Anaerobic Digestion Effluents (ADEs) Treatment Coupling with Chlorella sp. Microalgae Production.

Nutrient removal effectiveness from anaerobic digestion effluents (ADEs) by Chlorella sp. cultivation and microalgae biomass productivity were evaluated in this study. The results showed that the highest Chlorella sp. biomass productivities of 386.5 ± 24.1 mg dry weight/L•d and 338.3 ± 11.0 mg dry weight/L•d were respectively obtained with the anaerobically digested effluent of municipal wastewater sludge and effluent from a fermentation tank treating dairy wastewater. Lower (p < 0.05) microalgal growth was achieved with anaerobically digested effluents of maize silage and swine slurry and cattle manure. The increase of the initial ammonia nitrogen concentration in ADEs to the level of 160 mg/L did not encourage Chlorella sp. productivity because of phosphorus limitation. The removal efficiencies of ammonia nitrogen, total nitrogen, total phosphorus, and chemical oxygen demand (COD) reached 99.7%, 98.6%, 88.2%, and 58.7%, respectively, depending on the source of ADE, but not on the initial ammonia nitrogen concentrations.

Usage of Converter Gas as a Substitute Fuel for a Tunnel Furnace in Steelworks.

Converter gas (BOFG) is a by-product of the steel manufacturing process in steelworks. Its usage as a substitute fuel instead of natural gas for fueling a metallurgical furnace seems to be reasonable due to potential benefits as follows: CO2 emission reduction into the ambient air and savings in purchasing costs of natural gas. Results of theoretical analysis focused on implementing converter gas as a fuel for feeding a tunnel furnace for either steel plate rolling, steel sheet hardening in its real working condition or both, are discussed. The analysis was focused on the combustion chemistry of the converter gas and its potential ecological and economic benefits obtained from converter gas usage to heat up steel in a tunnel furnace. Simulations of combustion were conducted using a skeletal chemical kinetic mechanism by Konnov. The directed relation graph with error propagation aided sensitivity analysis (DRGEPSA) method was used to obtain this skeletal kinetic mechanism. Finally, the model was validated on a real tunnel furnace fueled by natural gas. Regarding exhaust emissions, it was found that nitric oxide (NO) dropped down from 275 to 80 ppm when natural gas was replaced by converter gas. However, carbon dioxide emissions increased more than three times in this case, but there is no possibility of eliminating carbon dioxide from steel manufacturing processes at all. Economic analysis showed savings of 44% in fuel purchase costs when natural gas was replaced by converter gas. Summing up, the potential benefits resulting from substituting natural gas with converter gas led to the conclusion that converter gas is strongly recommended as fuel for a tunnel furnace in the steel manufacturing process. Practical application requires testing gas burners in terms of their efficiency, which should provide the same amount of energy supplied to the furnace when fed with converter gas.

Thermal and Stress Properties of Briquettes from Virginia Mallow Energetic Crops.

The article discusses the influence of briquetting/compaction parameters. This includes the effects of pressure and temperature on material density and the thermal conductivity of biomass compacted into briquette samples. Plant biomass mainly consists of lignin and cellulose which breaks down into simple polymers at the elevated temperature of 200 °C. Hence, the compaction pressure, compaction temperature, density, and thermal conductivity of the tested material play crucial roles in the briquetting and the torrefaction process to transform it into charcoal with a high carbon content. The tests were realized for samples of raw biomass compacted under pressure in the range from 100 to 1000 bar and at two temperatures of 20 and 200 °C. The pressure of 200 bar was concluded as the most economically viable in briquetting technology in the tests conducted. The conducted research shows a relatively good log relationship between the density of the compacted briquette and the compaction pressure. Additionally, higher compaction pressure resulted in higher destructive force of the compacted material, which may affect the lower abrasion of the material. Regarding heat transfer throughout the sample, the average thermal conductivity for the compacted biomass was determined at a value of 0.048 ± 0.001 W/(K∙m). Finally, the described methodology for thermal conductivity determination has been found to be a reliable tool, therefore it can be proposed for other applications.

On Determination of the Effective Thermal Conductivity of a Bundle of Steel Bars Using the Krischer Model and Considering Thermal Radiation.

Cellular solid materials are commonly found in industrial applications. By definition, cellular solids are porous materials that are built of distinct cells. One of the groups of such materials contains metal foams. Another group of cellular metals contains bundles of steel bars, which create charges during the heat treatment of the bars. A granular structure connected by the lack of continuity of the solid phase is the main feature that distinguishes bundles from metal foams. The boundaries of the bundle cells are made of adjacent bars, with the internal region taking the form of an air cavity. In this paper, we discuss the possibility of using the Krischer model to determine the effective thermal conductivity of heat-treated bundles of steel bars based on the results of experimental tests and calculations. The model allows the kef coefficient to be precisely determined, although it requires the weighting parameter f to be carefully matched. It is shown that the value of f depends on the bar diameter, while its changes within the examined temperature range (25-800 °C) can be described using a third-degree polynomial. Determining the coefficients of such a polynomial is possible only when the effective thermal conductivity of the considered charge is known. Moreover, we analyze a simplified solution, whereby a constant value of the f coefficient is used for a given bar diameter; however, the kef values obtained thanks to this approach are encumbered with inaccuracy amounting to several dozen percentage points. The obtained results lead to the conclusion that the Krischer model cannot be used for the discussed case.