Prioritizing Organic Pollutants for Shale Gas Exploitation: Life Cycle Environmental Risk Assessments in China and the US.

Environmental impacts associated with shale gas exploitation have been historically underestimated due to neglecting to account for the production or the release of end-of-pipe organic pollutants. Here, we assessed the environmental impacts of shale gas production in China and the United States using life cycle assessment. Through data mining, we compiled literature information on organic pollutants in flowback and produced water (FPW), followed by assessments using USEtox to evaluate end-of-pipe risks. Results were incorporated to reveal the life cycle risks associated with shale gas exploitation in both countries. China exhibited higher environmental impacts than the US during the production phase. Substantially different types of organic compounds were observed in the FPW between two countries. Human carcinogenic and ecological toxicity attributed to organics in FPW was 3 orders of magnitude higher than that during the production phase in the US. Conversely, in China, end-of-pipe organics accounted for approximately 52%, 1%, and 47% of the overall human carcinogenic, noncarcinogenic, and ecological impacts, respectively. This may be partially limited by the quantitative data available. While uncertainties exist associated with data availability, our study highlights the significance of integrating impacts from shale gas production to end-of-pipe pollution for comprehensive environmental risk assessments.

Near-field exposures and human health impacts for organic chemicals in interior paints: A high-throughput screening.

Interior paints contain organic chemicals that might be harmful to painters and building residents. This study aims to develop a high-throughput approach to screen near-field human exposures and health impacts related to organic chemicals in interior paints. We developed mass balance models for both water- and solvent-based paints, predicting emissions during wet and dry phases. We then screened exposures and risks, focusing on Sri Lanka where residential houses are frequently repainted. These models accurately predict paint drying time and indoor air concentrations of organic chemicals. Exposures of both painter and household resident were estimated for 65 organic chemicals in water-based and 26 in solvent-based paints, considering 12 solvents. Chemicals of concerns (CoCs) were identified, and maximum acceptable chemical contents (MACs) were calculated. Water-based paints generally pose lower health risks than solvent-based paints but might contain biocides of high concern. The total human health impact of one painting event on all household adults ranges from 1.5 × 10-3 to 2.1 × 10-2 DALYs for solvent-based paints, and from 4.1 × 10-4 to 9.5 × 10-3 DALYs for water-based paints. The present approach is a promising way to support the formulation of safer paint, and is integrated in the USEtox scientific consensus model for use in life cycle assessment, chemical substitution and risk screening.

Freshwater ecotoxicity characterization factors for PMT/vPvM substances.

This study addresses the gap in freshwater ecotoxicological characterization factors (CFs) for Persistent, Mobile, and Toxic (PMT) and Very Persistent and Very Mobile (vPvM) substances. These CFs are vital for integrating the ecotoxicity impacts of these chemicals into life cycle assessments. Our goals are twofold: first, to calculate experimental freshwater CFs for PMT/vPvM substances listed by the German Environment Agency (UBA); second, to compare these CFs with those from the USEtox database. The expanded UBA list includes 343 PMT/vPvM substances, each representing a unique chemical structure, and linked to 474 REACH-registered substances. This study successfully computed CFs for 244 substances, with 107 overlapping the USEtox database and 137 being new. However, ecotoxicity data limitations prevented CF determination for 97 substances. This research enhances our understanding of freshwater CFs for PMT/vPvM substances, covering 72% of UBA's 343 PMT/vPvM substances. Data scarcity remains a significant challenge, which invariably impedes CF calculations. Notably, the disparities observed between CF values in the USEtox database and those derived in this research largely stem from variations in ecotoxicity data. Consequently, this research underscores the dynamic nature of CFs for substances, emphasizing the need for regular updates to ensure their accuracy and relevance.

Mitigating Ecotoxicity Risks of Pesticides on Ornamental Plants Based on Life Cycle Assessment.

Ornamental plants such as floriculture and nurseries, have become increasingly popular, but their growth relies heavily on the use of many different types of pesticides. The widespread and inefficient use of these pesticides causes environmental pollution and damage to non-target organisms. Despite these impacts, there has been little research conducted on potential agrochemical pollution in the ornamental plant industry. To address this gap, a life cycle assessment (LCA) was conducted to evaluate the pesticide-related freshwater ecotoxicity impact of the US ornamental plant industry in comparison to that of major field crops. The study analyzed 195 pesticide active ingredients used in 15 major ornamental plant and four field crops. Results showed that the freshwater ecotoxicity per area (PAF m3 d/ha) of ornamental plants was significantly higher than that of field crops due to the high pesticide intensity (kg/ha) and ecotoxicity of insecticides and fungicides used in floriculture and nurseries. To mitigate environmental stress, minimizing the use of highly toxic pesticides is recommended. A ban on low-dose, high-toxicity pesticides could reduce pesticide-driven ecotoxicity by 34% and 49% for floriculture and nursery plants, respectively. This study is among the first to quantify the pesticide-driven ecotoxicity impacts of horticultural ornamental plants and proposes feasible ways to reduce these impacts, thus making the world more sustainable while still preserving its beauty.

UV-dependent freshwater effect factor of nanoscale titanium dioxide for future life cycle assessment application.

Environmental impacts of nanoscale titanium dioxide (TiO2 ) should be assessed throughout the lifetime of nanoparticles (NPs) to improve the state of knowledge of the overall sustainability. Life cycle assessment (LCA) has been previously recognized as a promising approach to systematically evaluating environmental impacts of NPs. As a result of their unique nanospecific properties, characterization factors (CF) were previously used for compensating the release and potential impacts of TiO2 NPs. However, because TiO2 NPs are known to generate reactive oxygen species and elicit toxicity to freshwater organisms, the lack of adequate UV-dependent effect factors (EFs) remains a major shortcoming when addressing their life cycle impacts. To complement the LCA of TiO2 -NPs-enabled products under their specific applications, we recapitulated the freshwater toxicity of TiO2 NPs and then modeled in USEtox to determine trophic level EF ranges under UV and non-UV exposure conditions. Results indicate that EFs derived for non-UV exposure were 52 (42.9-65) potentially affected fraction (PAF) m3 /kg, and combined toxicity data derived EFs were 70.1 (55.6-90.5) PAF m3 /kg. When considering only the UV-induced exposure condition, the modeled EF increased to 500 (333-712) PAF m3 /kg. Our work highlights that case-dependent EFs should be considered and applied to reflect more realistic ecological impacts and illustrate comprehensive life cycle environmental impacts for nanoenabled products. Integr Environ Assess Manag 2023;19:578-585. © 2022 SETAC.

Scenario-based modelling of changes in chemical intake fraction in Sweden and the Baltic Sea under global change.

The climate in Europe is warming twice as fast as it is across the rest of the globe, and in Sweden annual mean temperatures are forecast to increase by up to 3-6 °C by 2100, with increasing frequency and magnitude of floods, heatwaves, and other extreme weather. These climate change-related environmental factors and the response of humans at the individual and collective level will affect the mobilization and transport of and human exposure to chemical pollutants in the environment. We conducted a literature review of possible future impacts of global change in response to a changing climate on chemical pollutants in the environment and human exposure, with a focus on drivers of change in exposure of the Swedish population to chemicals in the indoor and outdoor environment. Based on the literature review, we formulated three alternative exposure scenarios that are inspired by three of the shared socioeconomic pathways (SSPs). We then conducted scenario-based exposure modelling of the >3000 organic chemicals in the USEtox® 2.0 chemical library, and further selected three chemicals (terbuthylazine, benzo[a]pyrene, PCB-155) from the USEtox library that are archetypical pollutants of drinking water and food as illustrative examples. We focus our modelling on changes in the population intake fraction of chemicals, which is calculated as the fraction of a chemical emitted to the environment that is ingested via food uptake or inhaled by the Swedish population. Our results demonstrate that changes of intake fractions of chemicals are possible by up to twofold increases or decreases under different development scenarios. Changes in intake fraction in the most optimistic SSP1 scenario are mostly attributable to a shift by the population towards a more plant-based diet, while changes in the pessimistic SSP5 scenario are driven by environmental changes such as rain fall and runoff rates.

Ecotoxicity characterization of chemicals: Global recommendations and implementation in USEtox.

Chemicals emitted to the environment affect ecosystem health from local to global scale, and reducing chemical impacts has become an important element of European and global sustainability efforts. The present work advances ecotoxicity characterization of chemicals in life cycle impact assessment by proposing recommendations resulting from international expert workshops and work conducted under the umbrella of the UNEP-SETAC Life Cycle Initiative in the GLAM project (Global guidance on environmental life cycle impact assessment indicators). We include specific recommendations for broadening the assessment scope through proposing to introduce additional environmental compartments beyond freshwater and related ecotoxicity indicators, as well as for adapting the ecotoxicity effect modelling approach to better reflect environmentally relevant exposure levels and including to a larger extent chronic test data. As result, we (1) propose a consistent mathematical framework for calculating freshwater ecotoxicity characterization factors and their underlying fate, exposure and effect parameters; (2) implement the framework into the USEtox scientific consensus model; (3) calculate characterization factors for chemicals reported in an inventory of a life cycle assessment case study on rice production and consumption; and (4) investigate the influence of effect data selection criteria on resulting indicator scores. Our results highlight the need for careful interpretation of life cycle assessment impact scores in light of robustness of underlying species sensitivity distributions. Next steps are to apply the recommended characterization framework in additional case studies, and to adapt it to soil, sediment and the marine environment. Our framework is applicable for evaluating chemicals in life cycle assessment, chemical and environmental footprinting, chemical substitution, risk screening, chemical prioritization, and comparison with environmental sustainability targets.

Towards a more comprehensive life cycle assessment framework for assessing toxicity-related impacts for livestock products: The case of Danish pork.

In life cycle assessments of livestock systems, toxicity-related impacts are not commonly considered or only specific aspects (such as pesticides, manufacturing of inputs) are assessed. In this context, the aim of this study was to define a framework for assessing toxicity-related impacts and to characterize human toxicity and freshwater ecotoxicity for a livestock product based on applying the state-of-the-art models PestLCI Consensus and USEtox. Furthermore, methodological gaps were discussed and ways forward were suggested. The case study focused on Danish pork production and the toxicity results were reported per kg 'meat' (the parts of pig used for human consumption) leaving the slaughterhouse. The assessment framework included the use of pesticides and heavy metals in feed production, the use of veterinary pharmaceuticals in pig production, and the manufacturing of inputs. The use of cleaning agents could not be assessed with the currently available methods. New characterization factors were calculated for 35 chemicals not available in USEtox. For Danish pork production, feed production was the main contributor to the analyzed toxicity impacts. The use of pesticides was the main driver for organic substances while heavy metal emissions related to the application of pig manure to fields were the hotspot for metal-based substances. The use of veterinary pharmaceuticals contributed only to freshwater ecotoxicity by 3%. PestLCI Consensus estimates were compared with different approaches. The impact of metabolites of pesticides and veterinary pharmaceuticals was assessed and discussed. Methodological gaps and research needs were identified regarding the assessment of pesticides, veterinary pharmaceuticals, metal-based substances, inorganic substances, and combined exposure to multiple chemicals. Better data related to the use and chemical properties of substances are needed to reduce uncertainty in toxicity modeling.

Preschool children health impacts from indoor exposure to PM2.5 and metals.

To better understand the relation between children health and indoor air quality, we measured the concentrations of fine particulate matter (PM2.5) and 11 metals (arsenic, cadmium, chromium, copper, iron, manganese, nickel, lead, antimony, selenium, and zinc) from air samples taken during both winter and spring, and focused on urban and rural area kindergartens of the Upper Silesia Region, Poland, typified by the use of fossil fuels for power and heat purposes. We combined related inhalation intake estimates for children and health effects using separate dose-response approaches for PM2.5 and metals. Results show that impacts on children from exposure to PM2.5 was 7.5 min/yr, corresponding to 14 µDALY/yr (DALY: disability-adjusted life years) with 95% confidence interval (CI): 0.3-164 min/yr, which is approximately 10 times lower than cumulative impacts from exposure to the metal components in the PM2.5 fraction of indoor air (median 76 min/yr; CI: 0.2-4.5 × 103 min/yr). Highest metal-related health impacts were caused by exposure to hexavalent chromium. The average combined cancer and non-cancer effects for hexavalent chromium were 55 min/yr, corresponding to 104 µDALY/yr, with CI: 0.5 to 8.0 × 104 min/yr. Health impacts on children varied by season and across urban and rural sites, both as functions of varying PM2.5 metal compositions influenced by indoor and outdoor emission sources. Our study demonstrates the need to consider indoor environments for evaluating health impacts of children, and can assist decision makers to focus on relevant impact reduction and indoor air quality improvement.

Influence of local geological data and geographical parameters to assess regional health impact in LCA. Tomsk oblast', Russian Federation application case.

The research paper is aimed to modify the human health impact assessment of Cr in soils. The current article presents the input of several critical parameters for the human health Impact Score (IShum) assessment in soils. The modification of the IShum is derived using geological data - results of neutron activation analysis of soils are used in the IShum calculation; research area is divided using the watersheds and population size and density. Watersheds reflect the local environmental conditions of the territory unlike the administrative units (geographical areas of the studied region) due to their geological independence. The calculations of the characterization factor value underestimate the influence of the population size and density on the final result. Default characterization factor values cannot be considered during the assessment of the potential human health impact for the big sparsely inhabited areas. In case of very low population density, the result will be overrated and underestimated in the opposite case. The current approach demonstrates that the geographical separation in the USEtox model should be specified. The same approach can be utilized for other geo zones due to the accessibility of this information (area size, population size, and density, geological, and landscape features).

Potential trade-off between water consumption and water quality: life cycle assessment of nonaqueous solvent dyeing.

Fashion industry consumes over 60% of global fibers and attracts increasing attentions due to its environmentally polluting supply chain. In addition to natural fibers cultivation, wet processes of textile manufacturing are also important contributors to water-related impacts due to their large freshwater consumption and the production of chemicals containing wastewater. Despite of efforts made in improving efficiency of water use and wastewater treatment in textile industry, innovative 'water-free' technologies, such as nonaqueous dyeing technology using organic solvent, have been developed and demonstrated to reduce water consumption significantly. However, the potential impact on water quality by organic solvents induced in supply chain of this emerging technology remains unassessed, posing an unknown risk of its promotion. Hence, in the present study, a comprehensive life cycle assessment is applied to evaluate its full environmental impacts, including those on ecosystem and human health caused by decamethylcyclopentasiloxane (D5) as the solvent used. Further, the nonaqueous dyeing system is compared with traditional aqueous dyeing technology from both environmental and economic perspectives. Results indicate that nonaqueous dyeing system is advanced in most of environment categories except for abiotic depletion potential (ADP) and Ecotoxicity. However, scenarios analysis reveal that these findings are influenced by the loss fraction of D5 during the solvent recovery process. It is suggested that the loss fraction should be controlled below 2% o.w.f. for the nonaqueous dyeing technology to be advanced throughout all environmental categories. Nonaqueous D5 dyeing could reduce water consumption by 61.30%-79.95% and greenhouse gas emissions by 43.70% compared to the traditional system, delivering a promising contribution to China's 2060 carbon neutrality ambition. Sensitivity and uncertainty analyses are also conducted to investigate the effects of the key parameters (incl. inventory data and USEtox model inputs) and demonstrate the robustness of our assessment.

Life Cycle Assessment (LCA) of a food-production system in Spain: Iberian ham based on an extensive system.

Taking into account that in the literature on pork-production Life Cycle Assessment (LCA) there are a few studies about the Iberian pig, the present article evaluates an extensive (growing-fattening) Iberian-pig system in Spain, producing meat for Iberian ham and other quality-labelled products. The study has been based on Cumulative Energy Demand (CED), Global Warming Potential (GWP), ReCiPe (midpoint; endpoint) and USEtox (human toxicity; ecotoxicity). The analysis involves feed (for pigs and piglets), transportation, drinking water, straw usage and building materials (concrete). The impacts have been evaluated per kg of live or carcass weight (two functional units). The results show that the total impacts (per kg of live or carcass weight) range from: 1) 22.05 to 28.19 MJprim (CED), 2) 4.37 to 6.19 kg CO2.eq (GWP 20a, 100a and 500a), 3) 0.86 to 1.08 Pts (ReCiPe endpoint single-score, involving Human health, Ecosystems and Resources), 4) 9.9 × 10-6 to 1.2 × 10-5 DALY (ReCiPe endpoint with characterisation), 5) 2.8 × 10-7 to 3.5 × 10-7 (species.yr) (ReCiPe endpoint with characterisation), 6) 10.12 to 12.66 CTUe (USEtox: ecotoxicity). Overall, the results show that the feed for the pigs is responsible for the major part of the environmental impacts. More analytically, maize and soya are the components with the highest environmental impacts due to factors such as transportation, use of fertilisers and diesel fuel. The discussion about pig-production environmental impacts and the role of extensive pig farming is enriched with comparisons with the literature on pig-production LCA. Critical parameters are identified and discussed, with the aim of proposing solutions to reduce pork-production environmental impacts. Finally, the usefulness of the present study and future prospects are presented.

Assessing environmental impact of NOX and SO2 emissions in textiles production with chemical footprint.

Air pollution is a major concern of the new civilized world due to its adverse impact on human health and environment. As typical air pollutants, nitrogen oxide (NOX) and sulfur dioxide (SO2) not only pollute the atmosphere by forming acid rain and particulate matter, but are also harmful to the human respiratory system. Significant emissions of NOX and SO2 in the production phases make the textile industry under enormous environmental pressure. Chemical footprint (ChF) is an effective method for transforming the potential environmental risks of pollutant emissions into an intuitive form of toxicity. In this study, we present a ChF assessment method for NOX and SO2 emissions from textiles production. For this purpose, we adopt the USEtox model and calculate the relevant characterization factors (CFs) by considering the physicochemical properties and toxicity of NOX and SO2. The textile industry in Zhejiang Province, China, is chosen as a case study to demonstrate the feasibility of this proposed ChF assessment methodology. Results indicate that ChF caused by NOX emission in Zhejiang's textile industry is approximately eight times larger than that caused by SO2 emission. The four sub-sectors of Zhejiang's textile industry (textile manufacturing sector; textile wearing apparel, footware, and caps manufacturing sector; leather, fur, feather and related products manufacturing sector; chemical fibers manufacturing sector) also have similar proportional distributions of ChFs. Besides, the textile manufacturing sector has the largest ChF, accounting for 73% of the total ChF caused by NOX and SO2 emissions.

Modeling pesticides in global surface soils: Evaluating spatiotemporal patterns for USEtox-based steady-state concentrations.

To better manage pesticide pollution in surface soils, we introduced a first-order-kinetics-based screening model to evaluate the steady-state concentrations of pesticides in surface soils while considering degradation, volatilization, plant uptake, and precipitation processes. For each process, we developed a spatiotemporal-pattern-based model using spatiotemporal variables, including air temperature (TA), relative humidity (RHA), and rainfall intensity (IRA), to characterize the overall dissipation rates (kT) of pesticides in the soil. These dissipation rates were converted to fate factors (FFs), which are commonly used in life cycle analyses. The results indicate that, in general, the kT values increase with increasing TA and IRA and decrease with increasing RHA. This is because increased TA boosts the degradation, volatilization, and plant uptake processes, whereas increased RHA lowers the plant transpiration rate. Also, the simulation for over 700 pesticides indicated that the degradation process dominates the overall dissipation of most pesticides in the soil, and the volatilization process contributes the least. In addition, we simulated chlorpyrifos FFs for Brazil, China, the US, and the European Union (EU) using the annual average TA, RHA, and IRA values. The results indicate that, in general, Brazilian federal units have the smallest FFs and the narrowest simulated FF range because of their humid tropical climates. Meanwhile, the EU member states have the largest FFs and the widest FF range because of their range in locations. In addition, our simulated results show that the surface soils in the high-latitude regions could accumulate more chlorpyrifos than those in low-latitude regions because of the larger simulated FFs. Furthermore, we parameterized our model using 737 pesticides with the USEtox, thereby providing an alternative approach to simulate the steady-state concentration of pesticides in surface soils from the USEtox available data. The model developed herein is a useful screening tool for predicting pesticide concentrations in surface soil worldwide to improve soil and ecological health risk management.

Pesticide Toxicity Footprints of Australian Dietary Choices.

Pesticides are widely used in food production, yet the potential harm associated with their emission into the environment is rarely considered in the context of sustainable diets. In this study, a life cycle assessment was used to quantify the freshwater ecotoxicity, human toxicity carcinogenic effects, and human toxicity noncarcinogenic effects associated with pesticide use in relation to 9341 individual Australian adult daily diets. The three environmental indicators were also combined into a pesticide toxicity footprint, and a diet quality score was applied to each diet. Energy-dense and nutrient-poor discretionary foods, fruits, and protein-rich foods were the sources of most of the dietary pesticide impacts. Problematically, a dietary shift toward recommended diets was found to increase the pesticide toxicity footprint compared to the current average diet. Using a quadrant analysis, a recommended diet was identified with a 38% lower pesticide toxicity footprint. This was achieved mainly through a reduction in the discretionary food intake and by limiting the choice of fresh fruits. As the latter contradicts dietary recommendations to eat a variety of fruits of different types and colors, we concluded that dietary change may not be the best approach to lowering the environmental impacts of pesticides in the food system. Instead, targeted action in the horticultural industry may be more effective. Consumers might encourage this transition by supporting growers that reduce pesticide use and apply less environmentally harmful active ingredients.

Ecotoxicity of Plastics from Informal Waste Electric and Electronic Treatment and Recycling.

Plastic materials account for about 20% of waste electrical and electronic equipment (WEEE). The recycling of this plastic fraction is a complex issue, heavily conditioned by the content of harmful additives, such as brominated flame retardants. Thus, the management and reprocessing of WEEE plastics pose environmental and human health concerns, mainly in developing countries, where informal recycling and disposal are practiced. The objective of this study was twofold. Firstly, it aimed to investigate some of the available options described in the literature for the re-use of WEEE plastic scraps in construction materials, a promising recycling route in the developing countries. Moreover, it presents an evaluation of the impact of these available end-of-life scenarios on the environment by means of the life cycle assessment (LCA) approach. In order to consider worker health and human and ecological risks, the LCA analysis focuses on ecotoxicity more than on climate change. The LCA evaluation confirmed that the plastic re-use in the construction sector has a lower toxicity impact on the environment and human health than common landfilling and incineration practices. It also shows that the unregulated handling and dismantling activities, as well as the re-use practices, contribute significantly to the impact of WEEE plastic treatments.

Chemical footprint of pesticides used in citrus orchards based on canopy deposition and off-target losses.

The application of chemical pesticides is one of the main practices in citrus orchards. But during this operation, a considerable amount of sprayed volume is emitted to off-target areas using air-blast sprayers. The present study aimed to investigate pesticides' toxicological impacts in citrus orchards through determining the proportion of pesticides in different areas (air, soil, and canopy), which facilitate toxicity assessment of pesticides in citrus orchards. In this study, human toxicity and freshwater ecotoxicity impacts were assessed using USEtox 2.1 modeling approach for five active ingredients used in citrus orchards in the south of Iran. Different spraying scenarios were defined based on two types of nozzles (Hallow-cone and Teejet full-cone) and three levels of pressure (30, 40, and 50 bar) in two orchards with different row spacing. Results showed that only 26-37% of spray solution is deposited on the target with much loss to areas between tree canopies on the row. Scenario 1 (Hallow-cone nozzle with spraying pressure as 30 bar) shows the highest spraying efficiency in the both orchards (37% and 34% for Tangerine and Lemon orchards, respectively). Air emissions were obtained around 17 and 18% for hollow-cone and Teejet full-cone nozzles, respectively. The final inventory was obtained considering evaporation rate of active ingredients from soil surface and leaves. Based on the results obtained from toxicological impact assessment, Thiacloprid and Carbendazim had the highest negative environmental impacts on human health and freshwater aquatic ecosystem, respectively. Based on the results, soil emissions were identified as more critical than air emissions in terms of environmental consequences. It can be attributed to the higher characterization factor and deposition on the soil in comparison to the air. The present study provided well-founded information on the environmental performance of production systems by estimating the relevant emissions of pesticides to different compartments and determined the human and freshwater toxicity impact profiles, which assist decision-makers and LCA-practitioners to have a better perspective about pesticides behavior in receiving compartment.

A toxicity-based analysis of Canada's National Pollutant Release Inventory (NPRI): a case study in Nova Scotia.

After the success of the Toxics Release Inventory (TRI) in the United States (US), Canada created the National Pollutant Release Inventory (NPRI). Both NPRI and TRI focus on public opinion to coerce facilities to reduce quantities of emissions, through market pressure, although early reductions in Canada may be attributed to traditional command-and-control mechanisms. NPRI uses a quantity-based approach to report atmospheric and effluent releases of pollutants to air and water, but does not account for relative toxicity of releases, which could lead to harmful chemicals being overlooked. A toxicity-based approach using characterization factors from the USEtox® environmental impact assessment tool was used for this study. Releases of organic and inorganic pollutants to both air and water in Nova Scotia for 2015 were analyzed. Using an ecotoxicity analysis found that the highest priority chemicals identified using the NPRI's quantity-based approach differed markedly from those identified using the toxicity-based approach. Many of the high-priority chemicals identified using toxicity-based analysis are detrimental to ecosystem health and warrant regulatory attention. The Office of the Auditor General of Canada recently suggested that the Canadian federal government needs to improve control risks of toxic substances. Using a toxicity-based approach may help decision makers in the Canadian federal government effectively control risks of toxic substances and help to inform decision makers, regulators, and Canadians about those risks.

A regional approach for the calculation of characteristic toxicity factors using the USEtox model.

The lack of the spatial coverage as one of the main limitations of the Life-cycle impact assessment (LCIA) models leads to disagreement between their results. The USEtox model is only model that provides 8 continental and 17 subcontinental zones but does not consider the wind and water transfers affected areas around the source of pollution. Current investigation proposes the way to reduce this limitation by using the results of chemical analysis (instrumental neutron activation analysis "INAA") of pork meat as a regional indicator of anthropogenic influence. The concentration coefficient of Cr by replacing the Bioaccumulation factor (BAF) is extrapolated into the calculation of Exposure factor (XF) to modify Characterization factor (CF). Impacted and clean areas of Tomsk district (Russia) placed around Northern industrial hub (Seversk city) are studied. Neither area is located directly in the industrial hub, but the impacted area is under an anthropogenic influence due to air and water transfer of pollution. Results of our investigation present the difference between results of own investigation and default values of USEtox. Probably the model can minimize the impact because of lack of experiment data in the database. The database can be extended more with other analytical results for wide range of metals and geographical locations.

Towards integrating toxicity characterization into environmental studies: case study of bromine in soils.

AbstractPollution from bromine and some of its related compounds is currently unregulated in soil from Russia and other countries, and tools for sound assessment of environmental impacts of bromine contamination are largely missing. Hence, assessing potential implications for humans and ecosystems of bromine soil contamination is urgently needed, which requires the combination of measured soil concentrations from environmental studies and quantified potential toxicity impacts. To address this need, we used data from an experimental study assessing bromine in soils (384 samples) of Tomsk oblast, Russia, starting from measured concentrations obtained by Instrumental Neutron Activation Analysis in an earlier study. From these data, we calculated the bromine mass in soils and used these as starting point to characterize related cumulative impacts on human health and ecosystems in the Tomsk region, using a global scientific consensus model for screening-level comparative toxicity characterization of chemical emissions. Results show that the combination of sampling methodology with toxicity characterization techniques presents a new approach to be used in environmental studies aimed at environmental assessment and analysis of a territory. Our results indicate that it is important to account for substance-specific chemical reaction pathways and transfer processes, as well as to consider region-specific environmental characteristics. Our approach will help complement environmental assessment results with environmental sustainability elements, to consider potential tradeoffs in impacts, related to soil pollution, in support of improved emission and pollution reduction strategies.