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1.
Appl Opt ; 54(6): 1492-504, 2015 Feb 20.
Artigo em Inglês | MEDLINE | ID: mdl-25968218

RESUMO

A generalized transmission line method (TLM) that provides reflection and transmission calculations for a multilayer dielectric structure with coherent, partial coherent, and incoherent layers is presented. The method is deployed on two different application fields. The first application of the method concerns the thickness measurement of the individual layers of an organic light-emitting diode. By using a fitting approach between experimental spectral reflectance measurements and the corresponding TLM calculations, it is shown that the thickness of the films can be estimated. The second application of the TLM concerns the calculation of the external quantum efficiency of an organic photovoltaic with partially coherent rough interfaces between the layers. Numerical results regarding the short circuit photocurrent for different layer thicknesses and rough interfaces are provided and the performance impact of the rough interface is discussed in detail.

2.
Opt Express ; 22(8): 8856-70, 2014 Apr 21.
Artigo em Inglês | MEDLINE | ID: mdl-24787775

RESUMO

Broad-band Mach-Zehnder interferometry is analytically described and experimentally demonstrated as an analytical tool capable of high accuracy refractive index measurements over a wide spectral range. Suitable photonic engineering of the interferometer sensing and reference waveguides result in sinusoidal TE and TM spectra with substantially different eigen-frequencies. This allows for the instantaneous deconvolution of multiplexed polarizations and enables large spectral shifts and noise reduction through filtering in the Fourier Transform domain. Due to enhanced sensitivity, optical systems can be designed that employ portable spectrum analyzers with nm range resolution without compromising the sensor analytical capability. Practical detection limits in the 10(-6)-10(-7) RIU range are achievable, including temperature effects. Finally, a proof of concept device is realized on a silicon microphotonic chip that monolithically integrates broad-band light sources and single mode silicon nitride waveguides. Refractive index detection limits rivaling that of ring resonators with externally coupled laser sources are demonstrated. Sensitivities of 20 µm/RIU and spectral shifts in the tens of a pm are obtained.

3.
Opt Express ; 22(22): 26803-13, 2014 Nov 03.
Artigo em Inglês | MEDLINE | ID: mdl-25401827

RESUMO

A complete Mach-Zehnder interferometer monolithically integrated on silicon is presented and employed as a refractive index and bio-chemical sensor. The device consists of broad-band light sources optically coupled to photodetectors through monomodal waveguides forming arrays of Mach-Zehnder interferometers, all components being monolithically integrated on silicon through mainstream silicon technology. The interferometer is photonically engineered in a way that the phase difference of light travelling through the sensing and reference arms is approximately wavelength independent. Consequently, upon effective medium changes, it becomes feasible even with a broad-band source to induce sinusoidal-type of detector photocurrents similar to the classical monochromatic counterparts. The device is completed with its fluidic and interconnect components so that on chip interferometric measurements can be performed. Examples of refractive index and protein sensing are presented to establish the potential of the proposed device for real-time in situ monitoring applications. This is the only silicon device that has achieved complete on-chip interferometry.


Assuntos
Técnicas Biossensoriais/instrumentação , Interferometria/instrumentação , Refratometria/instrumentação , Silício/química , Simulação por Computador , Eletricidade , Limite de Detecção
4.
Opt Lett ; 35(9): 1476-8, 2010 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-20436608

RESUMO

Remote-point photonic sensors are fabricated and evaluated. They are based on nanocomposite thin films comprising NiCl(2) nanocrystals embedded in sol-gel silica matrix and are patterned using direct UV laser microetching techniques to form surface relief structures, which exhibit environment sensitive optical diffraction effects. A strong response to ammonia is detected via the alteration of diffraction efficiency of its orders upon exposure to the analyte. Detection of ammonia in the 2 ppm level with a typical response time of about 30 s in the ambient, 50% RH 20 degrees C, room environment is demonstrated.

5.
Sci Rep ; 5: 17600, 2015 Dec 02.
Artigo em Inglês | MEDLINE | ID: mdl-26825114

RESUMO

Protein detection and characterization based on Broad-band Mach-Zehnder Interferometry is analytically outlined and demonstrated through a monolithic silicon microphotonic transducer. Arrays of silicon light emitting diodes and monomodal silicon nitride waveguides forming Mach-Zehnder interferometers were integrated on a silicon chip. Broad-band light enters the interferometers and exits sinusoidally modulated with two distinct spectral frequencies characteristic of the two polarizations. Deconvolution in the Fourier transform domain makes possible the separation of the two polarizations and the simultaneous monitoring of the TE and the TM signals. The dual polarization analysis over a broad spectral band makes possible the refractive index calculation of the binding adlayers as well as the distinction of effective medium changes into cover medium or adlayer ones. At the same time, multi-analyte detection at concentrations in the pM range is demonstrated.


Assuntos
Técnicas Biossensoriais , Interferometria/métodos , Óptica e Fotônica/métodos , Algoritmos , Modelos Teóricos , Proteínas/química , Sensibilidade e Especificidade
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