Broad-band-enhanced plasmonic random laser in silver nanostar arrays.

As a novel optical device, the plasmonic random laser has unique working principle and emission characteristics. However, the simultaneous enhancement of absorption and emission by plasmons is still a problem. In this paper, we propose a broad-band-enhanced plasmonic random laser. Two-dimensional silver (Ag) nanostar arrays were prepared using a bottom-up method with the assistance of self-assembled nanosphere templates. The plasmon resonance of Ag nanostars contributes to the pump light absorption and photoluminescence (PL) of RhB. Coherent random lasing was achieved in RhB@PVA film based on localized surface plasmon resonance (SPR) dual enhancement and scattering feedback of Ag nanostars. Ag nanostars prepared with different nanosphere diameters affect the laser emission wavelength. In addition, the random laser device achieves wavelength tunability on a flexible substrate under mechanical external force.

Nonpolar Solvent Modulated Inkjet Printing of Nanoparticle Self-Assembly Morphologies.

Patterning of luminescent nanomaterials is critical in the fields of display and information encryption, and inkjet printing technology have shown remarkable significance with the advantage of fast, large-scalable and integrative. However, inkjet printing nanoparticle deposits with high-resolution and well controlled morphology from nonpolar solvent droplets is still challenging. Herein, a facile approach of nonpolar solvent modulated inkjet printing of nanoparticles self-assembly patterns driven by the shrinkage of the droplet and inner solutal convection is proposed. Through regulating the solvent composition and nanoparticle concentration, multicolor light-emissive upconversion nanoparticle self-assembly microarrays with tunable morphologies are achieved, showing the integration of designable microscale morphologies and photoluminescences for multimodal anti-counterfeit. Furthermore, inkjet printing of nanoparticles self-assembled continuous lines with adjustable morphologies by controlling the coalescence and drying of the ink droplets is achieved. The high resolution of inkjet printing microarrays and continuous lines' width < 5 and 10 µm is realized, respectively. This nonpolar solvent-modulated inkjet printing of nanoparticle deposits approach facilitates the patterning and integration of different nanomaterials, and is expected to provide a versatile platform for fabricating advanced devices applied in photonics integration, micro-LED, and near-field display.

Tunable random lasers via phase transition for information encryption.

Introducing phase transition materials to random systems provides a promising route to create new optoelectronic functionalities of random lasers. Here, a phase transition random laser with switchable lasing modes is reported, which is designed with a thermoresponsive hydrogel as scattering medium. By manipulating the phase transition in hydrogel, random lasing modes can be switched reversibility between incoherent and coherent random lasing. The phenomenon derives from the changing of light scattering properties in different phase states, thus affecting the optical feedback path of random lasing. Besides, based on its controllable and easily detectable time-domain characteristics, the phase transition random laser is applied in information encoding and transmission. It is the first time that the transition from coherent to incoherent random lasing is observed by varying the sample phase states. This work will inspire the design and application of novel random lasers in photoelectric device.

Tunable random laser based on hybrid plasmonic enhancement.

This research investigates the hybridized plasmonic response of silver film combined with dispersed silver (Ag) nanowires (NWs) to random laser emission. The mixture of Rhodamine B (RhB) dye and polyvinyl alcohol (PVA) matrix is taken as the gain medium for random lasing, and the silver combination provides feedback mechanisms for light trapping. Importantly, film roughness and the coupling between localized and extended (delocalized) surface plasmons play a vital role in RL performance evaluation. The laser threshold is strongly influenced by film thickness attributed to surface roughness. Furthermore, the variation in film thickness also supports the wavelength modulation of 9 nm (597 nm to 606 nm), which results from the reabsorption of RhB. Additionally, the intriguing capability of emission wavelength tuning under the variation of temperature facilitates exciting prospects for precise wavelength control in plasmonic devices.

Switchable whispering gallery mode lasing via phase transition.

Combining phase-transition materials with optical microcavities may advance the applications of whispering-gallery mode (WGM) lasing in performance customization, sensing, and optical switching. In this study, switchable WGM lasing based on phase transition is reported. The device is designed by introducing the phase-transition hydrogel into the capillary microcavity. After approaching the phase-transition point in hydrogel, the number of WGM lasing modes decreases sharply with a significant blueshift in the wavelength. The phenomenon is caused by the increase in light scattering and decrease in effective refractive index of the device. Furthermore, single-mode lasing is obtained by manipulating the phase transition, which exhibits superior reversibility. This study may pave the way for designing and multifunctioning of novel WGM lasing in photonic devices.

Chirality detection of biological molecule through spin selectivity effect.

The ability to accurately monitor chiral biological molecules is of great significance for their potential applications in disease diagnosis and virus detection. As the existing chiral detection technologies are mainly relying on an optical method by using left/right circularly polarized light, the universality is low and the operation is complicated. Moreover, large quantity of chiral molecules is required, causing low detection efficiency. Here, a self-assembled monolayer of polypeptides has been fabricated to realize trace detection of chirality based on spin selectivity of photon-electron interaction. We have utilized Kerr technique to detect the rotation angle by the molecular monolayer, which indicates the chirality of polypeptides. The chiral structure of a biological molecule could result in spin-selectivity of electrons and thus influence the interaction between electron spin and light polarization. A Kerr rotation angle of ∼3° has been obviously observed, equivalent to the magneto-optic Kerr effect without magnetic material or magnetic field. Furthermore, we have provided a novel solution to achieve chirality discrimination and amplification simultaneously through an optical fiber. The proposed design is applicable for chiral detection via increasing their differential output signal, which clearly demonstrates a useful strategy toward chirality characterization of biological molecules.

Random Lasing from Label-Free Living Cells for Rapid Cytometry of Apoptosis.

A random laser carrying the scattering information on a biological host is a promising tool for the characterization of biophysical properties. In this work, random lasing from label-free living cells is proposed to achieve rapid cytometry of apoptosis. Random lasing is achieved by adding biocompatible gain medium to a confocal dish containing cells under optically pumped conditions. The random lasing characteristics are distinct at different stages of cell apoptosis after drug treatment. By analyzing the power Fourier transform results of the random lasing spectra, the percentage of apoptotic cells could be distinguished within two seconds, which is more than an order of magnitude faster than traditional flow cytometry. These results provide a label-free approach for rapid cytometry of apoptosis, which is advantageous for further research of random lasers in the biological field.

Rylene-Fullerene Hybrid an Emerging Electron Acceptor for High-Performing and Photothermal-Stable Ternary Solar Cells.

Molecular carbon imides, especially extended perylene diimides (PDIs) have been the best wide-band-gap nonfullerene acceptors. Despite their excellent photothermal/chemical stability, flexible reaction sites, and unique photoelectronic properties, there is still a lack of fundamental understanding of their molecular characteristics as a third component. Here, generations of PDIs with distinctive molecular architecture, are deliberately screened out as the third component to PM6:Y6. Only a rylene-fullerene hybrid, S-Fuller-PMI, surprisingly boosts the fill factor (FF) of ternary organic solar cells (OSCs) to 0.77 from 0.72 for PM6:Y6 binary ones, and therefore the power conversion efficiency (PCE) of ternary cells is enhanced from 15.3% to 16.2%. Compared with highly-flexible rylene dimer and rigid multimer, S-Fuller-PMI exhibits higher electron mobility, favorable surface tension, and, therefore tailored compatibility with Y6. These formed Y6:S-Fuller-PMI alloys play as a morphological controller to improve charge separation and transport process. Simultaneously, the suppressed photothermal-induced traps, along with inherent enlarged entropy effect, endow the ternary OSCs still with ≈70% of initial PCE even after 500 h continuous illumination, whereas only 53% is left in their binary counterparts. These results provide new insight into the molecular design principle for distinctive molecular carbon imides as the third component for efficient and durable PM6:Y6-based OSCs.

Chiral-Molecule-Based Spintronic Devices.

Spintronics and molecular chemistry have achieved remarkable achievements separately. Their combination can apply the superiority of molecular diversity to intervene or manipulate the spin-related properties. It inevitably brings in a new type of functional devices with a molecular interface, which has become an emerging field in information storage and processing. Normally, spin polarization has to be realized by magnetic materials as manipulated by magnetic fields. Recently, chiral-induced spin selectivity (CISS) was discovered surprisingly that non-magnetic chiral molecules can generate spin polarization through their structural chirality. Here, the recent progress of integrating the strengths of molecular chemistry and spintronics is reviewed by introducing the experimental results, theoretical models, and device performances of the CISS effect. Compared to normal ferromagnetic metals, CISS originating from a chiral structure has great advantages of high spin polarization, excellent interface, simple preparation process, and low cost. It has the potential to obtain high efficiency of spin injection into metals and semiconductors, getting rid of magnetic fields and ferromagnetic electrodes. The physical mechanisms, unique advantages, and device performances of CISS are sequentially clarified, revealing important issues to current scientific research and industrial applications. This mini-review points out a key technology of information storage for future spintronic devices without magnetic components.

Plasmonic distributed feedback lasing in an anodic aluminum oxide/silver/polymer hybrid membrane.

A hybrid membrane is employed as a high-order plasmonic distributed feedback (DFB) cavity to reduce the lasing threshold of polymer lasers. The hybrid membrane consists of an anodic aluminum oxide (AAO) membrane, a 25 nm thick silver layer and a free-standing polymer membrane. The AAO membrane is fabricated by a low-cost, single chemical etching method. Then, a layer of silver with a thickness of 25 nm is sputtered on the surface of the AAO. Subsequently, a polymer membrane is directly attached to the silver-plated AAO membrane, forming an AAO/silver/polymer hybrid membrane. Under optical pumping conditions, low-threshold, three-order DFB lasing is observed. The proposed laser device exhibited a dual-threshold characteristic because of the evolution from amplified spontaneous emission to DFB lasing. And a significant shift from omnidirectional emission to directional emission lasing can be observed while the pump energy density is beyond the second threshold. Furthermore, the plasmonic enhancement sourced from silver corrugation reveals important improvement effects to the DFB lasing of AAO/silver/polymer hybrid membrane for decreasing threshold, narrowing full width at half maximum (FWHM), and an increasing Q factor. This work may promote the design and production of low-cost and large-area high-order plasmonic DFB polymer lasers.

Dynamic manipulation of WGM lasing by tailoring the coupling strength.

Miniaturized lasing with dynamic manipulation is critical to the performance of compact and versatile photonic devices. However, it is still a challenge to manipulate the whispering gallery mode lasing modes dynamically. Here, we design the quasi-three-dimensional coupled cavity by a micromanipulation technique. The coupled cavity consists of two intersection polymer microfibers. The mode selection mechanism is demonstrated experimentally and theoretically in the coupled microfiber cavity. Dynamic manipulation from multiple modes to single-mode lasing is achieved by controlling the coupling strength, which can be quantitatively controlled by changing the coupling angle or the coupling distance. Our work provides a flexible alternative for the lasing mode modulation in the on-chip photonic integration.

Colloidal quantum dots lasing and coupling in 2D holographic photonic quasicrystals.

Global research on the solution-processable colloidal quantum dots (CQDs) constitutes outstanding model systems in nanoscience, micro-lasers, and optoelectronic devices due to tunable color, low cost, and wet chemical processing. The two-dimensional (2D) CQDs quasicrystal lasers are more efficient in providing coherent lasing due to radiation feedback, high-quality-factor optical mode, and long-range rotational symmetry. Here, we have fabricated a 2D quasicrystal exhibiting 10-fold rotational symmetry by using a specially design pentagonal prism in the optical setup of a simple and low-cost holographic lithography. We developed a general analytical model based on the cavity coupling effect, which can be used to explain the underlying mechanism responsible for the multi-wavelength lasing in the fabricated 2D CQDs holographic photonic quasicrystal. The multi-wavelength surface-emitting lasers such as λ0 = 629.27 nm, λ1 = 629.85 nm, λ-1 = 629.06 nm, λ2 = 630.17 nm, and λ-2 = 628.76 with a coupling constant κ = 0.38 achieved from the 2D holographic photonic quasicrystal are approximately similar with the developed analytical model based on cavity coupling effect. Moreover, the lasing patterns of the 2D CQDs photonic quasicrystal laser exhibit a symmetrical polarization effect by rotating the axis of polarization with a difference of 1200 angle in a round trip. We expect that our findings will provide a new approach to customize the 2D CQDs holographic photonic quasicrystal lasers in the field of optoelectronic devices and miniature lasing systems.

Physical Investigations on Bias-Free, Photo-Induced Hall Sensors Based on Pt/GaAs and Pt/Si Schottky Junctions.

Hall-effect in semiconductors has wide applications for magnetic field sensing. Yet, a standard Hall sensor retains two problems: its linearity is affected by the non-uniformity of the current distribution; the sensitivity is bias-dependent, with linearity decreasing with increasing bias current. In order to improve the performance, we here propose a novel structure which realizes bias-free, photo-induced Hall sensors. The system consists of a semi-transparent metal Pt and a semiconductor Si or GaAs to form a Schottky contact. We systematically compared the photo-induced Schottky behaviors and Hall effects without net current flowing, depending on various magnetic fields, light intensities and wavelengths of Pt/GaAs and Pt/Si junctions. The electrical characteristics of the Schottky photo-diodes were fitted to obtain the barrier height as a function of light intensity. We show that the open-circuit Hall voltage of Pt/GaAs junction is orders of magnitude lower than that of Pt/Si, and the barrier height of GaAs is smaller. It should be attributed to the surface states in GaAs which block the carrier drifting. This work not only realizes the physical investigations of photo-induced Hall effects in Pt/GaAs and Pt/Si Schottky junctions, but also opens a new pathway for bias-free magnetic sensing with high linearity and sensitivity comparing to commercial Hall-sensors.

Low-cost biosensors based on a plasmonic random laser on fiber facet.

Low-cost and miniaturized biosensors are key factors leading to the possibility of portable and integrated biomedical system, which play an important role in clinical medicine and life sciences. Random lasers with simple structures provide opportunities for detecting biomolecules. Here, low-cost biosensors on fiber facet for label-free detecting biomolecules are demonstrated based on a plasmonic random laser. The random laser is achieved resorting to a self-assembled plasmonic scattering structure of Ag nanoparticles and polymer film on fiber facet. Refractive index sensitivity and near-surface sensitivity of the biosensor are systematically studied. Furthermore, the biosensor is used to detect IgG through specific binding to protein A, exhibiting the detecting limit of 0.68 nM. It is believed that this work may promote the applications of a plasmonic random laser bio-probe in portable or integrated medical diagnostic platforms, and provide fundamental understanding for the life science.

Tunable polymer lasing in chirped cavities.

Continuously tunable polymer lasing was achieved in one-dimensional, two-dimensional, and compound chirped cavities. The chirped cavity was simply fabricated by using interference lithography and spin coating. Two-dimensional and compound chirped cavities were obtained by employing oblique exposure and double exposure, respectively. The tunability range of two-dimensional chirped cavities was much wider than that of one-dimensional chirped cavities, which varied from 557 nm to 582 nm. The interaction between lasing modes was studied in the compound cavity by introducing an additional nanostructure into the two-dimensional chirped cavities. The threshold of the compound chirped cavities changed with the coupling strength between lasing modes. These results may be helpful for designing compact polymer laser sources.

Dual-color plasmonic random lasers for speckle-free imaging.

A dual-color plasmonic random laser under single-excitation is achieved in an ultrathin membrane doped with binary quantum dots and gold nanorods. The gold nanorods tune the luminescence lifetime and emission efficiency of quantum dots. Under single excitation, low-threshold random lasing is observed. Green random lasing at 547 nm is 'turned on' and red random lasing at 630 nm is greatly enhanced by the transversal and longitudinal surface plasmon resonance of the gold nanorods, respectively. Speckle-free color imaging is achieved by using the proposed dual-color random laser source. These properties would facilitate the development of random lasers in fields of illumination and imaging.

Continuously tunable distributed feedback polymer laser.

A fanshaped structure is proposed to achieve a continuously tunable polymer laser. The structure with gradual periods is fabricated by electron beam lithography, which acts as a distributed feedback cavity for the polymer laser. A light-emitting polymer is spin-coated on the cavity to form an active layer. The pump beam is focused by a cylindrical lens to a narrow stripe on the sample surface. When the position of the pump stripe on the fanshaped cavity is changed from long period (370 nm) to short period (340 nm) and vice versa, the output wavelength of the laser is continuously tuned from 584 nm to 552 nm. Tuning behavior can be interpreted by the Bragg condition. These results can be used to explore compact laser sources.

Tunable polymer lasers based on metal-dielectric hybrid cavity.

Tunable distributed feedback polymer lasing was achieved in a metal-dielectric hybrid cavity. The laser device consisted of a double-layer grating structure and a polymer membrane. Interference lithography and oblique evaporation techniques were employed in fabricating the cavity. The photoresist grating was fabricated by interference lithography. Silver was obliquely evaporated onto the photoresist grating, forming a double-layer grating structure. Then a free-standing polymer membrane was attached on the structure. Under optically pumped conditions, low-threshold lasing was obtained, due to the plasmonic enhancement. The lasing wavelength can be tuned by changing the silver grating's thickness, which results from the variance of the effective refractive index of the cavity. These results can be used to design high-efficiency laser devices.

Hybrid lasing in a plasmonic cavity.

Distributed feedback lasing and surface plasmon lasing were achieved in a single laser device. The laser cavity consisted of a four-layer structure including two metal films, a grating, and a gain material; the cavity was fabricated by combining interference lithography and metal evaporation. A hollow structure was employed to overcome the Joule losses of the metal film. The total thickness of the multilayer structure was 350 nm. The lasing threshold for this hybrid lasing was decreased significantly owing to the coupling between the SP mode in two metal films and the waveguide mode. The combination of SP lasing and distributed feedback lasing could benefit the design of biosensors, all-optical circuits, and electrically pumped devices.

Red-green-blue plasmonic random laser.

A red-green-blue plasmonic random laser is achieved in a multilayer structure, which is fabricated by spin-coating three polymer solutions successively on a silica substrate. Under optical pumping, strong amplification of the polymer radiation can be observed due to the localized surface plasmon resonance of silver nanoparticles embedded in the multilayer structure. Red-green-blue random lasing is simultaneously obtained from the sample based on the enhanced scattering strength of silver nanoparticles. These results are useful for designing compact integrated random laser sources.