Bovine Serum Albumin Bends Over Backward to Interact with Aged Plastics: A Model for Understanding Protein Attachment to Plastic Debris.

Plastic pollution, a major environmental crisis, has a variety of consequences for various organisms within aquatic systems. Beyond the direct toxicity, plastic pollution has the potential to absorb biological toxins and invasive microbial species. To better understand the capability of environmental plastic debris to adsorb these species, we investigated the binding of the model protein bovine serum albumin (BSA) to polyethylene (PE) films at various stages of photodegradation. Circular dichroism and fluorescence studies revealed that BSA undergoes structural rearrangement to accommodate changes to the polymer's surface characteristics (i.e., crystallinity and oxidation state) that occur as the result of photodegradation. To understand how protein structure may inform docking of whole organisms, we studied biofilm formation of bacteriaShewanella oneidensison the photodegraded PE. Interestingly, biofilms preferentially formed on the photodegraded PE that correlated with the state of weathering that induced the most significant structural rearrangement of BSA. Taken together, our work suggests that there are optimal physical and chemical properties of photodegraded polymers that predict which plastic debris will carry biochemical or microbial hitchhikers.

Plastic Paradox in Blue Carbon Ecosystems.

Plastics are rapidly accumulating in blue carbon ecosystems, i.e., mangrove forests, tidal marshes, and seagrass meadows. Accumulated plastic is diverted from the ocean, but the extent and nature of impacts on blue carbon ecosystem processes, including carbon sequestration, are poorly known. Here, we explore the potential positive and negative consequences of plastic accumulation in blue carbon ecosystems. We highlight the effects of plastic accumulation on organic carbon stocks and sediment biogeochemistry through microbial metabolism. The notion of beneficial plastic accumulation in blue carbon ecosystems is controversial, yet considering the alternative impacts of plastics on oceanic and aboveground environments, this may be the "lesser of evils". Using environmental life cycle impact assessment, we propose a research framework to address the potential positive and negative impacts of plastic accumulation in blue carbon ecosystems. Considering the multifaceted benefits, we prioritize expanding and managing blue carbon ecosystems, which may help with ecosystem conservation, as well as mitigating the negative effects of plastic.

A City-Wide Emissions Inventory of Plastic Pollution.

A global agreement on plastic should have quantitative reduction targets for the emissions of plastic pollution and regular measurements to track success. Here, we present a framework for measuring plastic emissions, akin to greenhouse gas emissions, and demonstrate its utility by calculating a baseline measurement for the City of Toronto in Ontario, Canada. We identify relevant sources of plastic pollution in the city, calculate emissions for each source by multiplying activity data by emission factors for each source, and sum the emissions to obtain the total annual emissions of plastic pollution generated. Using Monte Carlo simulations, we estimate that 3,531 to 3,852 tonnes (T) of plastic pollution were emitted from Toronto in 2020. Littering is the largest source overall (3,099 T), and artificial turf is the largest source of microplastic (237 T). Quantifying source emissions can inform the most effective mitigation strategies to achieve reduction targets. We recommend this framework be scaled up and replicated in cities, states, provinces, and countries around the world to inform global reduction targets and measure progress toward reducing plastic pollution.

Mapping Plastic and Plastic Additive Cycles in Coastal Countries: A Norwegian Case Study.

The growing environmental consequences caused by plastic pollution highlight the need for a better understanding of plastic polymer cycles and their associated additives. We present a novel, comprehensive top-down method using inflow-driven dynamic probabilistic material flow analysis (DPMFA) to map the plastic cycle in coastal countries. For the first time, we covered the progressive leaching of microplastics to the environment during the use phase of products and modeled the presence of 232 plastic additives. We applied this methodology to Norway and proposed initial release pathways to different environmental compartments. 758 kt of plastics distributed among 13 different polymers was introduced to the Norwegian economy in 2020, 4.4 Mt was present in in-use stocks, and 632 kt was wasted, of which 15.2 kt (2.4%) was released to the environment with a similar share of macro- and microplastics and 4.8 kt ended up in the ocean. Our study shows tire wear rubber as a highly pollutive microplastic source, while most macroplastics originated from consumer packaging with LDPE, PP, and PET as dominant polymers. Additionally, 75 kt of plastic additives was potentially released to the environment alongside these polymers. We emphasize that upstream measures, such as consumption reduction and changes in product design, would result in the most positive impact for limiting plastic pollution.

Replacing Plastics with Alternatives Is Worse for Greenhouse Gas Emissions in Most Cases.

Plastics are controversial due to their production from fossil fuels, emissions during production and disposal, potential toxicity, and leakage to the environment. In light of these concerns, calls to use less plastic products and move toward nonplastic alternatives are common. However, these calls often overlook the environmental impacts of alternative materials. This article examines the greenhouse gas (GHG) emission impact of plastic products versus their alternatives. We assess 16 applications where plastics are used across five key sectors: packaging, building and construction, automotive, textiles, and consumer durables. These sectors account for about 90% of the global plastic volume. Our results show that in 15 of the 16 applications a plastic product incurs fewer GHG emissions than their alternatives. In these applications, plastic products release 10% to 90% fewer emissions across the product life cycle. Furthermore, in some applications, such as food packaging, no suitable alternatives to plastics exist. These results demonstrate that care must be taken when formulating policies or interventions to reduce plastic use so that we do not inadvertently drive a shift to nonplastic alternatives with higher GHG emissions. For most plastic products, increasing the efficiency of plastic use, extending the lifetime, boosting recycling rates, and improving waste collection would be more effective for reducing emissions.

The Duration of Dry Events Promotes PVC Film Fragmentation in Intermittent Rivers.

The majority of microplastics (MPs) found in the environment originate from plastic fragmentation occurring in the environment and are influenced by environmental factors such as UV irradiation and biotic interactions. However, the effects of river drying on plastic fragmentation remain unknown, despite the global prevalence of watercourses experiencing flow intermittence. This study investigates, through laboratory experiments, the coupled effects of drying duration and UV irradiation on PVC film fragmentation induced by artificial mechanical abrasion. This study shows that PVC film fragmentation increases with drying duration through an increase in the abundance and size of formed MPs as well as mass loss from the initial plastic item, with significant differences for drying durations >50% of the experiment duration. The average abundance of formed MPs in treatments exposed to severe drying duration was almost two times higher than in treatments nonexposed to drying. Based on these results, we developed as a proof of concept an Intermittence-Based Plastic Fragmentation Index that may provide insights into plastic fragmentation occurring in river catchments experiencing large hydrological variability. The present study suggests that flow intermittence occurring in rivers and streams can lead to increasing plastic fragmentation, unraveling new insights into plastic pollution in freshwater systems.

Life-Cycle Environmental Impacts of Additive-Related Chemicals in Polyvinyl Chloride Plastics and the Mitigation Potential.

Plastic additive-related chemicals, particularly in polyvinyl chloride (PVC) plastics, have become a key issue in plastic pollution. Although addressing plastic pollution through the life-cycle approach is crucial, the environmental impacts of typical plastic additive-related chemicals in PVC plastics during the cradle-to-gate stage remain unexplored. Consequently, managing the life-cycle environmental impacts of these additives remains challenging. Herein, the environmental impacts of 23 typical plastic additive-related chemicals and six PVC plastic products were evaluated throughout the cradle-to-gate life-cycle stage using a life cycle assessment-material flow analysis (LCA-MFA) coupled model. The results indicate that plastic additives significantly contribute to the environmental impacts of PVC plastic products across various end point indicators, ranging from 8.7 to 40.6%. Additionally, scenario analysis (SA) reveals that conventional strategies for addressing plastic pollution may not be highly effective in mitigating the environmental impacts associated with plastic additives. Specifically, compared to primary polymers, these additives exhibit 4 to 13% lower mitigation potential under the same policy scenarios. However, technical adjustment strategies targeting additives show a mitigation potential of 12 to 39%, suggesting that guiding the plastic additive industry toward green transformation is a key strategy for reducing environmental impacts.

Traded Plastic, Traded Impacts? Designing Counterfactual Scenarios to Assess Environmental Impacts of Global Plastic Waste Trade.

The global trade of plastic waste has raised environmental concerns, especially regarding pollution in waste-importing countries. However, the overall environmental contribution remains unclear due to uncertain treatment shares between handling plastic waste abroad and domestically. Here, we conduct a life cycle assessment of global plastic waste trade in 2022 across 18 countries and six plastic waste types, alongside three "nontrade" counterfactual scenarios. By considering the required cycling rate, which balances importers' costs and recycling revenues, we find that the trade resulted in lower environmental impacts than treating domestically with the average treatment mix. The trade scenario alone reduced climate change impact by 2.85 million tonnes of CO2 equivalent and mitigated damages to ecosystem quality, human health, and resource availability by 12 species-years, 6200 disability-adjusted life years (DALYs), and 1.4 billion United States dollars (USD in 2013), respectively. These results underscore the significance of recognizing plastic waste trade as a pivotal factor in regulating global secondary plastic production when formulating a global plastics treaty.

Generation of macro- and microplastic databases by high-throughput FTIR analysis with microplate readers.

FTIR spectral identification is today's gold standard analytical procedure for plastic pollution material characterization. High-throughput FTIR techniques have been advanced for small microplastics (10-500 µm) but less so for large microplastics (500-5 mm) and macroplastics (> 5 mm). These larger plastics are typically analyzed using ATR, which is highly manual and can sometimes destroy particles of interest. Furthermore, spectral libraries are often inadequate due to the limited variety of reference materials and spectral collection modes, resulting from expensive spectral data collection. We advance a new high-throughput technique to remedy these problems using FTIR microplate readers for measuring large particles (> 500 µm). We created a new reference database of over 6000 spectra for transmission, ATR, and reflection spectral collection modes with over 600 plastic, organic, and mineral reference materials relevant to plastic pollution research. We also streamline future analysis in microplate readers by creating a new particle holder for transmission measurements using off-the-shelf parts and fabricating a nonplastic 96-well microplate for storing particles. We determined that particles should be presented to microplate readers as thin as possible due to thick particles causing poor-quality spectra and identifications. We validated the new database using Open Specy and demonstrated that additional transmission and reflection spectra reference data were needed in spectral libraries.

Green carbon and the chemical industry of the future.

The pressing need to mitigate climate change and drastically reduce environmental pollution and loss of biodiversity has precipitated a so-called energy transition aimed at the decarbonization of energy and defossilization of the chemical industry. The goal is a carbon-neutral (net-zero) society driven by sustainable energy and a circular bio-based economy relying on renewable biomass as the raw material. It will involve the use of green carbon, defined as carbon derived from terrestrial or aquatic biomass or organic waste, including carbon dioxide and methane emissions. It will also necessitate the accompanying use of green hydrogen that is generated by electrolysis of water using a sustainable source of energy, e.g. solar, wind or nuclear. Ninety per cent of the industrial chemicals produced in oil refineries are industrial monomers that constitute the precursors of a large variety of polymers, many of which are plastics. Primary examples of the latter are polyolefins such as polyethylene, polypropylene, polyvinyl chloride and polystyrene. Polyolefins are extremely difficult to recycle back to the olefin monomers and discarded polyolefin plastics generally end up as the plastic waste that is responsible for the degradation of our natural habitat. By contrast, waste biomass, such as the lignocellulose contained in forestry residues and agricultural waste, constitutes a renewable feedstock for the sustainable production of industrial monomers and the corresponding polymers. The latter could be the same polyolefins that are currently produced in oil refineries but a more attractive long-term alternative is to produce polyesters and polyamides that can be recycled back to the original monomers: a paradigm shift to a truly bio-based circular economy on the road to a net-zero chemical industry. This article is part of the discussion meeting issue 'Green carbon for the chemical industry of the future'.

Metabolomics revealed disruptions in amino acid and antioxidant biochemistry in Daphnia magna exposed to industrial effluents associated with plastic and polymer production.

Industrial wastewater effluents are a major source of chemicals in aquatic environments, and many of these chemicals may negatively impact aquatic life. In this study, the crustacean Daphnia magna, a common model organism in ecotoxicity studies, was exposed for 48 h to nine different industrial effluent samples from manufacturing facilities associated with the production of plastics, polymers, and coating products at a range of dilutions: 10, 25, 50, 100% (undiluted). A targeted metabolomic-based approach using liquid chromatography-tandem mass spectrometry (LC-MS/MS) was used to quantify polar metabolites from individual daphnids that survived the 48 h exposure. Multivariate analyses and metabolite changes revealed metabolic perturbations across all effluent samples studied, with non-monotonic responses and both up and downregulation relative to the unexposed control. Pathway analyses indicated the disruption of similar and distinct pathways, mostly connected to protein synthesis, amino acid metabolism, and antioxidant processes. Overall, we observed disruptions in Daphnia biochemistry that were similar across the effluent samples, but with unique features for each effluent sample. Additionally, non-monotonic heightened responses suggested additive and/or synergistic interactions between the chemicals within the industrial effluents. These findings demonstrate that targeted metabolomic approaches are a powerful tool for the biomonitoring of aquatic ecosystems in the context of complex mixtures, such as industrial wastewater effluents.

Microplastic pollution in wild and aquacultured Mediterranean mussels from the Sea of Marmara: Abundance, characteristics, and health risk estimations.

Microplastic (MP) pollution raises urgent concerns about the environmental well-being and the safety of the food supply for humans. Mussels are essential filter-feeding organisms that may be highly susceptible to MPs uptake due to their global distribution and sedentary lifestyle. There is also a knowledge gap regarding MP levels in commercially-farmed and wild-sourced mussels for human consumption, creating gaps in risk identification for food safety. This study aims to fill this gap in understanding by (a) investigating the presence and abundance of MPs in both wild and aquacultured mussels collected from six different stations in the Sea of Marmara, (b) comparing the levels of MPs between aquacultured and wild mussels, and (c) evaluating the potential health risks associated with the consumption of these contaminated mussels. Polymer types were verified by ATR-FTIR (Attenuated Total Reflectance Fourier Transform- Infrared Spectroscopy), and 6 different polymers have been identified. Among the total 753 identified MPs, the majority (79.8%) were fibers, with the predominant size range (42.4%) falling between 0.1 and 0.5 mm. Consuming wild mussels was associated with a 187.6% higher risk of MP intake compared to aquaculture. A consumer can potentially be exposed to 133.11 to 844.86 MP particles when consuming a 100 g serving of mussels, with risks becoming more significant as portion sizes increase, as is the case in some countries where portions reach 225 g. In this study, detailed information is presented on MP pollution in both wild and aquacultured mussels from Sea of Marmara, providing valuable insights for ensuring food safety, effective management and control of MP pollution in this region.

From pollution to solutions: Insights into the sources, transport and management of plastic debris in pristine and urban rivers.

River systems are important recipients of environmental plastic pollution and have become key pathways for the transfer of mismanaged waste from the land to the ocean. Understanding the sources and fate of plastic debris, including plastic litter (>5 mm) and microplastics (MPs) (<5 mm), entering different riverine systems is essential to mitigate the ongoing environmental plastic pollution crisis. We comprehensively investigated the plastic pollution in the catchments of two rivers in the Yangtze River basin: an urban river, the Suzhou section of the Beijing-Hangzhou Grand Canal (SZ); and a pristine rural river, the Jingmen section of the Hanjiang River (JM). The abundance of plastic pollutants in SZ was significantly higher than in JM: 0.430 ± 0.450 items/m3 and 0.003 ± 0.003 items/m3 of plastic litter in the water; 23.47 ± 25.53 n/m3 and 2.78 ± 1.55 n/m3 MPs in the water; and 218.82 ± 77.40 items/kg and 5.30 ± 1.99 items/kg of MPs in the sediment, respectively. Plastic litter and MPs were closely correlated in abundance and polymer composition. Overall, the polymer type, shape and color of MPs were dominant by polypropylene (42.5%), fragment (60.4%) and transparent (40.0%), respectively. Source tracing analysis revealed that packaging, shipping, and wastewater were the primary sources of plastic pollutants. The mantel analysis indicated that socio-economic and geospatial factors play crucial roles in driving the hotspot formation of plastic pollution in river networks. The composition of the MP communities differed significantly between the sediments and the overlying water. The urban riverbed sediments had a more pronounced pollutant 'sink' effect compared with the pristine rivers. These findings suggested that the modification of natural streams during urbanization may influence the transport and fate of plastic pollutants in them. Our results offer pivotal insights into effective preventive measures.

An insight decipher on photocatalytic degradation of microplastics: Mechanism, limitations, and future outlook.

Plastic material manufacturing and buildup over the past 50 years has significantly increased pollution levels. Microplastics (MPs) and non-biodegradable residual plastic films have become the two most pressing environmental issues among the numerous types of plastic pollution. These tiny plastic flakes enter water systems from a variety of sources, contaminating the water. Since MPs can be consumed by people and aquatic species and eventually make their way into the food chain, their presence in the environment poses a serious concern. Traditional technologies can remove MPs to some extent, but their functional groups, stable covalent bonds, and hydrophobic nature make them difficult to eliminate completely. The urgent need to develop a sustainable solution to the worldwide contamination caused by MPs has led to the exploration of various techniques. Advanced oxidation processes (AOPs) such as photo-catalytic oxidation, photo-degradation, and electrochemical oxidation have been investigated. Among these, photocatalysis stands out as the most promising method for degrading MPs. Photocatalysis is an environmentally friendly process that utilizes light energy to facilitate a chemical reaction, breaking down MPs into carbon dioxide and water-soluble hydrocarbons under aqueous conditions. In photocatalysis, semiconductors act as photocatalysts by absorbing energy from a light source, becoming excited, and generating reactive oxygen species (ROS). These ROS, including hydroxyl radicals (•OH) and superoxide ions ( [Formula: see text] ), play a crucial role in the degradation of MPs. This extensive review provides a detailed exploration of the mechanisms and processes underlying the photocatalytic removal of MPs, emphasizing its potential as an efficient and environmentally friendly approach to address the issue of plastic pollution.

Microplastics footprint in nature reserves-a case study on the microplastics in the guano from Yancheng Wetland Rare Birds National Nature Reserve, China.

Bio-ingestion of microplastics poses a global threat to ecosystems, yet studies within nature reserves, crucial habitats for birds, remain scarce despite the well-documented ingestion of microplastics by avian species. Located in Jiangsu Province, China, the Yancheng Wetland Rare Birds Nature Reserve is home to diverse bird species, including many rare ones. This study aimed to assess the abundance and characteristics of microplastics in common bird species within the reserve, investigate microplastic enrichment across different species, and establish links between birds' habitat types and microplastic ingestion. Microplastics were extracted from the feces of 110 birds, with 84 particles identified from 37.27% of samples. Among 8 species studied, the average microplastic abundance ranged from 0.97 ± 0.47 to 43.43 ± 61.98 items per gram of feces, or 1.5 ± 0.87 to 3.4 ± 1.50 items per individual. The Swan goose (Anser cygnoides) exhibited the highest microplastic abundance per gram of feces, while the black-billed gull (Larus saundersi) had the highest abundance per individual. The predominant form of ingested microplastics among birds in the reserve was fibers, with polyethylene being the most common polymer type. Significant variations in plastic exposure were observed among species and between aquatic and terrestrial birds. This study represents the first quantitative assessment of microplastic concentrations in birds within the reserve, filling a crucial gap in research and providing insights for assessing microplastic pollution and guiding bird conservation efforts in aquatic and terrestrial environments.

Phthalates and other organic chemicals in agricultural soils after use of different types of conventional and biodegradable plastics.

Various plastic materials are used in contact with agricultural soil, like mulching films, crop covers, weed controlling fabrics and nets. Polyethylene (PE) mulches have already been recognized as a significant source of plastic in soil and they have been shown to contain additives like phthalates, known as endocrine disruptors. However, other agricultural plastics are less studied, and little is known on the substances potentially released from them endangering biodiversity and the human health. This research aims to assess whether different agricultural plastics release additives into soil and to compare the release among various materials. We collected soil samples from 38 agricultural fields where conventional mulching films (PE), weed controlling fabrics (PP), biodegradable mulches based on polybutylene adipate terephthalate (PBAT), frost covers (PP), and oxo-degradable films (at least OXO-PE) were used. We analyzed the soils for phthalates and acetyl tributyl citrate (ATBC), used as plastic additives, and for polycyclic aromatic hydrocarbons (PAH) and dodecane that have high affinity for plastics. In comparison to the control soils, dibutylphthalate (DBP) and ATBC concentrations were significantly higher in soils mulched with PE and, partly, with biodegradable films. DBP concentration found in soil samples ranged between below the limit of quantification at a control site (1.5 µg kg-1) to 135 µg kg-1 at a site mulched with OXO-PE. The highest ATBC concentration, 22 ± 6 µg kg-1, was registered in a site mulched with PE, showing a statistically significant difference not only in comparison to the controls but also when compared to sites mulched with OXO-PE (p = 0.029) and PBAT (p < 0.009). On the contrary, the use of agricultural plastics did not influence the concentration of PAHs and dodecane. Our results indicate that agricultural plastics are a source of some organic chemicals to agricultural soils, including phthalates that are known for posing threat to soil ecosystem and human health.

Review of Methods for Automatic Plastic Detection in Water Areas Using Satellite Images and Machine Learning.

Ocean plastic pollution is one of the global environmental problems of our time. "Rubbish islands" formed in the ocean are increasing every year, damaging the marine ecosystem. In order to effectively address this type of pollution, it is necessary to accurately and quickly identify the sources of plastic entering the ocean, identify where it is accumulating, and track the dynamics of waste movement. To this end, remote sensing methods using satellite imagery and aerial photographs from unmanned aerial vehicles are a reliable source of data. Modern machine learning technologies make it possible to automate the detection of floating plastics. This review presents the main projects and research aimed at solving the "plastic" problem. The main data acquisition techniques and the most effective deep learning algorithms are described, various limitations of working with space images are analyzed, and ways to eliminate such shortcomings are proposed.

Mapping Microplastics in Humans: Analysis of Polymer Types, and Shapes in Food and Drinking Water-A Systematic Review.

Microplastics (MPs) pervade the environment, infiltrating food sources and human bodies, raising concerns about their impact on human health. This review is focused on three key questions: (i) What type of polymers are humans most exposed to? (ii) What are the prevalent shapes of MPs found in food and human samples? (iii) Are the data influenced by the detection limit on the size of particles? Through a systematic literature analysis, we have explored data on polymer types and shapes found in food and human samples. The data provide evidence that polyester is the most commonly detected polymer in humans, followed by polyamide, polyurethane, polypropylene, and polyacrylate. Fibres emerge as the predominant shape across all categories, suggesting potential environmental contamination from the textile industry. Studies in humans and drinking water reported data on small particles, in contrast to larger size MPs detected in environmental research, in particular seafood. Discrepancies in size detection methodologies across different reports were identified, which could impact some of the discussed trends. This study highlights the need for more comprehensive research on the interactions between MPs and biological systems and the effects of MPs on toxicity, together with standardised analytical methodologies to accurately assess contamination levels and human exposure. Understanding these dynamics is essential for formulating effective strategies to mitigate the environmental and health implications of MP pollution.

Quantifying annual microplastic emissions of an urban catchment: Surface runoff vs wastewater sources.

Urban clusters are recognized as hotspots of microplastic pollution, and the associated urban rivers convey microplastics into the global oceans. Despite this knowledge, the relative contributions of various sources to the annual microplastic emissions from urban catchments remain scarcely quantified. Here, we quantified microplastic emissions from a riverine urban catchment in Japan. The total microplastics (size range: 10-5000 µm) released from the catchment amounted to 269.1 tons/annum, of which 78.1% is contributed by surface runoff and other uncontrolled emissions (UCE), and 21.1% emerges from the regulated wastewater (controlled emissions; CE), implying that approximately one-fifth is intercepted and removed by the wastewater treatment plants (WWTPs). This further indicated higher microplastic pollution by unmanaged surface runoff compared to untreated wastewater. In the dry season, WWTPs contributed significantly to the reduction of total microplastic emissions (95%) compared to wet periods (8%). On an annual scale, the treated effluent occupies only 0.1% of the total microplastics released to the river network (212.4 tons/annum), while the remaining portion is dominated by UCE, i.e., primarily surface runoff emissions (98.9%), and trivially by the background microplastic inputs that are potentially derived through atmospheric depositions in dry days (1.0%). It was shown that moderate and heavy rainfall events which occur during 18% of the year (within the context of Japan), leading to 95% of the annual microplastic emissions, are crucial for pollution control of urban rivers. Furthermore, our study demonstrated that surface area-normalized microplastic emissions from an urban catchment (∼0.8 tons/km2/annum) is globally relevant, especially for planning microplastic interventions for developed cities.

Development and CO2 capture of nitrogen-enriched microporous carbon by coupling waste polyamides with lignocellulosic biomass.

Due to the substantial emissions of global CO2, there has been growing interest in nitrogen-enriched porous carbonaceous materials that possess exceptional CO2 capture capabilities. In this study, a novel N-enriched microporous carbon was synthesized by integrating waste polyamides with lignocellulosic biomass, involving carbonization and physicochemical activation. As-synthesized adsorbents demonstrated significant characteristics including a high specific surface area (1710 m2/g) and a large micropore volume (0.497 cm3/g), as well as abundant N- and O-containing functional groups, achieved through activation at 700 °C. They displayed remarkable CO2 capture capability, achieving uptake levels of up to 6.71 mmol/g at 1 bar and 0 °C, primarily due to the filling effect of narrow micropore along with electrostatic interaction. Furthermore, the adsorbent exhibited a rapid capacity for CO2 capture, achieving 94.9% of its saturation capacity within a mere 5 min at 30 °C. This impressive performance was accurately described by the pseudo second-order dynamic model. Additionally, as-synthesized adsorbents displayed a moderate isosteric heat of CO2 adsorption, as well as superior selectivity over N2. Even after undergoing five consecutive cycles, it maintained ∼100% of its initial capacity. Undoubtedly, such findings hold immense significance in the mitigation of global plastic pollution and greenhouse effect.