Advanced H2O2 oxidation for diethyl phthalate degradation in treated effluents: effect of nitrate on oxidation and a pilot-scale AOP operation.

One of the objectives of this study was to delineate the effect of nitrate on diethyl phthalate (DEP) oxidation by conducting a bench-scale ultraviolet (UV)/H2O2 and O3/H2O2 operations as suggested in a previous study. We also aim to investigate DEP oxidation at various UV doses and H2O2 concentrations by performing a pilot-scale advanced oxidation processes (AOP) system, into which a portion of the effluent from a pilot-scale membrane bioreactor (MBR) plant was pumped. In the bench-scale AOP operation, the O3 oxidation alone as well as the UV irradiation without H2O2 addition could be among the desirable alternatives for the efficient removal of DEP dissolved in aqueous solutions at a low DEP concentration range of 85+/-15 microg/L. The adverse effect in the UV/H2O2 process was significantly greater than that in the UV oxidation alone, and its oxidation was almost halved by the nitrate. However, the nitrate clearly enhanced the DEP oxidation in the O3 oxidation and O3/H2O2 process. Especially, the addition of nitrate almost doubled the DEP oxidation efficiency in the O3/H2O2 process. The series of pilot-scale AOP operations confirmed that about 30-50% of DEP dissolved in the treated MBR effluent streams was, at least, oxidized by the O3 oxidation alone as well as the UV irradiation without H2O2 addition. The UV photolysis of H2O2 was most effective for DEP degradation with an H2O2 concentration of 40 mg/L at a UV dose of 500 mJ/cm2.

Evaluation of a membrane bioreactor system coupled with sludge pretreatment for aerobic sludge digestion.

The effects of ozone and alkaline pretreatment of sewage sludge on the performances of membrane-coupled aerobic sludge digestion were investigated. In particular, the effects of sludge pretreatment on the solubilization, sludge biodegradation and the stability of membrane filtration were evaluated. Three sets of reactors were operated under different conditions of sludge treatment; 1) ozone treatment at 0.1 g O3 g(-1) suspended solids (SS) of the influent sludge, 2) alkaline treatment at pH 11.4-12.0, 3) no treatment. Without sludge pretreatment, 27% of suspended solids (SS) reduction was obtained at the hydraulic retention time(HRT) of 5 days. With ozone and alkaline treatment, the average SS reduction increased to 83 and 76%, respectively, at the same HRT. Membrane fouling occurred earliest with the non-treated sludge, followed by the alkali-treated sludge. With ozonated sludge, stable membrane filtration for more than 150 days was possible without chemical cleaning of the membrane. The dynamic viscosity of the mixed liquor in the reactor fed with ozonated sludge was relatively low, indicating the role of ozone treatment in controlling membrane fouling. In conclusion, sludge pretreatment followed by aerobic sludge digestion in a membrane-coupled bioreactor can achieve a very high rate of sludge reduction at a relatively short HRT.

Application of membrane bioreactor system with full scale plant on livestock wastewater.

A full-scale plant of an MBR system treating livestock wastewater has shown impressive results. The Cheorwon County Environmental Authorities adopted the MBR process with UF membrane for retrofitting the old plant, which removes organic matter, nitrogen and phosphorus at a high level. According to 6 months operation data, BOD and SS removal were about 99.9% and COD(Mn), TN and TP removal were 92.0%, 98.3% and 82.7%, respectively. It is considered that the temperature at the bioreactor has to be controlled to be below 40 degrees C so as to ensure sufficient nitrification. It appeared that the MBR system is competitive with other conventional technologies for treatment of livestock wastewater such as piggery waste.

A pilot study on accelerated sludge degradation by a high-concentration membrane bioreactor coupled with sludge pretreatment.

A new sludge treatment process combining a high MLSS membrane bioreactor with sludge pretreatment techniques was studied in pilot-scale experiments. The membrane bioreactor (MBR) was adopted for high efficiency aerobic digestion. The combination of alkaline-ozone treatment of the mixed liquor in the MBR reactor accelerated the biodegradation process by enhancing biodegradability of the sludge. The hydraulic retention time (HRT) of the reactor was set as 3.1 days and the DO level was 1 mg/L on average. After 5 months of operation, the accumulative total solids reduction was more than 70%. Removal efficiency of volatile solids and non-volatile solids were 76% and 54%, respectively. It was found that a considerable portion of the non-volatile solids was dissolved into ions and then flushed out with the effluent. Also, about 41% and 28% of T-N and T-P in the raw sludge were removed although no biological nutrient removal process was adopted. The experiment was run smoothly without significant membrane fouling, even at the relatively high levels of MLSS concentration (11,000-25,000 mg/L). It is concluded that the newly proposed process can significantly increase the sludge reduction efficiency with much shorter retention times.

Improvement of the thickening and dewatering characteristics of activated sludge by electroflotation (EF).

The performances of electroflotation (EF) on the thickening of activated sludge were investigated using laboratory scale batch flotation reactors. Four activated sludges including bulking sludges were tested. After 30 minutes of EF operation, 57-84% of sludge volume reduction could be achieved by EF, while only about 1.5-14% could be obtained by gravity thickening for the same period. After thickening the effluent water quality in terms of TCOD, SS, and turbidity was improved by EF operation for all sludge samples. In addition, the EF thickened sludge showed much better dewaterability both in SRF and cake solid content. It is induced that the air bubbles entrapped in the thickened sludge play a key role in the observed dewaterbility improvement.

Effects of ozone treatment on the biodegradability of sludge from municipal wastewater treatment plants.

The effects of ozone pretreatment on the biodegradability of municipal wastewater sludge were determined. Three types of experiments were conducted: anaerobic digestion, aerobic biodegradation, and denitrification using ozone-treated sludge as a carbon source. For 5 days, ozonated sludge at 0.1 gO3/g-SS showed about 2-3 times greater biodegradation compared to the raw sludge in both aerobic and anaerobic conditions. In anaerobic experiments, biodegradation increased with ozone dosage up to 0.2 gO3/g-SS. Further increase of ozone dosage did not improve the biodegradation. In aerobic condition, about 77% of the ozonated sludge at 0.1 gO3/g-SS could be biodegraded after 15 days and is compared with 36% degradation of the untreated sludge. Most of the biodegradation of the ozonated sludge occurred within 5 days while the raw sludge was biodegraded steadily throughout the experimental period. The biodegradation enhancement of ozonated sludge was confirmed in batch denitrification experiments.

Reduction of sludge by ozone treatment and production of carbon source for denitrification.

The feasibility of ozone treatment of municipal sludge for sludge reduction and carbon source production has been investigated. Significant accumulation of solubilized organics and unsettlable micro-solids (UMS) was observed at relatively low ozone dosages while mineralization became dominant at higher dosages. Batch denitrification experiments showed that the solubilized organics and the UMS could be utilized as carbon sources for nitrogen removal. In terms of overall sludge reduction, 54% reduction of the total sludge mass could be achieved by ozone treatment at 0.2 g-O3/g-MLSS.

Nonequilibrium mass transfer of multi-component NAPL in a soil column venting.

This study was conducted to investigate the mass transfer behavior for a multi-component system in the soil venting process. Soil venting experiments were conducted using gasoline-contaminated soil and models of local equilibrium assumption (LEA) and the first-order kinetic approach were used to descnbe the gasoline volatilization process. However, the focus was on the application of the kinetic model. In both models, thirteen major components of gasoline were selected for the model input and the rest of the gasoline was divided into 11 groups based on the retention times in the gas chromatography of gasoline. The LEA model had the tendency of underestimating the gas concentration at the initial phase and overestimating at the later phase due to the different volatilities of multi-components. n the kinetic model, the estimation of mass transfer coefficient values were carried out by adopting the relationship developed in the single-components system and choosing the appropriate modified Sherwood number. This method resulted in the good agreement with the simulation and the experimental results.