In-situ monitoring of refractive index change during water-ice phase transition with a multiresonant fiber grating.

In-situ monitoring of refractive index changes during a liquid-solid phase transition is achieved by measurement of the transmission spectrum from a single tilted fiber Bragg grating immersed in water. Differential wavelength shifts of multiple mode resonances are used to eliminate cross-talk from temperature, throughout the phase transition, and from strains occurring after solidification. The measured sudden shift of refractive index at the phase transition is shown to be consistent with the expected difference from water to ice, in spite of the observed onset of compressive strain on the fiber by the frozen water. Beyond the obvious application to research on the dynamics of liquid-solid phase transitions, this work demonstrates the multiparameter measurement capabilities of multiresonant gratings.

Strong cladding mode excitation in ultrathin fiber inscribed Bragg grating with ultraviolet photosensitivity.

Strong UV-written Bragg gratings written in 50 µm-diameter cladding single mode fibers compatible with conventional fiber couple core guided light to dozens of cladding modes distributed across 140 nm in the 1400-1600 nm region, without the need for complex symmetry breaking mechanisms such as tilted, laterally offset, or localized gratings. The extent of the coupling to high order modes and the smaller cladding diameter both contribute to increasing the sensitivity to surrounding refractive index changes by more than one order of magnitude, and to an increased spacing between mode resonances to facilitate unambiguous measurements of larger index changes between 1.3 and 1.44. These improvements are confirmed by theoretical and experimental studies that also cover the temperature and strain differential sensitivities of the cladding mode resonances for complete multiparameter sensing capability.

Multiresonant analysis improves the limit of detection of tilted fiber Bragg grating refractometers.

A multiresonant approach based on tracking 27 cladding mode resonances of tilted fiber Bragg grating refractometers is shown to improve the limit of detection by a factor of 3 to 4 relative to the conventional approach of tracking the single-most sensitive resonance. Limits of detection below 2 × 10-5 in index change are achieved for dilutions of ethanol in water in repeated experiments. In all cases, wavelengths are referenced to the core mode resonance which eliminates the effect of small temperature changes during and between experiments.

Self-monitored and optically powered fiber-optic device for localized hyperthermia and controlled cell death in vitro.

Localized hyperthermia therapy involves heating a small volume of tissue in order to kill cancerous cells selectively and with limited damage to healthy cells and surrounding tissue. However, these features are only achievable through real-time control of the tissue temperature and heated volume, both of which are difficult to obtain with current heating systems and techniques. This work introduces an optical fiber-based active heater that acts both as a miniature heat source and as a thermometer. The heat-induced damage in the tissue is caused by the conductive heat transfer from the surface of the device, while the heat is generated in an absorptive coating on the fiber by near-infrared light redirected from the fiber core to the surface by a tilted fiber Bragg grating inscribed in the fiber core. Simultaneous monitoring of the reflection spectrum of the grating provides a measure of the local temperature. Localized temperature increases between 0°C and 100°C in 10 mm-long/5 mm-diameter cylindrical volumes are obtained with continuous-wave pump power levels up to 1.8 W. Computational and experimental results further indicate that the temperature rise and dimensions of the heated volume can be maintained at a nearly stable level determined by the input optical power.

Co-located angularly offset fiber Bragg grating pair for temperature-compensated unambiguous 3D shape sensing.

A 10 mm-long three-dimensional shape sensor in a single-mode fiber is described and demonstrated experimentally. The sensor is based on a pair of fiber Bragg gratings inscribed at the same location along the fiber axis but offset along different radial directions away from the fiber center. Each offset grating generates cladding mode resonances over a ${\sim}{20}\;{\rm{nm}}$-wide spectral bandwidth, and the two gratings are also offset in period so that their transmission spectra are separated by 40 nm, and thus non-overlapping and fully distinguishable. Directional bending sensitivity results from the differential amplitude response of the cladding mode resonances from the two gratings, depending on the relative orientation of the bend with the azimuthal direction of the grating offsets. It is further demonstrated that both axial deformation and temperature have no influence on the shape measurement as they both only cause a global wavelength shift of the spectra without amplitude change. The experimental results demonstrate that the shape orientation of an object can be unambiguously determined for bend directions covering the full 360° range around the fiber axis with sensitivities of the order of ${{1}}\;{\rm{dB/}}{{\rm{m}}^{- 1}}$ and small curvatures between 0 and ${{1}}\;{{\rm{m}}^{- 1}}$.

High-resolution interrogation of tilted fiber Bragg gratings using an extended range dual wavelength differential detection.

An extended range dual wavelength differential detection technique for interrogating fiber Bragg grating sensors is implemented for the measurement of tilted fiber Bragg gratings. The dynamic chirp of a single DFB laser diode modulated with a square wave is used to generate two pairs of wavelengths, in the high and low modulation states, with a separation approximately equal to the bandwidth of the TFBG, resulting in a doubling of the range of the DWDD measurement. A spectral resolution of 0.08 pm and a refractive index resolution of 9.9 × 10-6 are obtained over a range of refractive index of 3.7 × 10-2, corresponding to 11.9 bits of resolution.

Microfluidic flow direction and rate vector sensor based on a partially gold-coated TFBG.

In microfluidic chips applications, the monitoring of the rate and the direction of a microfluidic flow is very important. Here, we demonstrate a liquid flow rate and a direction sensor using a partially gold-coated tilted fiber Bragg grating (TFBG) as the sensing element. Wavelength shifts and amplitude changes of the TFBG transmission resonances in the near infrared reveal the direction of the liquid flowing along the fiber axis in the vicinity of the TFBG due to a nanoscale gold layer over part of the TFBG. For a device length of 10 mm (and a diameter of 125 µm for easy insertion into microfluidic channels), the flow rates and the direction can be detectable unequivocally. The TFBG waveguiding properties allow such devices to function in liquids with refractive indices ranging from 1.33 to about 1.40. In addition, the proposed sensor can be made inherently temperature-insensitive by referencing all wavelengths to the wavelength of the core mode resonance of the grating, which is isolated from the fiber surroundings.

Symmetry selective cladding modes coupling in ultrafast-written fiber Bragg gratings in two-mode fiber.

The lower order cladding mode resonances of a fiber Bragg grating (FBG) are sensitive to fiber bending but their spectral density makes their response to bending very complex. In this work we present a simple method to reduce and control the number of low order cladding mode resonances via FBGs written in a two-mode fiber (TMF) with an ultrafast laser. Owing to the larger core size of the TMF, a slight break of the cylindrical asymmetry of the grating patterns can be induced when using femtosecond side-irradiation with a small change in the writing condition. This allows us to control the mode families coupled by the grating, and in particular to those modes that have positive or negative bending responses along certain bend directions. Experimental results demonstrate that several lower-order neighboring-cladding mode pairs coupled by the asymmetric TMFBG have antagonistic loss responses (by several dB) for different bending directions, thus allowing full 2D bending measurements with many applications in shape sensing. Finally, this device has similar advantages as tilted FBGs, i.e. temperature de-correlation and the possibility of increasing the signal to noise ratio by averaging simultaneous measurements on several pairs of resonances.

Self-heating tilted fiber Bragg grating device for melt curve analysis of solid-phase DNA hybridization and thermal cycling.

We demonstrate a DNA-based optical fiber device that uses an in-fiber grating, a light absorbing coating with surface anchored DNA, and a built-in optical thermometer. This device is used for precisely thermal cycling surface DNA spots bound by a simple UV cross-linking technique. Near-infrared light of wavelengths near 1550 nm and guided power near 300 mW is coupled out of the fiber core by a tilted fiber Bragg grating inscribed in the fiber and absorbed by the coating to increase its temperature to more than 95 °C. A co-propagating broadband light signal (also in the near-infrared region) is used to measure the reflection spectrum of the grating and thus the temperature from the wavelength shifts of the reflection peaks. The device is capable of sensitive DNA melt analysis and can be used for DNA amplification. Graphical abstract.

Optical spectral sweep comb liquid flow rate sensor.

In microfluidic chip applications, the flow rate plays an important role. Here we propose a simple liquid flow rate sensor by using a tilted fiber Bragg grating (TFBG) as the sensing element. As the water flows in the vicinity of the TFBG along the fiber axis direction, the TFBG's spectrum changes due to its contact with water. By comparing the time-swept spectra of the TFBG in water to that of the TFBG with water flowing over it, a spectral sweep comb was formed, and the flow rate can be detected by selecting a suitable sweeping frequency. The proposed sensor has a high Q-value of over 17,000 for the lower rate and a large detectable range from 0.0058 mm/s to 3.2 mm/s. And the calculated corresponding lower detectable flow rate of 0.03 nL/s is 3 orders magnitude better than that of the current fiber flowmeter. Meanwhile, the proposed sensor has the temperature self-compensation function for the variation of the external temperature. We believe that this simple configuration will open a research direction of the TFBG-deriving theory and configuration for lower flow rate measurements for microfluidic chip applications.

Measurements of milli-Newton surface tension forces with tilted fiber Bragg gratings.

Small lateral forces (lower than 0.1 N) cannot normally be measured with conventional single-mode fiber-based sensors because of the high value of their Young modulus (>70 GPa). Here we demonstrate the measurement of lateral forces in the range from 0.2 to 1.4×10-3 N with a tilted fiber Bragg grating (TFBG) in conventional single-mode fiber pushed against the surface tension (ST) of a bead of water. The measured transmission changes of individual cladding mode resonances of the TFBG corresponding to these force values are of the order of 29 dB. Separate measurements of the contact angle between the surface of the water and the fiber are used to calibrate the sensor with help from the known value of ST for water. Once calibrated, a TFBG can be used to measure unknown forces in the same range or to measure an unknown ST, provided a separate force measurement is available.

Sample orientation in corona-poled multilayer silica structures.

The impact of sample orientation on the poling of single-sided multilayer silica structures is studied. The results show that the presence of a multilayer stack near the cathode creates a nonlinear region where it otherwise would not have formed. It is shown that field orientation impacts the location and magnitude of the induced nonlinearity. A nonlinearity is always present in the stack independent of whether the stack is on the anode or cathode side of the sample unlike the nonlinearity in bulk silica, which is always located on the anode side.

Hypersensitivity and Applications of Cladding Modes of Optical Fibers Coated with Nanoscale Metal Layers.

Theoretical and experimental results are presented to show that the complex effective index of the modes of optical fibers coated with non-uniform metal coatings of gold, silver, copper, or palladium, with thicknesses between 0 and 20 nm, acquire a greatly enhanced sensitivity to various forms of perturbations. Thickness changes of less than 1 nm can be measured as well as the binding of record low concentrations of chemical and biochemical species.

Electrochemical Surface Plasmon Resonance Fiber-Optic Sensor: In Situ Detection of Electroactive Biofilms.

Spectroelectrochemistry has been found to be an efficient technique for revealing extracellular electron transfer (EET) mechanism of electroactive biofilms (EABs). Herein, we propose a novel electrochemical surface plasmon resonance (EC-SPR) optical fiber sensor for monitoring EABs in situ. The sensor uses a tilted fiber Bragg grating (TFBG) imprinted in a commercial single-mode fiber and coated with nanoscale gold film for high-efficiency SPR excitation. The wavelength shift of the surface plasmon resonance (SPR) over the fiber surface clearly identifies the electrochemical activity of the surface localized (adjacent to the electrode interface) bacterial cells in EABs, which differs from the "bulk" detections of the conventional electrochemical measurements. A close relationship between the variations of redox state of the EABs and the changes of the SPR under potentiostatic conditions has been achieved, pointing to a new way to study the EET mechanism of the EABs. Benefiting from its compact size, high sensitivity, and ease of use, together with remote operation ability, the proposed sensor opens up a multitude of opportunities for monitoring EABs in various hard-to-reach environments.

High resolution fiber optic surface plasmon resonance sensors with single-sided gold coatings.

The surface plasmon resonance (SPR) performance of gold coated tilted fiber Bragg gratings (TFBG) at near infrared wavelengths is evaluated as a function of the angle between the tilt plane orientation and the direction of single- and double-sided, nominally 50 nm-thick gold metal depositions. Scanning electron microscope images show that the coating are highly non-uniform around the fiber circumference, varying between near zero and 50 nm. In spite of these variations, the experimental results show that the spectral signature of the TFBG-SPR sensors is similar to that of simulations based on perfectly uniform coatings, provided that the depositions are suitably oriented along the tilt plane direction. Furthermore, it is shown that even a (properly oriented) single-sided coating (over only half of the fiber circumference) is sufficient to provide a theoretically perfect SPR response with a bandwidth under 5 nm, and 90% attenuation. Finally, using a pair of adjacent TFBG resonances within the SPR response envelope, a power detection scheme is used to demonstrate a limit of detection of 3 × 10-6 refractive index units.

Off-axis ultraviolet-written fiber Bragg gratings for directional bending measurements.

Off-axis fiber Bragg gratings are inscribed by ultraviolet irradiation limited to expose only a portion of the fiber core cross section. The coupling to cladding modes is significantly increased, and the amplitude of the cladding mode resonances becomes sensitive to bending in magnitude and direction. Sensitivities ranging from +1.17 dB/m(-1) to -1.25 dB/m(-1) were obtained for bending in different directions relative to the offset direction of the grating, for curvatures from 0 to 1.1 m(-1), a range ideal for the shape sensing of large structures. The bending sensor response is also shown to be independent of temperature and the surrounding refractive index.

Near-infrared grating-assisted SPR optical fiber sensors: design rules for ultimate refractometric sensitivity.

Plasmonic optical fiber sensors are continuously developed for (bio)chemical sensing purposes. Recently, surface plasmon resonance (SPR) generation was achieved in gold-coated tilted fiber Bragg gratings (TFBGs). These sensors probe the surrounding medium with near-infrared narrowband resonances, which enhances both the penetration depth of the evanescent field in the external medium and the wavelength resolution of the interrogation. They constitute a unique configuration to probe all the fiber cladding modes individually. We use them to analyze the modal distribution of gold-coated telecommunication-grade optical fibers immersed in aqueous solutions. Theoretical investigations with a finite-difference complex mode solver are confirmed by experimental data obtained on TFBGs. We show that the refractometric sensitivity varies with the mode order and that the global SPR envelope shift in response to surrounding refractive index (SRI) changes higher than 1e-2 RIU (refractive index unit) can be ~25% bigger than the local SPR mode shift arising from SRI changes limited to 1e-4 RIU. We bring clear evidence that the optimum gold thickness for SPR generation lies in the range between 50 and 70 nm while a cladding diameter decrease from 125 µm to 80 µm enhances the refractometric sensitivity by ~20%. Finally, we demonstrate that the ultimate refractometric sensitivity of cladding modes is ~550 nm/RIU when they are probed by gold-coated TFBGs.

Evanescently coupled optical fiber refractometer based a tilted fiber Bragg grating and a D-shaped fiber.

A novel tip-reflective and power-referenced refractometer based on strong fiber-to-fiber optical coupling for a large range of surrounding refractive index (SRI) (from 1.33 to 1.45) is proposed and experimentally demonstrated. A short D-shaped fiber stub is placed in parallel and close contact to another standard circular fiber containing a weakly tilted Bragg grating (TFBG). The TFBG couples the light from the circular fiber's core into its cladding where it remains guided. Apart from the direct light coupling over the contact interface, the evanescent field from the guided cladding modes penetrates the surroundings and reaches the D-fiber core by tunneling across the medium into which the fiber pair is located. The amount of tunneling depends strongly on the SRI so that the total amount of light collected by the D-fiber provides a measure of the SRI. Sensitivities ranging from ~1000 to 13000 nW/RIU (Refractive Index Unit) have been obtained and the result is independent of temperature (within +/-10 nW of uncertainty). The measurement can be temperature-referenced through measurement of the TFBG spectrum if needed.

Absolute near-infrared refractometry with a calibrated tilted fiber Bragg grating.

The absolute refractive indices (RIs) of water and other liquids are determined with an uncertainty of ±0.001 at near-infrared wavelengths by using the tilted fiber Bragg grating (TFBG) cladding mode resonances of a standard single-mode fiber to measure the critical angle for total internal reflection at the interface between the fiber and its surroundings. The necessary condition to obtain absolute RIs (instead of measuring RI changes) is a thorough characterization of the dispersion of the core mode effective index of the TFBG across the full range of its cladding mode resonance spectrum. This technique is shown to be competitive with the best available measurements of the RIs of water and NaCl solutions at wavelengths in the vicinity of 1550 nm.

Bending sensor combining multicore fiber with a mode-selective photonic lantern.

A bending sensor is demonstrated using the combination of a mode-selective photonic lantern (PL) and a multicore fiber. A short section of three-core fiber with strongly coupled cores is used as the bend sensitive element. The supermodes of this fiber are highly sensitive to the refractive index profiles of the cores. Small bend-induced changes result in drastic changes of the supermodes, their excitation, and interference. The multicore fiber is spliced to a few-mode fiber and excites bend dependent amounts of each of the six linearly polarized (LP) modes guided in the few-mode fiber. A mode selective PL is then used to demultiplex the modes of the few-mode fiber. Relative power measurements at the single-mode PL output ports reveal a high sensitivity to bending curvature and differential power distributions according to bending direction, without the need for spectral measurements. High direction sensitivity is demonstrated experimentally as well as in numerical simulations. Relative power shifts of up to 80% have been measured at radii of approximately 20 cm, and good sensitivity was observed with radii as large as 10 m, making this sensing system useful for applications requiring both large and small curvature measurements.