Experimental investigation of Cd (II) ion adsorption on surface-modified mixed seaweed Biosorbent: A study on analytical interpretation and thermodynamics.

Despite advancements in wastewater treatment technologies, heavy metal contamination, especially cadmium (Cd), severely threatens human health and ecosystems. The purpose of this work is to compare the removal of Cd (II) ions from aqueous solutions by chemically modified mixed seaweed biosorbent (CMSB) and physically modified mixed seaweed biosorbent (PMSB). BET, SEM, EDAX, FTIR, and XRD techniques characterized the mixed seaweed biosorbents before and after adsorption. They are well-known for their sustainability, affordability, and biodegradability. The BET study revealed that CMSB had a surface area of 19.682 m2/g, while PMSB had a lower surface area of 14.803 m2/g. The optimum adsorption conditions were a temperature of 303 K, pH of 6.0, and biosorbent dosages of 1 g/L for CMSB and 2.5 g/L for PMSB. For CMSB and PMSB, the most efficient contact times were 40 and 80 min, respectively. The Langmuir model was demonstrated to be the best fit for the experimental data when compared to other isotherm models, with a coefficient of determination, or R2, of 0.9713 and a maximum monolayer capacity of 151.2 mg/g and 181.6 mg/g for physical and chemical activated mixed seaweed biomass. There was a significant relationship between the R2 values of chemically modified and physically modified biomass. The findings demonstrate that pseudo-second-order kinetics more accurately represent the adsorption process than pseudo-first-order and Elovich models. Thermodynamic experiments validated the endothermic, spontaneous and favourable characteristics of the removal process. According to the results of the current study, PMSB and CMSB may be used as effective adsorbents to remove Cd (II) from aqueous solutions.

A comprehensive review on immobilized microbes - biochar and their environmental remediation: Mechanism, challenges and future perspectives.

The environment worldwide has been contaminated by toxic pollutants and chemicals through anthropogenic activities, industrial growth, and urbanization. Microbial remediation is seen to be superior compared to conventional remediation due to its low cost, selectivity towards particular metal ions, and high efficiency. One key strategy in enhancing microbial remediation is employing an immobilization technique with biochar as a carrier. This review provides a comprehensive summary of sources and toxic health effects of hazardous water pollutants on human health and the environment. Biochar enhances the growth and proliferation of contaminant-degrading microbes. The combined activity of biochar and microbes in eliminating the contaminants has gained the researcher's interest. Biochar demonstrates its biocompatibility by fostering microbial populations, the release of enzymes, and protecting the microbes from the acute toxicity of surrounding contaminants. The current review complies with the immobilization technique and remediation mechanisms of microbes in pollutant removal. This review also emphasizes the combined utilization, environmental adaptability, and the potential of the combined effect of immobilized microbes and biochar in the remediation of contaminants. Challenges and future outlooks are urged to commercialize the immobilized microbes-biochar interaction mechanism for environmental remediation.

Review on biopolymers and composites - Evolving material as adsorbents in removal of environmental pollutants.

The presence of pollutants and toxic contaminants in water sources makes it unfit to run through. Though various conventional techniques are on deck, development of new technologies are vital for wastewater treatment and recycling. Polymers have been intensively utilized recently in many industries owing to their unique characteristics. Biopolymers resembles natural alternative to synthetic polymers that can be prepared by linking the monomeric units covalently. Despite the obvious advantages of biopolymers, few reviews have been conducted. This review focuses on biopolymers and composites as suitable adsorbent material for removing pollutants present in environment. The classification of biopolymers and their composites based on the sources, methods of preparation and their potential applications are discussed in detail. Biopolymers have the potentiality of substituting conventional adsorbents due to its unique characteristics. Biopolymer based membranes and effective methods of utilization of biopolymers as suitable adsorbent materials are also briefly elaborated. The mechanism of biopolymers and their membrane-based adsorption has been briefly reviewed. In addition, the methods of regeneration and reuse of used biopolymer based adsorbents are highlighted. The comprehensive content on fate of biopolymer after adsorption is given in brief. Finally, this review concludes the future investigations in recent trends in application of biopolymer in various fields in view of eco-friendly and economic perspectives.

Engineering microbes for enhancing the degradation of environmental pollutants: A detailed review on synthetic biology.

Anthropogenic activities resulted in the deposition of huge quantities of contaminants such as heavy metals, dyes, hydrocarbons, etc into an ecosystem. The serious ill effects caused by these pollutants to all living organisms forced in advancement of technology for degrading or removing these pollutants. This degrading activity is mostly depending on microorganisms owing to their ability to survive in harsh adverse conditions. Though native strains possess the capability to degrade these pollutants the development of genetic engineering and molecular biology resulted in engineering approaches that enhanced the efficiency of microbes in degrading pollutants at faster rate. Many bioinformatics tools have been developed for altering/modifying genetic content in microbes to increase their degrading potency. This review provides a detailed note on engineered microbes - their significant importance in degrading environmental contaminants and the approaches utilized for modifying microbes. The genes responsible for degrading the pollutants have been identified and modified fir increasing the potential for quick degradation. The methods for increasing the tolerance in engineered microbes have also been discussed. Thus engineered microbes prove to be effective alternate compared to native strains for degrading pollutants.

Modeling analysis on the effective elimination of toxic pollutant from aquatic environment using pyrolysis assisted palmyra palm male inflorescence.

In this study adsorption of Cd(II) ions using the pyrolysis assisted Palmyra palm male inflorescence (PAPMI) was systematically examined. A batch adsorption study was carried out to determine the type of interactions and removal efficiency which is based on the surface property of PAPMI. The diverse parameters which affect the adsorption performance of PAPMI for Cd(II) ion removal were optimized: biosorbent dose - 1.25 g/L, pH - 6.0, temperature - 303 K, initial cadmium ions concentration - 50 mg/L and contact time - 40 min. Pseudo-first order kinetics and Langmuir isotherm models were more suitable to describe the adsorption kinetics and isotherm, respectively. Therefore, modeling studies portrayed the present Cd(II) ions adsorption on PAPMI as monolayer adsorption occurs on the homogeneous surface and follows the physisorption mechanism. The maximum adsorption capacity of the synthesized PAPMI was examined as 233.2 mg/g from the equilibrium isotherm investigation. Based on the calculated thermodynamic parameters (ΔGo, ΔHo and ΔSo) values, the present Cd(II) ions adsorption on PAPMI was explicated as feasible, and exothermic. The outcome proposed that Palmyra palm male inflorescence can be a suitable adsorbent for expulsion of Cd(II) ions from aqueous environment. In the interim, the utilization of pyrolysis assisted is a viable and fast uptake innovation for the removal of heavy metals from water environment.

Isolation and identification of Vibrio cholerae and Vibrio parahaemolyticus from prawn (Penaeus monodon) seafood: Preservation strategies.

Bacterial diseases are one of the major problems which affects the production, development and expansion of aqua culture. Vibrio sp. are widespread in marine and estuarine environments. The several pathogenic species are commonly associated with outbreaks of Vibrio species and it is mainly associated with food poisonings. In this research, the occurrence of Vibrio sp. was studied by the isolation and it is confirmed by the biochemical methods. The growth rate was studied by changing the different operating parameters. Isolation studies were done by using enrichment and selective plating methods. The different biochemical test was carried out and inferred that the isolated organisms were Vibrio choleraee and Vibrio parahaemolyticus. The antibiotic study was also performed to find out the resistant and sensitivity of the Vibrio species. From the results, it was observed that this can be able to correlate the growth of vibrio species to a limited condition and other environmental parameters for which it will be able to find the remedial measures to prevent the growth and spreading of the diseases. Also the different preservation method was carried out to suppress the growth rate of Vibrio sp.

Innovative approaches to harnessing natural pigments from food waste and by-products for eco-friendly food coloring.

With unprecedented growth in the world population, the demand for food has risen drastically leading to increased agricultural production. One promising avenue is recovery of value-added pigments from food waste which has been gaining global attention. This review focuses on sustainable strategies for extracting pigments, examining the factors that influence extraction, their applications, and consumer acceptability. The significant findings of the study state the efficiency of pigment extraction through innovative extraction techniques rather than following conventional methods that are time-consuming, and unsustainable. In addition to their vibrant colors, these pigments provide functional benefits such as antioxidant properties, extended shelf life and improved food quality. Societal acceptance of pigments derived from food waste is positively driven by environmental awareness and sustainability. The study concludes by highlighting the stability challenges associated with various natural pigments, emphasizing the need for tailored stabilization methods to ensure long-term stability and effective utilization in food matrices.

Sustainable approaches for removing toxic heavy metal from contaminated water: A comprehensive review of bioremediation and biosorption techniques.

In this comprehensive study, highlights emerging environmentally friendly methods to eliminating hazardous heavy metals from contaminated water, with an emphasis on bioremediation and biosorption. Breakthroughs, such as the combination of biological remediation and nanotechnology to improve the elimination of metals effectiveness and the use of genetically modified microbes for targeted pollutant breakdown. Developing biosorption materials made from agricultural waste and biochar, this indicates interesting areas for future research and emphasizes the necessity of sustainable practices in tackling heavy metal contamination in water systems. There seems to be a surge in enthusiasm for the utilization of biological remediation and biosorption methods as sustainable and viable options for eliminating heavy metals from contaminated water in the past couple of decades. The present review intends to offer an in-depth review of the latest understanding and advances in the discipline of biological remediation methods like bioaccumulation, biofiltration, bio-slurping, and bio-venting. Biosorption is specifically explained and includes waste biomass as biosorbent with the removal mechanisms and the hindrances caused in the process are detailed. Advances in biosorption like microbes as biosorbents and the mechanism involved in it. Additionally, novel enhancement techniques like immobilization, genetic modification, and ultrasound-assisted treatment in microbial sorbent are clarified. However, the review extended with analyzing the future advances in the overall biological methods and consequences of heavy metal pollution.

Microorganism-mediated bioremediation of dyes from contaminated soil: Mechanisms, recent advances, and future perspectives.

Many methods have been proposed for the remediation of dye-contaminated soils, a widespread form of environment pollution. Bioremediation, it is hoped, can combine ecological benefits with efficiency of dye decontamination. We review the types and sources of dye contaminants; their possible effects on plant, animal, and human health; and emerging strategies for microbial bioremediation. Challenges, limitations, recommendations for future research, and prospects for large-scale commercialization of microbial bioremediation are discussed.

A systematic review on enhancement strategies in biochar-based remediation of polycyclic aromatic hydrocarbons.

Polycyclic aromatic hydrocarbons (PAHs) are pervasive ecological pollutants produced essentially during the inadequate burning of organic materials. PAHs are a group of different organic compounds that are made out of various aromatic rings. PAHs pose a serious risk to humans and aquatic ecosystems because of their mutagenic and carcinogenic properties. In this way, there is a critical prerequisite to utilizing successful remediation strategies and methods to limit the dangerous effect of these pollutants on the ecosystem. Biochar has believed of intriguing properties such as simple manufacturing operations and more affordable and more productive materials. Biochar is a sustainable carbonaceous material that has an enormous surface area with bountiful functional groups and pore structure, which has huge potential for the remediation of toxic pollutants. This review emphasizes the occurrence, development, and fate of toxic PAHs in the environment. In the present review, the properties and role of biochar in the removal of PAHs were illustrated, and the influencing factors and an efficient key mechanism of biochar for the remediation of PAHs were discussed in detail. Various surface modification methods can be utilized to improve the biochar properties with the magnetization process; the advancements of modified biochar are pointed out in this review. Finally, the constraints and prospects for the large-scale application of biochar in the remediation of toxic pollutants are highlighted.

Current strategies on bioremediation of personal care products and detergents: Sustainability and life cycle assessment.

The increased use of personal care products and detergents in modern society has raised concerns about their potential adverse effects on the environment. These products contain various chemical compounds that can persist in water bodies, leading to water pollution and ecological disturbances. Bioremediation has emerged as a promising approach to address these challenges, utilizing the natural capabilities of microorganisms to degrade or remove these contaminants. This review examines the current strategies employed in the bioremediation of personal care products and detergents, with a specific focus on their sustainability and environmental impact. This bioremediation is essential for environmental rejuvenation, as it uses living organisms to detergents and other daily used products. Its distinctiveness stems from sustainable, nature-centric ways that provide eco-friendly solutions for pollution eradication and nurturing a healthy planet, all while avoiding copying. Explores the use of microbial consortia, enzyme-based treatments, and novel biotechnological approaches in the context of environmental remediation. Additionally, the ecological implications and long-term sustainability of these strategies are assessed. Understanding the strengths and limitations of these bioremediation techniques is essential for developing effective and environmentally friendly solutions to mitigate the impact of personal care products and detergents on ecosystems.

Recent insights into mechanism of modified bio-adsorbents for the remediation of environmental pollutants.

Rapid industrialization has exacerbated the hazard to health and the environment. Wide spectrums of contaminants pose numerous risks, necessitating their disposal and treatment. There is a need for further remediation methods since pollutant residues cannot be entirely eradicated by traditional treatment techniques. Bio-adsorbents are gaining popularity due to their eco-friendly approach, broad applicability, and improved functional and surface characteristics. Adsorbents that have been modified have improved qualities that aid in their adsorptive nature. Adsorption, ion exchange, chelation, surface precipitation, microbial uptake, physical entrapment, biodegradation, redox reactions, and electrostatic interactions are some of the processes that participate in the removal mechanism of biosorbents. These processes can vary depending on the particular biosorbent and the type of pollutants being targeted. The systematic review focuses on the many modification approaches used to remove environmental contaminants. Different modification or activation strategies can be used depending on the type of bio-adsorbent and pollutant to be remediated. Physical activation procedures such as ultrasonication and pyrolysis are more commonly used to modify bio-adsorbents. Ultrasonication process improves the adsorption efficiency by 15-25%. Acid and alkali modified procedures are the most effective chemical activation strategies for adsorbent modification for pollution removal. Chemical modification increases the removal to around 95-99%. The biological technique involving microbial culture is an emerging field that needs to be investigated further for pollutant removal. A short evaluation of modified adsorbents with multi-pollutant adsorption capability that have been better eliminated throughout the adsorption process has been provided.

A biotechnological roadmap for decarbonization systems combined into bioenergy production: Prelude of environmental life-cycle assessment.

Decarbonization has become a critical issue in recent years due to rising energy demands and diminishing oil resources. Decarbonization systems based on biotechnology have proven to be a cost-effective and environmentally benign technique of lowering carbon emissions. Bioenergy generation is an environmentally friendly technique for mitigating climate change in the energy industry, and it is predicted to play an important role in lowering global carbon emissions. This review essentially provides a new perspective on the unique biotechnological approaches and strategies based decarbonization pathways. Furthermore, the application of genetically engineered microbes in CO2 biomitigation and energy generation is particularly emphasized. The production of biohydrogen and biomethane via anaerobic digestion techniques has been highlighted in the perspective. In this review, role of microorganisms in bioconversion of CO2 into different types of bioproducts such as biochemical, biopolymers, biosolvents and biosurfactant was summarized. The current analysis, which includes an in-depth discussion of a biotechnology-based roadmap for the bioeconomy, provides a clear picture of sustainability, forthcoming challenges, and perspectives.

Recent advances in edible coatings and their application in food packaging.

The food packaging industries are facing the challenge of food waste generation. This can be addressed through the use of edible coating materials. These coatings aid in extending the shelf life of food products, reducing waste. The key components of these coatings include food-grade binding agents, solvents, and fillers. The integration of polysaccharide, protein, lipids, bioactive and composite-based materials with edible coating matrix aids to combat substantial post-harvest loss of highly perishable commodities and elevates the quality of minimally processed food. The aim of this review is to introduce the concept of edible coatings and discuss the different coating materials used in the food industry, along with their properties. Additionally, this review aims to classify the coating types based on characteristic features and explore their application in various food processing industries. This review provides a comprehensive overview of edible coatings, including the integration of polysaccharides, proteins, lipids, bioactive, and composite-based materials into the coating matrix. This review also addresses the significant post-harvest loss of highly perishable commodities and emphasizes the enhancement of quality in minimally processed food. Furthermore, the antimicrobial, anti-corrosive, and edible characteristics are highlighted, showcasing their potential applications in different food packaging industries. Moreover, it also discusses the challenges, safety and regulatory aspects, current trends, and future perspectives, aiming to shed light on the commercialization and future investigation of edible coatings.

A review on algae biosorption for the removal of hazardous pollutants from wastewater: Limiting factors, prospects and recommendations.

Heavy metals, dyes and pharmaceutical pollutants in water environment are considered as serious threat to the human and animal health globally. Rapid development of industrialization and agricultural activities are the major source for eliminating the toxic pollutants into the aquatic environment. Several conventional treatment methods have been suggested for the removal of emerging contaminants from wastewater. Algal biosorption, among other strategies and techniques, is demonstrating to be a limited technical remedy that is more focused and inherently more efficient and helps remove dangerous contaminants from water sources. The different environmental effects of harmful contaminants, including heavy metals, dyes, and pharmaceutical chemicals, as well as their sources, were briefly compiled in the current review. This paper provides a comprehensive definition of the future possibilities in heavy compound decomposition by using algal technology, from aggregation to numerous biosorption procedures. Functionalized materials produced from algal sources were clearly proposed. This review further highlights the limiting factors of algal biosorption to eliminate the hazardous material. Finally, this study showed how the existence of algae indicates a potential, effective, affordable, and sustainable sorbent biomaterial for minimizing environmental pollution.

Bioremediation of hazardous pollutants from agricultural soils: A sustainable approach for waste management towards urban sustainability.

Soil contamination is perhaps the most hazardous issue all over the world; these emerging pollutants ought to be treated to confirm the safety of our living environment. Fast industrialization and anthropogenic exercises have resulted in different ecological contamination and caused serious dangerous health effects to humans and animals. Agro wastes are exceptionally directed because of their high biodegradability. Effluents from the agro-industry are a possibly high environmental risk that requires suitable, low-cost, and extensive treatment. Soil treatment using a bioremediation method is considered an eco-accommodating and reasonable strategy for removing toxic pollutants from agricultural fields. The present review was led to survey bioremediation treatability of agro soil by microbes, decide functional consequences for microbial performance and assess potential systems to diminish over potentials. The presence of hazardous pollutants in agricultural soil and sources, and toxic health effects on humans has been addressed in this review. The present review emphasizes an outline of bioremediation for the effective removal of toxic contaminants in the agro field. In addition, factors influencing recent advancements in the bioremediation process have been discussed. The review further highlights the roles and mechanisms of micro-organisms in the bioremediation of agricultural fields.

Valorization of agro-industrial wastes for biorefinery process and circular bioeconomy: A critical review.

Energy recovery from waste resources is a promising approach towards environmental consequences. In the prospect of environmental sustainability, utilization of agro-industrial waste residues as feedstock for biorefinery processes have gained widespread attention. In the agro-industry, various biomasses are exposed to different unit processes for offering value to various agro-industrial waste materials. Agro-industrial wastes can generate a substantial amount of valuable products such as fuels, chemicals, energy, electricity, and by-products. This paper reviews the methodologies for valorization of agro-industrial wastes and their exploitation for generation of renewable energy products. In addition, management of agro-industrial wastes and products from agro-industrial wastes have been elaborated. The waste biorefinery process using agro-industrial wastes does not only offer energy, it also offers environmentally sustainable modes, which address effective management of waste streams. This review aims to highlight the cascading use of biomass from agro-industrial wastes into the systemic approach for economic development.

Advances in the application of immobilized enzyme for the remediation of hazardous pollutant: A review.

Nowadays, ecofriendly, low-cost, and sustainable alternatives techniques have been focused on the effective removal of hazardous pollutants from the water streams. In this context, enzyme immobilization seems to be of specific interest to several researchers to develop novel, effective, greener, and hybrid strategies for the removal of toxic contaminants. Immobilization is a biotechnological tool, anchoring the enzymes on support material to enhance the stability and retain the structural conformation of enzymes for catalysis. Recyclability and reusability are the main merits of immobilized enzymes over free enzymes. Studies showed that immobilized enzyme laccase can be used up to 7 cycles with 66% efficiency, peroxidase can be recycled to 2 cycles with 50% efficiency, and also cellulase to 3 cycles with 91% efficiency. In this review, basic concepts of immobilization, different immobilization techniques, and carriers used for immobilization are summarized. In addition to that, the potential of immobilized enzymes as the bioremediation agents for the effective degradation of pollutants from the contaminated zone and the impact of different operating parameters are summarized in-depth. Further, this review provides future trends and challenges that have to be solved shortly for enhancing the potential of immobilized systems for large-scale industrial wastewater treatment.

Fabrication and characterization of magnetic nanomaterials for the removal of toxic pollutants from water environment: A review.

The success of any sustainable growth represents an advancement of novel approaches and new methodologies for managing any ecological concern. Magnetic nanoparticles have gained recent interest owing to their versatile properties such as controlled size, shape, quantum and surface effect, etc, and outcome in wastewater treatment and pollutant removal. Developments have progressed in synthesizing magnetic nanoparticles with the required size, shape and morphology, surface and chemical composition. Magnetic nanoparticles are target specific and inexpensive compared to conventional treatment techniques. This review insight into the synthesis of magnetic nanoparticles using physical, chemical, and biological methods. The biological method of synthesizing magnetic nanoparticles serves to be cost-effective, green process, and eco-friendly for various applications. Characterization studies of synthesized nanoparticles using TEM, XRD, SARS, SANS, DLS, etc are discussed in detail. Magnetic nanoparticles are widely utilized in recent research for removing organic and inorganic contaminants. It was found that the magnetic nanosorption approach together with redox reactions proves to be an effective and flexible mechanism for the removal of pollutants from waste effluents.

A comprehensive review on the biological conversion of lignocellulosic biomass into hydrogen: Pretreatment strategy, technology advances and perspectives.

The globe has dependent on energy generation and utilization for many years; conversely, ecological concerns constrained the world to view hydrogen as an alternative for economic development. Lignocellulosic biomass is broadly accessible as a low-cost renewable feedstock and nonreactive nature; it has received a lot of consideration as a global energy source and the most attractive alternative to replace fossil natural substances for energy production. Pretreatment of lignocellulosic biomass is essential to advance its fragmentation and lower the lignin content for sustainable energy generation. This review's goal is to provide the different pretreatment strategies for enlarging the solubility and surface area of lignocellulosic biomass. The biological conversion of lignocellulosic biomass to hydrogen was reviewed and operational conditions and enhancing methods were discussed. This review summarizes the working conditions, parameters, yield percentages, techno-economic analysis, challenges, and future recommendations on the direct conversion of biomass to hydrogen.