Nanostructured cobalt/copper catalysts for efficient electrochemical carbon dioxide reduction.

The search for an efficient and stable catalyst for the electrochemical reduction of CO2 to value-added chemicals is especially critical for lowering the atmospheric CO2 concentration. In this study, self-supported cobalt/copper nanostructured catalysts were designed, where the influences of the elemental composition and acid-etching on their efficiency towards the CO2 reduction reaction were studied. The developed Co/Cu catalysts showed superb catalytic activity with a low onset potential at -0.2 V vs. RHE. Gas and liquid product analysis revealed that formate and CO were the main products. It was observed that lower reductive potentials were favourable for formate production, while higher reductive potentials were more favourable for CO formation. In situ electrochemical FTIR studies were further conducted to gain insight into the CO2 reduction mechanism. The novel synthetic procedure reported in this study leads to promising electrocatalysts with high efficiencies for the conversion of CO2 into valuable products.

Electrochemical Reduction of Carbon Dioxide at TiO2/Au Nanocomposites.

Herein, we report on the facile synthesis of nanocomposite consisting of TiO2 and Au nanoparticles (NPs) via a tailored galvanic replacement reaction (GRR). The electrocatalytic activity of the synthesized TiO2/Au nanocomposites for CO2 reduction was investigated in an aqueous solution using various electrochemical methods. Our results demonstrated that the TiO2/Au nanocomposites formed through the GRR process exhibited improved catalytic activities for CO2 reduction, while generating more hydrocarbon molecules than the typical formation of CO in contrast to polycrystalline Au. GC analysis and NMR spectroscopy revealed that CO and CH4 were the gas products, whereas HCOO-, CH3COO-, CH3OH, and CH3CH2OH were the liquid products from the CO2 reduction at different cathodic potentials. This remarkable change was further studied using the density functional theory (DFT) calculations, showing that the TiO2/Au nanocomposites may increase the binding energy of the formed ·CO intermediate and reduce the free energy compared to Au, thus favoring the downstream generation of multicarbon products. The TiO2/Au nanocomposites have high catalytic activity and excellent stability and are easy to fabricate, indicating that the developed catalyst has potential application in the electrochemical reduction of CO2 to value-added products.