Magnetic biochar as a revolutionizing approach for diverse dye pollutants elimination: A comprehensive review.

The term "biomass" encompasses all substances found in the natural world that were once alive or derived from living organisms or their byproducts. These substances consist of organic molecules containing hydrogen, typically oxygen, frequently nitrogen, and small amounts of heavy, alkaline earth and alkali metals. Magnetic biochar refers to a type of material derived from biomass that has been magnetized typically by adding magnetic components such as magnetic iron oxides to display magnetic properties. These materials are extensively applicable in widespread areas like environmental remediation and catalysis. The magnetic properties of these compounds made them ideal for practical applications through their easy separation from a reaction mixture or environmental sample by applying a magnetic field. With the evolving global strategy focused on protecting the planet and moving towards a circular, cost-effective economy, natural compounds, and biomass have become particularly important in the field of biochemistry. The current research explores a comparative analysis of the versatility and potential of biomass for eliminating dyes as a sustainable, economical, easy, compatible, and biodegradable method. The elimination study focused on the removal of various dyes as pollutants. Various operational parameters which influenced the dye removal process were also discussed. Furthermore, the research explained, in detail, adsorption kinetic models, types of isotherms, and desorption properties of magnetic biochar adsorbents. This comprehensive review offers an advanced framework for the effective use of magnetic biochar, removing dyes from textile wastewater.

Sustainable efficient utilization of magnetic porous biochar for adsorption of orange G and tetracycline: Inherent roles of adsorption and mechanisms.

Iron-doped biochar has been widely used as an adsorbent to remove contaminants due to the high adsorption performance, but it still suffers from complicated preparation methods, unstable iron loading, unsatisfactory specific surface area, and uneven distribution of active sites. Here, a novel magnetic porous biochar (FeCS800) with nanostructure on surface was synthesized by one-pot pyrolysis method of corn straw with K2FeO4, and used in orange G (OG) and tetracycline (TC) adsorption. FeCS800 exhibited outstanding adsorption capacities for OG and TC after K2FeO4 activation and the adsorption data were fitted satisfactorily to Langmuir isotherm and Pseudo-second-order kinetic model. The maximum adsorption capacities of FeCS800 for OG and TC were around 303.03 mg/g and 322.58 mg/g, respectively, at 25 °C and pH 7.0, which were 16.27 and 24.61 times higher than that before modification. Thermodynamic studies showed that the adsorption of OG/TC by FeCS800 were thermodynamically favorable and highly spontaneous. And the adsorption capacity of OG and TC by FeCS800 remained 77% and 81% after 5 cycles, respectively, indicating that FeCS800 had good stability. The outstanding adsorption properties and remarkable reusability of FeCS800 show its great potential to be an economic and environmental adsorbent in contaminants removal.

Influence of different stalks on the metallization degree of FeCl3-derived magnetic biochar through pyrolysis behavior and compositional differences.

To investigate the effect of stalk type on the metallization degrees in FeCl3-derived magnetic biochar (MBC), MBC was synthesized via an impregnation-pyrolysis method using six different stalks. The Fe0 content in MBC significantly influenced its magnetic properties and ostensibly governed its catalytic capabilities. Analysis of the interaction between stalks and FeCl3 revealed that the variation in metallization degrees, resulting from FeCl2 decomposition (6.1%) and stalk-mediated reduction (20.7%), was directly responsible for the observed differences in MBC metallization. The presence of oxygen-containing functional groups and fixed carbon appeared to promote metallization in MBC induced by reduction. A series of statistical analyses indicated that the cellulose, lignin, and hemicellulose content of the stalks were key factors contributing to differences in MBC metallization degrees. Further exploration revealed that hemicellulose and cellulose were more effective than lignin in enhancing metallization through FeCl2 decomposition and reduction. Constructing stalk models demonstrated that the variance in the content of these three biomass components across the six stalk types could lead to differences in the metallization degree attributable to reduction and FeCl2 decomposition, thereby affecting the overall metallization degree of MBC. A prediction model for MBC metallization degree was developed based on these findings. Moreover, the elevated Si content in some stalks facilitated the formation of Fe2(SiO4), which subsequently impeded the reduction process. This study provides a theoretical foundation for the informed selection of stalk feedstocks in the production of FeCl3-derived MBC.

Magnetic biochar serves as adsorbents and catalyst supports for the removal of antibiotics from wastewater: A review.

Numerous antibiotics are being released into the natural environment through wastewater. As antibiotic usage increases annually, its detrimental impact on the environment is escalating. Addressing environmental sustainability and human health requires significant attention towards antibiotic removal. In recent years, magnetic biochar (MBC) has gained widespread application in water treatment due to its exceptional adsorption and catalytic degradation capabilities. Antibiotics such as sulfamethoxazole (SMX), tetracycline (TC), ciprofloxacin (CIP), and others commonly exhibit an adsorption capacity by MBC ranging from 5 mg/g to 900 mg/g. Moreover, MBC typically removes over 90% of these antibiotics within 60 min. The effectiveness of antibiotic removal is significantly influenced by various preparation and modification methods. Furthermore, the incorporation of magnetism enables the material to be recycled and reused multiple times, thereby reducing consumption costs. This article discusses recent studies on antibiotic removal using MBC. It has been observed that variations in the selection of raw material and preparation procedures significantly affect antibiotic removal, while the mechanisms involved in antibiotic removal remain ambiguous. Additionally, it has been noted that the removal process may lead to secondary pollution and high preparation costs. Therefore, this review comprehensively outlines the utilization of MBC in the removal of antibiotics from wastewater, including aspects such as modification, preparation, removal mechanism, and factors influencing removal, and providing recommendations for antibiotic development. The aim is to offer researchers a clear understanding to advance the field of MBC materials.

Rapid and efficient removal of multiple heavy metals from diverse types of water using magnetic biochars derived from antibiotic fermentation residue.

Pyrolysis is a promising method to treat antibiotic fermentation residue (AFR), a hazardous waste in China, with the benefits of detoxification and resource recycling. However, the application of the AFR-derived biochar has been limited yet, restricting the use of pyrolysis to treat AFR. Herein, for the first time, we reported the use of magnetic biochars derived from vancomycin fermentation residue to rapidly and efficiently co-adsorb multiple heavy metals from diverse types of water with complex matrices. The biochar prepared at 700 °C (labeled as VBC700) exhibited high affinity and selectivity for multiple heavy metals, especially for Ag(I), Hg(II), Pb(II), and Cu(II). The kinetics for Ag(I), Hg(II), and Pb(II) were ultrafast with an equilibrium time of only 5 min, while those for Cu(II) were relatively slower. The maximum adsorption capacity calculated from the Langmuir model for Ag(I), Hg(II), Pb(II), and Cu(II) reached 177.4, 105.9, 387.1, 124.5 mg/g, respectively, which were superior to much previously reported adsorbents. Impressively, Na(I), K(I), Ca(II), Mg(II), and salinity did not affect the capture of these heavy metals, and thus >99% of Ag(I), Pb(II), and Cu(II) were concurrently removed from complex water matrices including seawater, which has rarely been reported before. Furthermore, VBC700 remained high adsorption performance at pH ≥ 3. The adsorption mechanisms included ion exchange, precipitation, and inner-sphere complexation. Overall, the results demonstrate that VBC700 would be an excellent adsorbent to co-capture multiple heavy metals from diverse types of water, highlighting the feasibility of using pyrolysis to achieve a win-win goal for AFR management and heavy metal pollution control.

Magnetic biochar enhanced copper immobilization in agricultural lands: Insights from adsorption precipitation and redox.

Biochar has exceeded expectations for heavy metal immobilization and has been prepared from widely available sources and inexpensive materials. In this research, coconut shell biochar (CSB), bamboo biochar (BC), magnetic coconut shell charcoal (MCSB), and magnetic bamboo biochar (MBC) were manufactured via co-pyrolysis, and their adsorption properties were tested. The pseudo-secondary (R2 = 0.980-0.985) adsorption kinetic fittings for the four biochas were superior to the pseudo-primary kinetics (R2 = 0.969-0.982). Unmodified biochar adsorption isotherms were more consistent with the Freundlich model, while magnetic biochar fitted Langmuir models better. The maximum adsorption capacity of MCSB for Cu(Ⅱ) reached 371.50 mg g-1. The adsorption mechanisms quantitatively analysis of the biochar indicated that chemical precipitation and ion exchange contributed to the adsorption, in which the magnetic biochar metal-π complexation also enhanced the adsorption. The pot experiment revealed that MCSB (2.0 %DW) significantly enhanced the biomass of lettuce, and facilitated the immobilization of DTPA-Cu (p < 0.05). SEM-EDS, XPS, and FTIR were utilized for morphological characterization and functional group identification, and the increased active adsorption sites (-OH, -COOH, CO, and Fe-O) of MCSB enhanced chemisorption and π-π EDA complexation with Cu(Ⅱ). EEM-PARAFAC and RDA analysis further elucidated that magnetic biochar immobilized copper and reduced biotoxicity (efficiency: 76.12%) by adjusting soil pH, phosphate, and SOM release (negative correlation). The presence of iron oxides (FeOx) promoted in situ adsorption of metallic copper and offered new insights into soil remediation.

Pb/As simultaneous removal from soil leachate of Pb/Zn smelting sites by magnetic biochar.

Lead (Pb) and arsenic (As) contaminated soils, caused by Pb and zinc (Zn) smelting activities, pose an urgent environmental issue. Magnetic biochar (MB) has been regarded as an increasingly appealing candidate for the remediation of multi-metals in contaminated soils or their leachate. Finding economically feasible preparation methods for MB and demonstrating its remediation potential is desperately required for the remediation of such complex smelting sites. In this study, a modified MB was prepared using an optimized co-precipitation method, and its application potential for Pb/As simultaneous removal based on the basic properties of a typical Pb/Zn smelting site was evaluated. The surface modifications of MB facilitated the encapsulation of various ultrafine iron oxide particles, predominantly γ-Fe2O3 and Fe3O4, whilst notably enhancing the presence of oxygen-containing surface functional groups. The adsorption of Pb(II) and As(III) by MB was well-described using the pseudo-second-order adsorption and Langmuir models. The existence of SO42- and Ca2+ in the soil leachate competed with the adsorption sites for Pb(II) and As(III). Notably, within the pH range of 5-9, the adsorption efficiency of Pb(II) by MB increased with the rising solution pH, whereas alterations in pH minimally affected the removal rate of As(III), maintaining a consistent removal rate exceeding 95%. Furthermore, dissolved organic matter (DOM) abundant in organic functional groups, particularly CO and CC groups, significantly augmented the adsorption affinity for both Pb(II) and As(III). An application rate of 2 g/L could effectively reduce the concentration of Pb(II) and As(III) in soil leachate to <0.05 mg/L. The findings demonstrated the potential of the prepared MB for simultaneous removal of As(III) and Pb(II) in soil leachate, which should be beneficial to multi-metals polluted soil remediation in Pb/Zn smelting sites.

Unlocking the potential of magnetic biochar in wastewater purification: a review on the removal of bisphenol A from aqueous solution.

Bisphenol A (BPA) is an essential and extensively utilized chemical compound with significant environmental and public health risks. This review critically assesses the current water purification techniques for BPA removal, emphasizing the efficacy of adsorption technology. Within this context, we probe into the synthesis of magnetic biochar (MBC) using co-precipitation, hydrothermal carbonization, mechanical ball milling, and impregnation pyrolysis as widely applied techniques. Our analysis scrutinizes the strengths and drawbacks of these techniques, with pyrolytic temperature emerging as a critical variable influencing the physicochemical properties and performance of MBC. We explored various modification techniques including oxidation, acid and alkaline modifications, element doping, surface functional modification, nanomaterial loading, and biological alteration, to overcome the drawbacks of pristine MBC, which typically exhibits reduced adsorption performance due to its magnetic medium. These modifications enhance the physicochemical properties of MBC, enabling it to efficiently adsorb contaminants from water. MBC is efficient in the removal of BPA from water. Magnetite and maghemite iron oxides are commonly used in MBC production, with MBC demonstrating effective BPA removal fitting well with Freundlich and Langmuir models. Notably, the pseudo-second-order model accurately describes BPA removal kinetics. Key adsorption mechanisms include pore filling, electrostatic attraction, hydrophobic interactions, hydrogen bonding, π-π interactions, and electron transfer surface interactions. This review provides valuable insights into BPA removal from water using MBC and suggests future research directions for real-world water purification applications.

A novel magnetic sludge biochar was prepared by making full use of internal iron in sludge combining KMnO4-NaOH modification to enhance the adsorption of Pb (â ¡), Cu (â ¡) and Cd (â ¡).

This study synthesized novel magnetic biochar (PCMN600) by KMnO4-NaOH combined modification using iron-containing pharmaceutical sludge to remove toxic metals from wastewater effectively. Various characterization experiments of engineered biochar showed that the modification process introduced ultrafine MnOx particles on the carbon surface and resulted in higher BET surface area and porosity along with more oxygen-containing surface functional groups. Batch adsorption studies indicated that the maximum adsorption capacities of PCMN600 for Pb2+, Cu2+ and Cd2+ were 181.82 mg/g, 30.03 mg/g and 27.47 mg/g, respectively, at a temperature of 25 °C and pH of 5.0, which were much higher than that of pristine biochar (26.46 mg/g, 6.56 mg/g and 6.40 mg/g). The adsorption datums of three toxic metal ions fitted well to the pseudo-second-order model and Langmuir isotherm, and the sorption mechanisms were identified as electrostatic attraction, ion exchange, surface complexation, cation-π interaction and precipitation. The strong magnetic properties of the engineered biochar endowed the adsorbent with remarkable reusability, and after five cycles of recycling, PCMN600 still retained nearly 80% of its initial adsorption capacities.

Effective decontamination of methylene blue from aqueous solutions using novel nano-magnetic biochar from green pea peels.

The conversion of agricultural waste into high-value carbon products has been an attractive area in waste management strategy. This study highlighted the synthesis and effectiveness of green pea peels (GPP), green pea biochar (GPBC), and nano-ferromagnetic green pea biochar (NFGPBC) by the ferrous/ferric co-precipitation synthesis method for eliminating cationic dyes molecules from solutions. The morphological, physicochemical, and structural properties of GPP, GPBC, and NFGPBC were approved by Scanning Electron Microscopy (SEM), Transmission Emission Microscopy (TEM), Energy Dispersive X-ray (EDX), Bruneau Emmett Teller (BET), Fourier Transform Infrared spectroscopy (FTIR), and X-ray Diffraction (XRD) techniques. Vibrating Sample Magnetometry (VSM) analysis confirmed the NFGPBC magnetization performance. The capacity of each adsorbent for methylene blue removal was evaluated at various parameters of material dosage (50-250 mg/150 mL), pH (2-12), initial concentration (50-250 mg/L), contact time (0-90 min) and temperature (20-60 °C). The three developed adsorbent materials GPP, GPBC, and NFGPBC, possessed reasonable BET surface areas of 0.6836, 372.54, and 147.88 m2g-1, and the corresponding monolayer adsorption capacities of 163.93, 217.40, and 175.44 mg/g, respectively. The superior performances of GPBC and NFGPBC were due to their increased surface area compared with the parent green pea peels (GPP). The results from adsorption kinetics studies of all prepared materials were pseudo-second-order and Elovich kinetics models. The thermodynamic parameters exhibited MB sorption's favorability, spontaneity, and endothermic nature. The NFGPBC material experienced Vander Waal forces, electrostatic interaction, hydrogen bonding, and hydrophobic interactions as predominant modes of the solid-liquid interaction. The regeneration, recycling, and reusability of the synthesized GPP, GPBC, and NFGPBC performed at five adsorption cycles revealed that NFGPBC demonstrated excellent cyclical performances attaining a minimum 8.9% loss in capacity due to paramagnetic properties. Thus, NFGPBC is a green, efficient, and eco-friendly material recommended for large-scale production and application in wastewater.

Treatment of nanofiltration membrane concentrates integrated magnetic biochar pretreatment with anaerobic digestion.

nanofiltration membrane concentrate (NMC) is an emerging type of wastewater with significant environmental concerns. which can be treated efficiently by an integrated method. In this study, magnetic biochar (MBC) pretreatment integrated with anaerobic digestion (AD) (MBC + AD) was used to treat NMC. Results showed that under the optimal MBC + AD conditions, 79%, 69.4%, 52.9%, and 86.5% of COD, total nitrogen (TN), chromaticity, and light absorbing substances were reduced. For heavy metals removal, 18.3%, 70.0%, 96.4%, 43.8% and 97.5% of Cr (VI), Cd, Pb, Cu and Zn were removed, respectively. LC-MS analysis indicated that p-nitrophenol (4-NP) diethyl and phthalate (DEP) were the main organic pollutants in NMC with a removal rate of 60% and 90%. Compared with single AD, in MBC + AD samples, bacterial activity was improved, and genus DMER64 (23.2%) was dominant. The predominant archaea were Methanocorpusculum (53.3%) and Methanosarcina (25.3%), with microbial restructuring and slight methane generation. Additionally, metabolic pathway prediction revealed that both bacterial and archaeal metabolism were significantly enhanced, contributing to the central functional pathways, namely microbial activity metabolism and biodegradation metabolism. In addition, the significantly increased genera Syner-01, Vulcanibacillus, Methanocorpusculum, and Norank_c_Bathyarchaeia were significantly positively related to metabolic function. This finding demonstrated that MBC + AD enhanced contaminant removal, mainly by regulating bacterial diversity and activity. Moreover, the toxicity of NMC decreased after MBC + AD treatment. This study provides a potential biological strategy for the treatment of membrane concentrates and water recovery.

Improved Cr (VI) adsorption performance in wastewater and groundwater by synthesized magnetic adsorbent derived from Fe3O4 loaded corn straw biochar.

This work developed an easy method to utilize corn straw (CS) waste for sustainable development and reduce the volume of waste volume as well as bring value-added. The magnetic adsorbent was prepared by loading Fe3O4 onto biochar derived from corn straw (Fe@CSBC), then used for capturing Cr (VI) in groundwater and wastewater samples. The characterization of adsorbents showed that Fe3O4 was successfully loaded on corn straw biochar (CSBC) and contributed to the improvement of the surface area, and surface functional groups like Fe-O, Fe-OOH, CO, and O-H. The presence of iron oxide was further confirmed by XPS and XRD analysis and a magnetization value of 35.6 emu/g was obtained for Fe@CSBC. The highest uptake capacity of Cr (VI) onto Fe@CSBC and CSBC by monolayer were 138.8 and 90.6 mg/g, respectively. By applying magnetic adsorbent Fe@CSBC for the treatment of groundwater and wastewater samples, the chromium could be removed up to 90.3 and 72.6%, respectively. The remaining efficiency of Cr (VI) was found to be 84.5% after four times reused Fe@CSBC, demonstrating the great recyclable ability of the adsorbent. In addition, several interactions between Cr (VI) and Fe@CSBC like ion exchange, complexation, and reduction reaction were discussed in the proposed adsorption mechanism. This study brings an efficient method to turn corn straw biomass into an effective magnetic adsorbent with high adsorption performance and good reusability of Cr (VI) in groundwater as well as in wastewater.

Date palm-magnetized biochar for in-situ stabilization of toxic metals in mining-polluted soil: evaluation using single-step extraction methods and phytoavailability.

Mining activities provide a pathway for the entry and accumulation of various heavy metals in soil, which ultimately leads to severe environmental pollution. Utilization of various immobilizing agents could restore such contaminated soils. Therefore, in this study, date palm-derived biochars (BCs: produced at 300 °C, 500 °C and 700 °C) and magnetized biochars (MBCs) were employed to stabilize heavy metals (Cd, Pb, Cu and Zn) in mining polluted soil. Metal polluted soil was amended with BCs and MBCs at w/w ratio of 2% and cultivated with wheat (Triticum aestivum L.) in a greenhouse. After harvesting, dry and fresh biomass of plants were recorded. The soil and plant samples were collected, and the concentrations of heavy metals were measured after extracting with water, DTPA (diethylenetriaminepentaacetic acid), EDTA (ethylenediaminetetraacetic acid), and acetic acid. BCs and MBCs resulted in reduced metal availability and uptake, with higher fresh and dry biomass (>36%). MBCs showed maximum decrease (>70%) in uptake and shoot concentration of metals, as these reductions for Cd and Pb reached below the detection limits. Among all single-step extractions, the DTPA-extractable metals showed a significant positive correlation with shoot concentrations of tested metals. Thus, the synthesized BCs and MBCs could effectively be used for stabilizing heavy metals and improve plant productivity in multi-contaminated soils. However, future studies should focus on long term field trials to restore contaminated mining soils using modified biochars.

This study has demonstrated the performance of magnetized biochars for in-situ stabilization of toxic metals (Cd, Pb, Cu and Zn) in mining polluted soil by single extraction method. All the produced BCs and magnetized BCs showed great potential in immobilizing the metals and reducing their availability in soil, consequently decreasing their shoot concentration and plant uptake. Significant negative correlations were observed between soil pH and metal extraction from applied extraction methods such as water soluble, DTPA, and EDTA extractions. We found DTPA as a suitable extractant for investigating metal uptake in plant in multi-contaminated soils. Treatments with MBCs showed maximum decrease in plant uptake and concentration of studied metals. Thus, application of MBCs could efficiently immobilize soil heavy metals.

Effect of CeO2-Reinforcement on Pb Absorption by Coconut Coir-Derived Magnetic Biochar.

Magnetic separable biochar holds great promise for the treatment of Pb2+-contaminated wastewater. However, the absorption effect of unmodified magnetic biochar is poor. Considering this gap in knowledge, CeO2-doped magnetic coconut coir biochar (Ce-MCB) and magnetic coconut coir biochar (MCB) for Pb2+ absorption were prepared by the impregnation method, and the efficiency of Ce-MCB for Pb2+ absorption was evaluated in comparison with MCB. Conducting the absorption experiments, the study provided theoretical support for the exploration of the absorption mechanism. The quantitative analysis exposed that the enhanced absorption capacity of Ce-MCB was attributed to the increase in oxygen-containing functional groups and mineral precipitation. The Langmuir and Freundlich isotherm model showed that Ce-MCB is a suitable adsorbent for Pb2+. The absorption characteristics of Ce-MCB was fit well with the pseudo-second-order (PSO) and Langmuir models, which revealed that the absorption of Pb2+ in water was monolayer chemisorption with a maximum theoretical adsorption capacity of 140.83 mg·g-1. The adsorption capacity of Ce-MCB for Pb(II) was sustained above 70% after four cycles. In addition, the saturation magnetization intensity of Ce-MCB was 7.15 emu·g-1, which was sufficient to separate out from the solution. Overall, Ce-MCB has wide application prospects in terms of biomass resources recycling and environmental conservation.

Magnetic biochar promotes the risk of mobile genetic elements propagation in sludge anaerobic digestion.

Mobile genetic elements (MGEs) mediated horizontal gene transfer is the primary reason for the propagation of antibiotic resistance genes in environment. The behavior of MGEs under magnetic biochar pressure in sludge anaerobic digestion (AD) is still unknown. This study evaluated the effects of different dosage magnetic biochar on the MGEs in AD reactors. The results showed that the biogas yield was highest (106.68 ± 1.16 mL g-1 VSadded) with adding optimal dosage of magnetic biochar (25 mg g-1 TSadded), due to it increased the microorganism's abundance involved in hydrolysis and methanogenesis. While, the total absolute abundance of MGEs in the reactors with magnetic biochar addition increased by 11.58%-77.37% compared with the blank reactor. When the dosage of magnetic biochar was 12.5 mg g-1 TSadded, the relative abundance of most MGEs was the highest. The enrichment effect on ISCR1 was the most significant, and the enrichment rate reached 158.90-214.16%. Only the intI1 abundance was reduced and the removal rates yield 14.38-40.00%, which was inversely proportional to the dosage of magnetic biochar. Co-occurrence network explored that Proteobacteria (35.64%), Firmicutes (19.80%) and Actinobacteriota (15.84%) were the main potential host of MGEs. Magnetic biochar changed MGEs abundance by affecting the potential MGEs-host community structure and abundance. Redundancy analysis and variation partitioning analysis showed that the combined effect of polysaccharides, protein and sCOD exhibited the greatest contribution (accounted for 34.08%) on MGEs variation. These findings demonstrated that magnetic biochar increases the risk of MGEs proliferation in AD system.

The Removal of Pollutants from Wastewater Using Magnetic Biochar: A Scientometric and Visualization Analysis.

In recent years, the use of magnetic biochar in wastewater treatment has shown significant effects and attracted scholars' attention. However, due to the relatively short research time and the lack of systematic summaries, it is difficult to provide a more in-depth analysis. This study utilizes RStudio and CiteSpace software to comprehensively analyze the research trends and progress of magnetic biochar in wastewater treatment. The analysis of bibliometrics is performed on 551 relevant papers retrieved from the Web of Science, spanning the period between 2011 and 2022. The most influential countries, institutions, journals, disciplinary distribution, and top 10 authors and papers in this field have been identified. The latest dataset has been used for keyword clustering and burst analysis. The results indicated that: (1) Bin Gao is the most influential author in this field, and high-level journals such as Bioresource Technology are more inclined to publish articles in the field of magnetic biochar. (2) Research in this field has predominantly focused on the removal of heavy metals and organic compounds. Keyword burst analysis shows a shift in research direction towards the removal of complex organic pollutants recently. (3) For the future development of magnetic biochar, an environment-friendly approach, economic viability, and joint technology are the directions that need more exploration. Finally, this paper provides a summary of the various adsorption mechanisms of magnetic biochar and several common modification methods, aiming to assist scholars in their research endeavors.

Magnetic Biochar Derived from Fenton Sludge/CMC for High-Efficiency Removal of Pb(II): Synthesis, Application, and Mechanism.

Magnetic biochar composites (MBC) were developed by a simple one-step pyrolysis method using Fenton sludge waste solid and carboxymethyl cellulose sodium. Detailed morphological, chemical, and magnetic characterizations corroborate the successful fabrication of MBC. Batch adsorption experiments show that the synthesized MBC owns high-efficiency removal of Pb(II), accompanied by ease-of-separation from aqueous solution using magnetic field. The experiment shows that the equilibrium adsorption capacity of MBC for Pb(II) can reach 199.9 mg g-1, corresponding to a removal rate of 99.9%, and the maximum adsorption capacity (qm) reaches 570.7 mg g-1, which is significantly better than that of the recently reported magnetic similar materials. The adsorption of Pb(II) by MBC complies with the pseudo second-order equation and Langmuir isotherm model, and the adsorption is a spontaneous, endothermic chemical process. Investigations on the adsorption mechanism show that the combination of Pb(II) with the oxygen-containing functional groups (carboxyl, hydroxyl, etc.) on biochar with a higher specific surface area are the decisive factors. The merits of reusing solid waste resource, namely excellent selectivity, easy separation, and simple preparation make the MBC a promising candidate of Pb(II) purifier.

Synthesis and application of lanthanum-doped magnetic biochar composite adsorbent for removal of fluoride from water.

Fluoride levels greater than 1.5 mg/L in drinking water are a global environmental issue that can seriously harm the health of humans. One of the most effective techniques for defluoridating water is adsorption. The main drawbacks of many adsorbent materials include their poor adsorption capabilities, prolonged contact times, excessively low or high pH levels, and high dosages. The biochar-based magnetic nanocomposite adsorbent was synthesized in the current study and used as an adsorbent for water defluoridation. Through slow pyrolysis, coffee husk waste was converted to biochar. The composite was created by chemically co-precipitating iron and lanthanum oxide nanoparticles onto the surface of biochar. By using X-ray diffraction analysis (XRD), Fourier transform infrared spectrometry (FTIR), Brunauer-Emmett-Teller (BET), and pHPZC values, researchers were able to describe the magnetic biochar nanocomposite material. The Central Composite Design (CCD), which uses four input variables including dosage (2-5 g/L), solution pH (4-8), contact time (30-70 min), and initial concentration (10-20 mg/L), was used to design the experiments. The quadratic model indicated that the ideal conditions for removing 98.994% of the fluoride from water (adsorbent dosage of 5 g L-1, pH 5.74, contact period of 60 min, and initial concentration of 12.245 mg/L) would be attained. The average triplicate value in ideal circumstances produced a removal effectiveness of 98.51%, demonstrating the proposed response surface's capacity for prediction. The findings of this investigation showed that the magnetic biochar nanocomposite that was created is an effective fluoride adsorbent.

Life cycle assessment of biodiesel production by using impregnated magnetic biochar derived from waste palm kernel shell.

Biodiesel is renewable, biodegradable, biocompatible (non-toxic) and environmentally friendly, which emits less pollution than traditional fossil-based diesel, making it the most promising and ideal option. However, biodiesel is facing many current issues, mostly related to the utilisation of homogeneous catalytic technology, and this circumstance obstructs its potential development and advancement. Therefore, new pathways for biodiesel production need to be explored, and the aforementioned issues need to be addressed. Recently, a study was conducted on the impregnated magnetic biochar derived from a waste palm kernel shell (PKS) catalyst that can replace conventional catalysts due to its reusability property. Nevertheless, the environmental impacts of impregnated magnetic biochar derived from waste PKS catalyst for biodiesel production are yet to be studied. This study focuses on the evaluation of the life cycle assessment (LCA) of palm-based cooking oil for biodiesel production catalysed by impregnated magnetic biochar derived from waste PKS. Simapro was used in this study to evaluate the impact assessment methodologies. Case 1 (6.64 × 102 Pt) has contributed less to environmental impacts than Case 2 (1.83 × 103 Pt). This indicates purchasing refined palm oil for biodiesel production may reduce environmental impacts by 64% compared to producing biodiesel from raw fruit bunches. In the midpoint assessment, the transesterification process was identified as the hotspot and marine aquatic ecotoxicity as the highest impact category with a value of 1.00 × 106 kg 1,4-DB eq for 1 tonne of biodiesel produced. The endpoint results showed that Case 1 revealed the greatest impact on the transesterification process, with cumulative damage of 461 Pt. Scenario without processing the raw palm fruit bunches to obtained palm oil was better than Case 2. Further research should be conducted on life cycle cost and sensitivity analysis to evaluate the economic feasibility and promote sustainable biodiesel production.

Efficiency of iron modified Pyrus pyrifolia peels biochar as a novel adsorbent for methylene blue dye abatement from aqueous phase: equilibrium and kinetic studies.

Herein, a magnetic biochar adsorbent based on Pyrus pyrifolia discarded peels impregnated with precursor FeCl3·6H2O was fabricated and probed as a low-cost adsorbent for toxic cationic dye methylene blue (MB). The textural characterization of Pyrus pyrifolia magnetic biochar (PMBC) obtained from BET analysis exhibited its mesoporous nature with SBET of 133.960 m2/g. The physicochemical characteristics of PMBC were elucidated using XRD, FTIR, SEM-EDX and TEM techniques. The impregnation of FeCl3 has a significant impact on the microstructure of Pyrus pyrifolia based biochar which resulted in enhancement in adsorption efficiency of PMBC. The sorption parameters adsorbent dosage, time, initial MB concentration, and pH were thoroughly elucidated using a batch methodology which were found to be 0.8 g/L, 40 min, 90 mg/L and 6, respectively. Temkin and pseudo-second-order rate equation respectively appropriated the equilibrium data than the rest of the models. The maximum adsorption capacity determined by the Langmuir model was found to be 967.80 mg/g. The adsorbent exhibited better regeneration up to 3 cycles validating its practical usage. The facile synthesis, economic, and environmentally benign characteristic of Pyrus pyrifolia magnetic biochar corroborated it as a highly efficient adsorbent to sequester MB from an aqueous phase.

Pyrus pyrifolia discarded peels impregnated with FeCl₃·6H₂O were exploited as a novel magnetic biosorbent for the abatement of cationic dye from wastewater. The impact of operative variables was analyzed using batch methodology. Isotherm and kinetic modeling on equilibrium data was executed via non-linear approach which is very reliable in comparison to linear way.