Chitosan-thioglycolic acid composite cross-linked with glutaraldehyde for selective recovery of Au(III) ions from e-waste leachate via reduction-coupled adsorption and incineration.

The recovery of gold (Au) from electronic waste (e-waste) has gained significant attention due to its high Au content and economic feasibility compared to natural ores. This study presents a facile, single-step approach to prepare the chitosan-thioglycolic acid composite crosslinked with glutaraldehyde (CS-TGA-GA) and demonstrates its unique capability for precious metal management, which is a less investigated application area for thiolated chitosan materials. The novel cost-effective biosorbent CS-TGA-GA demonstrated a very high adsorption capacity of 1351.9 ± 96 mg/g and selectivity for Au(III) from an acidic e-waste solution at pH 1 and 298 K. The high adsorption capacity and selectivity of the sorbent can be attributed to the abundance of -NH2, -OH, and -SH groups present on its surface. Various characterizations, such as scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffractometry, Fourier-transform infrared spectroscopy, and X-ray photoelectron spectroscopy, as well as sorption experiments, including pH, kinetic, and isotherm studies, were performed. The kinetic data align with a pseudo-second-order model and the isotherm data can be well expressed by the Freundlich model. The CS-TGA-GA composite effectively facilitated the conversion of Au(III) to Au(0), leading to the formation of Au nanoparticles that aggregated in the reaction vessel over time. Subsequently, the Au-loaded CS-TGA-GA underwent an incineration procedure, yielding recovered Au with a purity of 99.6%, as measured by X-ray fluorescence. In addition to its large uptake capacity, acid stability, and recyclability, the prepared sorbent showed a highly selective uptake of Au(III) ions in a solution containing various metal ions leached from waste printed circuit boards. These results highlight the potential of CS-TGA-GA as an adsorbent for the recovery of Au from e-waste leachate, thereby contributing to sustainable resource management.

Development of quaternized polyethylenimine-cellulose fibers for fast recovery of Au(CN)2- in alkaline wastewater: Kinetics, isotherm, and thermodynamic study.

The purpose of this study was to fabricate quaternized polyethylenimine-cellulose fibers (QPCFs) for the fast recovery of Au(I) from alkaline e-waste leachate. QPCFs were prepared by quaternizing PEI-modified cellulose fibers using a (3-chloro-2-hydroxypropyl)trimethylammonium chloride solution. The maximum Au(I) adsorption capacity of QPCFs was estimated to be 109.87 ± 3.67 mg/g at pH 9.5 using the Langmuir model. The values of k1 and k2 calculated by the pseudo-first and pseudo-second-order models were 1.79 ± 0.15 min-1 and 0.045 ± 0.003 g/mg min, respectively. Adsorption equilibrium was reached within 5 min. Thermodynamic studies revealed that the Au(I) adsorption process by the QPCFs was spontaneous (ΔG° < 0) and exothermic (ΔH° < 0). The characterization and adsorption mechanism of QPCFs were investigated by Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectrometry. Quaternary amine sites were well developed in the QPCFs. Oxidation or reduction of adsorbed Au(I) was not observed. When QPCFs were applied to the solution obtained by bioleaching of e-waste, the recovery efficiencies of Au and Cu were 61.7 ± 3.1% and 11.1 ± 2.9%, respectively, indicating that QPCFs have Au selectivity. Therefore, QPCFs are suitable for actual wastewater applications because of their high adsorption performance and fast adsorption rate.