Verification of an alternative sludge treatment process for pathogen reduction at two wastewater treatment plants in Victoria, Australia.

At South East Water wastewater treatment plants (WwTPs) in Victoria, Australia, biosolids are stockpiled for three years in compliance with the State guidelines to achieve the highest pathogen reduction grade (T1), suitable for unrestricted use in agriculture and landscaping. However, extended stockpiling is costly, may increase odour nuisance and greenhouse gas emissions, and reduces the fertiliser value of the biosolids. A verification programme of sampling and analysis for enteric pathogens was conducted at two WwTPs where sludge is treated by aerobic and anaerobic digestion, air drying (in drying pans or solar drying sheds) and stockpiling, to enumerate and, if present, monitor the decay of a range of enteric pathogens and parasites. The sludge treatment processes at both WwTPs achieved T1 grade biosolids with respect to prescribed pathogenic bacterial numbers (<1 Salmonella spp. 50 g-1 dry solids (DS) and <100 Escherichia coli g-1 DS) and >3 log10 enteric virus reduction after a storage period of one year. No Ascaris eggs were detected in the influent to the WwTPs, confirming previous studies that the presence of helminth infections in Victoria is extremely low and that Ascaris is not applicable as a control criterion for the microbiological quality of biosolids in the region.

Decoupling anthropogenic vs. natural impacts at a wastewater treatment plant situated on acid sulfate soils.

Decoupling natural and anthropogenic impacts on the subsurface environment can be difficult, particularly when it has been subject to a wide range of influences over time and space. In this work we show how the use of hydrogeochemical plotting tools, time-series analysis of key contaminants of concern, and targeted isotopic analysis can be used to better understand the contamination sources/processes in a complex environment - a Wastewater Treatment Plant (WWTP) located on coastal acid sulfate soils (ASS). Analysis of soil profiles for potential oxidisable sulfur, acid neutralising capacity (ANC), and pHfox along with groundwater chemistry, revealed that oxidation of pyritic sediments, initially deposited during the mid-Holocene, have led to significant pH declines and the secondary mobilisation of metals into the groundwater environment. This is further complicated by historic anthropogenic inputs associated with the WWTP (e.g., effluent leakages) and the surrounding agricultural land uses. There is distinct separation between spatial and temporal trends in the nutrient and heavy metals data in groundwater, suggesting these reflect different contaminant sources and/or processes. Isotopic data indicate nutrients are largely derived from the WWTP, whereas time-series analysis of key contaminants of concern and hydrogeochemical plotting tools indicate metals are largely derived from the secondary mobilisation of ASS due to acidity generated during sulfide oxidation. This work highlights the importance of understanding the hydrogeological environment and need for careful planning and ongoing management of WWTP sites, particularly those constructed on potential acid sulfate soils (PASS), which, if disturbed or exposed, can lead to impacts beyond the area of ASS via groundwater discharge to nearby surface water bodies (in this case the site is adjacent to a Ramsar-listed wetland). The outcomes of this work have significant global application in the identification, assessment, and control of ASS, the practice of contaminant source attribution, and the siting and design of future WWTPs, which will continue to be sited in coastal areas to meet population needs.

Data for the Determination of Total Carbon in Biosolids using MID-Infrared Spectroscopy.

The data presented in this article relates to "Determination of Total Carbon in Biosolids using MID-Infrared Spectroscopy" published in Science of the Total Environment. In this new article, we present the data used for the development of the methodology using Partial Least Squares (PLS) combined with MID-Infrared (MID-IR) spectroscopy for the determination of total carbon in biosolids. Based on the data used, MID-IR combined with PLS was found to be an acceptable alternative and inexpensive method to determine the total C of biosolids compared to conventional methods such as the Dumas combustion method using a LECO C analyser.

Determination of total carbon in biosolids using MID-infrared spectroscopy.

This study was designed to determine if MID-Infrared (MID-IR) spectroscopy combined with Partial Least Squares (PLS) modelling could be used to predict total carbon (C) in biosolids generated from wastewater treatment plants. Biosolids samples were selected and analysed for total C, and MID-IR spectra were recorded. Using the total C and MID-IR data, a PLS model was developed using both the full spectral range and selected wavelengths regions. The PLS modelling showed that an R2 of 0.97 was achieved for both approaches. To validate the modelling, PLS prediction was applied to a randomly selected validation set of 20 samples and prediction uncertainties determined using The Unscrambler software. A prediction error (or uncertainty) of approximately ±2% carbon was achieved using both full spectra and selected wavelengths regions. Based on the results of the study, MID-IR combined with PLS could be used as an alternate and inexpensive method to determine the total C of biosolids compared to conventional methods such as the Dumas combustion method using a LECO C analyser.

Combining environmental isotopes with Contaminants of Emerging Concern (CECs) to characterise wastewater derived impacts on groundwater quality.

The potential for Wastewater Treatment Plants (WWTPs) to cause adverse impacts to groundwater quality is a major global environmental challenge. Robust and sensitive techniques are required to characterise these impacts, particularly in settings with multiple potential contaminant sources (e.g. agricultural vs. site-derived). Stable (δ2HH2O, δ18OH2O, δ15NNO3, δ18ONO3 and δ13CDIC) and radioactive (3H and 14C) isotopes were used in conjunction with three Contaminants of Emerging Concern (CECs) - carbamazepine, simazine and sulfamethoxazole - to discriminate between multiple potential contamination sources at an Australian WWTP. The radioactive isotope tritium provided a sensitive indicator of recent (post-1990s) leakage, with groundwater activities between 0.68 and 1.83 TU, suggesting WWTP infrastructure (activities between 1.65 and 2.41) acted as a recharge 'window', inputting treated or partially treated effluent to the underlying groundwater system. This was corroborated by water stable isotopes, which showed clear demarcation between δ18OH2O and δ2HH2O in background groundwater (δ18OH2O and δ2HH2O values of approximately -5 and -28‰, respectively) and those associated with on-site wastewater (median δ18OH2O and δ2HH2O values of -1.2 and -7.6‰, respectively), with groundwater down-gradient of the plant plotting on a mixing line between these values. The CECs, particularly the carbamazepine:simazine ratio, provided a means to further distinguish wastewater impacts from other sources, with groundwater down-gradient of the plant reporting elevated ratios (median of 0.98) compared to those up-gradient (median of 0.11). Distinctive CEC ratios in impacted groundwater close to the WWTP (∼3.0) and further down-gradient (2.7-9.3) are interpreted to represent a change in composition over time (i.e., recent vs. legacy contamination), consistent with the site development timeline and possible changes in effluent composition resulting from infrastructure upgrades over time. The data indicate a complex set of co-mingled plumes, reflecting different inputs (in terms of both quantity and concentration) over time. Our approach provides a means to better characterise the nature and timing of wastewater derived impacts on groundwater systems, with significant global implications for site management, potentially allowing more targeted monitoring, management and remedial actions to be undertaken.

Influence of pyrolysis parameters on phosphorus fractions of biosolids derived biochar.

Transforming biosolids into biochar, through pyrolysis, could result in more sustainable waste management. Influence of pyrolysis conditions (temperature, heating rate and residence time) on physico-chemical properties of biosolids (collected at Mount Martha Water Recycling Plant, Melbourne), phosphorus fractions and phosphorus forms was investigated. Twelve different biochar samples were produced at 400, 500 and 600 °C, at two heating rates (5 and 20 °C/min) and at two residence times (30 and 120 min). Biochar yield, pH, electrical conductivity (EC), elements (C, H and N) and BET surface area were analysed. Sequential extraction of P in biosolids and resultant biochars was done using Hedley method. Characterization was completed with SEM images and results from 31P liquid state NMR. Increased temperatures would not only increase the alkalinity, decrease EC and increase the adsorption capacity by increasing the surface area but also convert the readily available P to a less available pool. Therefore, this nutrient might be released to soil slowly over a longer period of time. The results showed that temperature, along with residence time and heating rate, had a significant effect on the characteristics observed. Therefore, all these factors need to be carefully considered when preparing biochar for use as a soil amendment.

Contaminants of Emerging Concern as novel groundwater tracers for delineating wastewater impacts in urban and peri-urban areas.

Management and treatment of environmental impacts from wastewater treatment plants (WWTPs) is a major, worldwide, sustainability challenge. One issue associated with WWTP operation is the potential for groundwater contamination via leaking or infiltration of wastewater, particularly with inorganic nutrients (ammonia and nitrate) as well as persistent organic compounds. Despite the potential for such contamination to create environmental and health risks, conventional methods, such as the assessment of major ions, nutrients, bacteriological indicators and conventional tracers (such as stable and radiogenic isotopes) are often unable to provide accurate delineation of multiple potential sources of contamination. This is particularly important for WWTPs which often occur in urban, peri-urban or intensively farmed agricultural areas where multiple potential sources (such as livestock, fertilisers, wastewater irrigation, and domestic septic systems) may contribute similar contaminants. This review explores the applicability of promising novel groundwater tracers, such as Contaminants of Emerging Concern (CECs) and isotopic tracers, which can be used in conjunction with conventional tracers (i.e. 'co-tracers') to provide a more definitive assessment of contaminant sources, plume delineation and even (potentially) indicating the age of contamination (e.g., recent vs. legacy). The suitability of the novel groundwater tracers is evaluated according to four key criteria: (i). sufficient presence in raw wastewater and/or treated effluents; (ii) diagnostic of WWTP impacts as opposed to other potential off-site contamination sources; (iii) persistence in the subsurface environment; and (iv) amenable to rapid and sensitive analysis. Further analysis of various classes of CECs along with improved detection limits associated with improvements in analytical methodologies should allow for future application of promising groundwater tracers, providing WWTP operators and regulatory authorities a more definitive toolbox with which to assess groundwater contamination associated with site operations. These include: persistent pharmaceuticals and personal care products (carbamazepine, crotamiton, primidone, atenolol and sulfamethoxazole), artificial sweeteners (acesulfame, sucralose, saccharin and cyclamate) and potentially, certain pesticides (atrazine and simazine).

A review on alum sludge reuse with special reference to agricultural applications and future challenges.

Alum salts are commonly used in the water industry to promote coagulation in the production of clean drinking water, which results in the generation and accumulation of 'waste' by-product 'alum sludge' in large volumes. Effective and efficient management of alum sludge in an economically and environmentally sustainable manner remains a significant social and environmental concern with ever increasing demand for potable water as a result of rapidly escalating world population and urban expansion. Various intensive practices have been employed to reuse the alum sludge in an attempt to figure out how to fill the gap between successful drinking water treatment process and environmentally friendly alum sludge management for over the years. This paper primarily aimed at comprehensive review of the existing literature on alum sludge characteristics, its environmental concerns and their potential utilization, especially in agricultural and horticultural sectors leading to update our recent state of knowledge and formulate a compendium of present and past developments. Different types of alum sludge utilizations in various fields were recognized and examined. The strengths, weaknesses, opportunities and potential risks of alum sludge reuse options with particular reference to agriculture were highlighted and knowledge gaps were identified. Research priorities and future challenges that will support in the development of effective alumsludgemanagement practices in agriculture with multi-prong strategies were discussed.