes.
RESUMEN
Ureteral stents and urethral catheters are commonly used medical devices for maintaining urinary flow. However, long-term placement (>30 days) of these devices in the urinary tracts is limited by the development of encrustation, a phenomenon that holds a prevalence of 50% within this patient population, resulting in a great deal of morbidity to the patients. Here we report the influence of surface coating of an all-silicone catheter with rhenium-doped fullerene-like molybdenum disulfide (Re:IF-MoS2) nanoparticles on the growth and attachment of in vitro encrustation stones. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction (XRD) analyses indicated a remarkable attenuation in encrustation occupation on the Re:IF-MoS2-coated catheter surfaces compared to neat catheters. The doped nanoparticles displayed a unique tendency to self-assemble into mosaic-like arrangements, modifying the surface to be encrustation-repellent. The mechanism of encrustation retardation on the surface coated catheters is discussed in some detail. The ramification of these results for the clogging of other body indwelling devices is briefly discussed.