Solute exchanges between multi-depth groundwater and surface water of climatically vulnerable Gangetic delta front aquifers of Sundarbans.

The coastal aquifers of Sundarbans, an UNESCO world biodiversity heritage site, are highly vulnerable due to changing climatic conditions, intensification and increasing frequency of extreme climate events and uncontrolled abstraction of groundwater. The exchange of solutes between hydraulically connective shallow and deep aquifers, the seawater intrusion and the role of growing population are poorly understood in the Sundarbans. This study aims to address the solute exchange (Cl-, Sr2+, and salinity) process between surface water and groundwater (SW-GW) at local to regional scale under variable hydraulic head conditions, where annual rainfall is declining and population density is increasing [population 573 (1991) to 819 (2011)/Km2]. Electrical resistivity tomography (ERT) in combination with salinity and δ18O data was used to address the exchange of solutes between SW-GW in a hydraulic continuation. The results revealed that regionally, the Cl- concentration of Sundarbans shows an increasing trend (average 329-351 mg/L) with declining groundwater levels (⁓3 m). Local, depth-dependent study depicting there is a predominant exchange of Sr2+ between shallow depth [D1: 14-25 and D2: 30-50 m below ground level (m bgl)] with seawater (Sr2+: 30-85 µM), which is possibly absent at greater depths (D3:115 and D4: 333 m bgl). The recorded Sr2+ content ranged from 25 to 102 and 16 to 78 µM for shallow depth D1 and D2, respectively, whereas, the Sr2+ concentrations ranged from 1.4 to 6.8 and 1.2 to 5.7 µM for D3 and D4, respectively. The ERT data showed progressively increasing resistivity with increasing depth, similar to high salinity and enriched δ18O at shallow depths and depleted δ18O with low salinity at higher depth reflects the continuous distribution of solutes, which is possibly a result of local downward migration of contaminated shallow brackish water within this physically disconnected zone. The lateral and vertical transportation of solutes in variable hydraulic head conditions would be a measure of drinking water threat in present-day and in imminent future for millions of inhabitants near the coastal area.

Assessment of a naturally occurring high background radiation area with elevated levels of thorium along coastal Odisha, India using radiometric methods.

The present study evaluates the enrichment and distribution of radioelements along the eastern coast of India. India possesses the second largest reserve of thorium bearing monazite in the world, in terms of heavy minerals present primarily along its long coastline. Radioelement estimation of about 30 km long beach area along the eastern coast of India is reported and implications discussed. A total number of 822 data points were studied using a portable Geiger Muller counter, to estimate the variation of dose rates, due to the ambient radionuclides along two different trends. One was parallel (northeast-southwest) and the second one perpendicular to the coastline. Pre-selected samples from in-situ radiometric surveys on the heavy mineral placers were studied further, for quantitative estimation of the abundance of radioactive elements primarily uranium and thorium, using a High Purity Germanium detector. Radioelement concentration assessment of core samples (depth ~2 m), were studied from two different beaches. Radiological parameters like radium equivalent, annual effective doserate and absorbed dose rate has been calculated based on the 238U, 232Th and 40K concentrations. Heavy mineral placers along the shoreline indicate a very high thorium (avg - 2990.22 Bq kg-1) which is due to the extensive distribution indicative of monazite. The coastal area also exhibits relatively low uranium (avg - 319.1 Bq kg-1). Based on its high thorium concentration, the area can be considered as a high natural background radiation area. Based on the concentrations of uranium and thorium, the weathering conditions and depositional environment prevalent along the beach areas have been discussed.

Using a multi-method approach based on soil radon deficit, resistivity, and induced polarization measurements to monitor non-aqueous phase liquid contamination in two study areas in Italy and India.

Geochemical and geophysical surveys employing radon deficit, resistivity, and induced polarization (IP) measurements were undertaken on soil contaminated with non-aqueous phase liquids (NAPLs) in two different sites in India and in Italy. Radon deficit, validated through the comparison with average soil radon in reference unpolluted areas, shows the extension of contamination in the upper part of the unsaturated aquifers. In site 1 (Italy), the spill is not recent. A residual film of kerosene covers soil grains, inhibiting their chargeability and reducing electrical resistivity difference with background unpolluted areas. No correlation between the two parameters is observed. Soil volatile organic compounds (VOCs) concentration is not linked with radon deficit, supporting the old age of the spillage. NAPL pollution in sites 2a and 2b (India) is more recent and probably still active, as demonstrated by higher values of electrical resistivity. A good correlation with IP values suggests that NAPL is still distributed as droplets or as a continuous phase in the pores, strengthening the scenario of a fresh spill or leakage. Residual fraction of gasoline in the pore space of sites 2a and 2b is respectively 1.5 and 11.8 kg per cubic meter of terrain. This estimation is referred to the shallower portion of the unsaturated aquifer. Electrical resistivity is still very high indicating that the gasoline has not been strongly degraded yet. Temperature and soil water content influence differently radon deficit in the three areas, reducing soil radon concentration and partly masking the deficit in sites 2a and 2b.